05442nam 2200697Ia 450 991014605300332120170814180050.01-280-52023-X97866105202373-527-60508-83-527-60168-6(CKB)1000000000019224(EBL)482160(OCoLC)70044093(SSID)ssj0000254850(PQKBManifestationID)11226404(PQKBTitleCode)TC0000254850(PQKBWorkID)10211385(PQKB)11733074(MiAaPQ)EBC482160(EXLCZ)99100000000001922420010917d2004 uy 0engur|n|---|||||txtccrSynthetic metal-containing polymers[electronic resource] /Ian MannersWeinheim ;Cambridge Wiley-VCHc20041 online resource (291 p.)Description based upon print version of record.3-527-29463-5 Includes bibiographical references and index.Synthetic Metal-Containing Polymers; Preface; Contents; Abbreviations; 1 Introduction; 1.1 Metal-Containing Polymers; 1.2 Fundamental Characteristics of Polymeric Materials; 1.2.1 Polymer Molecular Weights; 1.2.2 Amorphous, Crystalline, and Liquid-Crystalline Polymers: Thermal Transitions; 1.2.3 Polymers versus Oligomers: Why are High Molecular Weights Desirable?; 1.2.4 Polymer Solubility; 1.2.5 Block Copolymers; 1.2.6 Dendrimers and Hyperbranched Polymers; 1.2.7 Electrically Conducting Polymers; 1.3 Motivations for the Incorporation of Metals into Polymer Structures1.3.1 Conformational, Mechanical, and Morphological Characteristics1.3.2 Precursors to Ceramics; 1.3.3 Magnetic, Redox, Electronic, and Optical Properties; 1.3.4 Catalysis and Bioactivity; 1.3.5 Supramolecular Chemistry and the Development of Hierarchical Structures; 1.4 Historical Development of Metal-Based Polymer Science; 1.5 Synthetic Routes to Metal-Containing Polymers; 1.5.1 The Synthesis of Side-Chain Metal-Containing Polymers; 1.5.2 Main-Chain Metal-Containing Polymers; 1.5.2.1 Why are Transition Metals in the Polymer Main Chain Desirable?1.5.2.2 The Synthesis of Main-Chain Metal-Containing Polymers1.5.2.2.1 Addition Polymerization; 1.5.2.2.2 Polycondensations; 1.5.2.2.3 Ring-Opening Polymerization (ROP); 1.6 References; 2 Side-Chain Metal-Containing Polymers; 2.1 Introduction; 2.2 Side-Chain Polymetallocene Homopolymers and Block Copolymers; 2.2.1 Organic Polymers with Metallocene Side Groups; 2.2.1.1 Poly(vinylferrocene); 2.2.1.2 Other Organic Polymers with Metallocene-Containing Side Groups; 2.2.2 Inorganic Polymers with Metallocene Side Groups; 2.2.2.1 Polyphosphazenes with Ferrocene- or Ruthenocene-Containing Side Groups2.2.2.2 Polysilanes, Polysiloxanes, and Polycarbosilanes with Metallocene Side Groups2.3 Other Side-Chain Metallopolymers; 2.3.1 Polymers with π-Coordinated Metals; 2.3.2 Polymers with Pendant Polypyridyl Complexes; 2.3.3 Polymers with Other Pendant Metal-Containing Units, Including the Area of Polymer-Supported Catalysts; 2.3.4 Block Copolymers with Pendant Metal-Containing Groups; 2.3.4.1 Approaches using Ring-Opening Metathesis Polymerization (ROMP); 2.3.4.2 Coordination to Pyridyl Substituents in Preformed Blocks; 2.3.4.3 Coordination to Other Substituents in Preformed Blocks2.4 References3 Main-Chain Polymetallocenes with Short Spacer Groups; 3.1 Introduction; 3.2 Polymetallocenylenes and Polymetallocenes with Short Spacers Obtained by Condensation Routes; 3.2.1 Polymetallocenylenes; 3.2.2 Other Polymetallocenes with Short Spacers Obtained by Polycondensation Routes; 3.3 Ring-Opening Polymerization (ROP) of Strained Metallocenophanes; 3.3.1 Thermal ROP of Silicon-Bridged [1]Ferrocenophanes; 3.3.2 Thermal ROP of Other Strained Metallocenophanes; 3.3.3 Living Anionic ROP of Strained Metallocenophanes3.3.4 Transition Metal-Catalyzed ROP of Strained MetallocenophanesThe development of the field of synthetic metal-containing polymers - where metal atoms form an integral part of the main chain or side group structure of a polymer - aims to create new materials which combine the processability of organic polymers with the physical or chemical characteristics associated with the metallic element or complex. This book covers the major developments in the synthesis, properties, and applications of synthetic metal-containing macromolecules, and includes chapters on the preparation and characterization of metal-containing polymers, metallocene-based polymers, rigCopolymersAnalysisMetal-filled plasticsAnalysisMetallic compositesPolymeric compositesPolymerizationAnalysisElectronic books.CopolymersAnalysis.Metal-filled plasticsAnalysis.Metallic composites.Polymeric composites.PolymerizationAnalysis.547.7620.192Manners Ian1961-888347MiAaPQMiAaPQMiAaPQBOOK9910146053003321Synthetic metal-containing polymers2171236UNINA01064nam0 22002771i 450 UON0052524220240624124055.28720240624d1978 |0itac50 basloSK|||| 1||||Modernita súčasnostiJozef FelixBratislavaSlovenský spisovatel'1978313 p.20 cm001UON003820782001 Horizonty210 BratislavaSlovensky spisovatel'Letteratura slovaccaStoriaUONC044010FISKBratislavaUONL000503891.87Letteratura slovacca21FELIXJozefUONV1871951853524Slovenský spisovatel'UONV271126650ITSOL20251107RICASIBA - SISTEMA BIBLIOTECARIO DI ATENEOUONSIUON00525242SIBA - SISTEMA BIBLIOTECARIO DI ATENEOSI SLOVACCO C 0118 SI RU 5543 5 0118 Modernita súčasnosti4450087UNIOR