01276nam 2200325 n 450 99638659200331620221102113729.0(CKB)1000000000613440(EEBO)2264217055(UnM)9958787500971(EXLCZ)99100000000061344019980410d1690 uy engurbn||||a|bb|[Queen Eleanor's confession][electronic resource] shewing how King Henry, with the Earl Martial, in fryars habits, came to her instead of two fryars from France, which she sent for. To a pleasant new tune[London] Printed for C. Bates, at the White-hart, in West-Smithfield.[1690?]1 sheet ([1] p.) ill. (woodcut)Title, date and place of publication suggested by Wing.Verse: "Queen Elenor was a sick Woman ..."Imperfect: cropped at head with partial loss of title.Reproduction of original in the Harvard University, Houghton Library.eebo-0067Ballads, English17th centuryBallads, EnglishCu-RivESCu-RivESBOOK996386592003316Queen Eleanor's confession2304932UNISA07578nam 2200469 450 991048378860332120231110230513.03-030-62996-1(CKB)4100000011912224(MiAaPQ)EBC6578011(Au-PeEL)EBL6578011(OCoLC)1249471496(PPN)255290217(EXLCZ)99410000001191222420211211d2021 uy 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierSymmetry in inorganic and coordination compounds a student's guide to understanding electronic structure /Franca MorazzoniCham, Switzerland :Springer,[2021]©20211 online resource (196 pages)Lecture Notes in Chemistry ;v.1063-030-62995-3 Intro -- Preface -- Acknowledgements -- Introduction -- Contents -- About the Author -- 1 The Electronic Structure Determination -- 1.1 Variation Method (Molecular Orbital Linear Combination of Atomic Orbitals, MO-LCAO) -- 1.2 A Matrix Formulation of MO Calculations -- 1.3 The Hückel Approximation -- 1.3.1 The Case of the Allyl Anion (MO-LCAO by π Orbitals) -- 1.4 The Extended Hückel Procedure -- 1.5 Group Theory -- 1.5.1 Rules for the Elements Which Constitute a Group -- 1.5.2 Group Multiplication Tables -- 1.5.3 Representation of Symmetry Operations by Matrices -- 1.6 Irreducible Representations -- 1.6.1 Character Table of groups -- 1.6.2 Factoring the Total Representations into Irreducible Representation -- 1.6.3 Relation Between Molecular Wave Functions and Irreducible Representations -- 1.6.4 Obtaining Molecular Orbitals with a Given Symmetry -- 2 Symmetry Orbitals for Different Bis and Polyatomic Molecules -- 2.1 Homonuclear Diatomic Molecules A-A of the Periodic Table First Row -- 2.2 Water Molecule, as Example of Triatomic Molecule -- 2.3 Ammonia Molecule, as Example of Tetratomic Molecule -- 2.4 Methane Molecule, as Example of Pentatomic Molecule -- 2.5 Considerations About the Models of Chemical Bond in Use Before the Adoption of the Symmetry Molecular Orbital Model -- 3 Perturbation Theory -- 3.1 Interelectronic Repulsion Perturbation -- 3.2 Spin-Orbit Coupling Perturbation -- 3.3 Crystal Field Perturbation -- 3.3.1 Use of the Group Theory to Predict the Orbital Spitting in a Given Symmetry -- 3.4 Examples of Attribution of the Absorption Bands -- 3.5 Crystal Field Limits -- 3.6 Effect of Distortion from Cubic Symmetry -- 4 Magnetism -- 4.1 Interaction Between Electrons and Magnetic Field -- 4.2 Magnetic Susceptibility Expression for S = 1/2 -- 4.3 Electron Spin Resonance -- 4.3.1 Hyperfine Nuclear Interaction.4.3.2 Hyperfine Interaction by Quantum Mechanical Approach -- 4.3.3 The Electronic Interaction with the Magnetic Field in Oriented Systems -- 4.3.4 The Electronic Interaction with the Magnetic Field in Oriented Systems -- 4.3.5 The Origin of the g Anisotropic Behavior -- 4.3.6 g Expressions for a d1 Electronic Configuration in Tetragonal Symmetry Field -- 4.3.7 g Tensor Dependence on the Energy Level Trend of the Paramagnetic Centers -- 5 The Symmetry Properties Describe the Electronic Structure of Inorganic and Coordination Compounds -- 5.1 The Case of [Fe3 Pt3 (CO)15]n− n = 2, 1, and of [Fe3 Pt3 (CO)15]2-n -- 5.2 Discussion of the Case -- 5.2.1 X-Ray Diffraction Studies -- 5.2.2 Diffuse Reflectance Spectra -- 5.2.3 Electron Spin Resonance (ESR) Spectra -- 5.3 Chemical Message -- 5.4 The Case of Adducts of NN'Ethylenebis (acetylacetoneiminato)Cobalt (II) -- 5.5 Discussion of the Case -- 5.6 Chemical Message -- 5.7 The Case of Phthalocyaninato Co(II) -- 5.8 Discussion of the Case -- 5.8.1 Electron Spin Resonance (ESR) Spectra -- 5.8.2 Diffuse Reflectance Spectra -- 5.9 Chemical Message -- 5.10 The Case of Oxygen Reduction by CoPc Supported on Inorganic Oxide -- 5.11 Discussion of the Case -- 5.12 Chemical Message -- 5.13 The Case of Metal-Dispersed Inorganic Oxides -- 5.14 Discussion of the Case -- 5.14.1 Electron Spin Resonance of Decarbonylated Systems -- 5.14.2 Interaction with Oxygen -- 5.14.3 Interaction with Carbon Monoxide -- 5.14.4 Interaction with Carbon Monoxide and Oxygen -- 5.15 Chemical Message -- 5.16 The Case of Phosphate Glasses Containing Ruthenium and Titanium Ions -- 5.17 Discussion of the Case -- 5.18 Chemical Message -- 5.19 The Case of Superoxide Dismutase Enzyme, Interacting with Antitumor Drugs -- 5.20 Discussion of the Case -- 5.21 Chemical Message -- 5.22 The Case of Generation of Free Radicals in Intact Tissues.5.23 Discussion of the Case -- 5.24 Chemical Message -- 5.25 The Case of Functional Defects in Semiconductor Oxides: ZnO -- 5.26 Discussion of the Case -- 5.27 Chemical Message -- 5.28 The Case of Functional Defects in Semiconductor Oxides: SnO2 -- 5.29 Discussion of the Case -- 5.29.1 Air Interaction with SnO2 -- 5.29.2 Argon Interaction with SnO2 -- 5.29.3 H2 and CO Interaction with SnO2, in the Presence of Air -- 5.30 Chemical Message -- 5.31 The Case: Enhancing of the Oxide Sensing Properties by Transition Metal Ions -- 5.32 Discussion of the Case -- 5.33 Chemical Message -- 5.34 The Case of the Inhibitory Effect of Cu(II) Toward Protein Kinase C -- 5.35 Discussion of the Case -- 5.36 Chemical Message -- 5.37 The Case of the Catalytic Oxidation of Propenoidic Phenols -- 5.38 Discussion of the Case -- 5.39 The Case of Sn-Doped Solgel Silica Glasses -- 5.40 Discussion of the Case -- 5.41 Chemical Message -- 5.42 The Cases of Photocatalytic TiO2 -- 5.43 Discussion of the Case -- 5.44 Chemical Message -- 5.45 The Case of Shape-Controlled TiO2 Nanoparticles -- 5.46 Discussion of the Case -- 5.47 Chemical Message -- 5.48 The Case of Charge Separation in TiO2 Embedded in Membrane -- 5.49 Discussion of the Case -- 5.50 Chemical Message -- 5.51 The Case of Shape-Controlled SnO2 -- 5.52 Discussion of the Case -- 5.52.1 Shape and Structure -- 5.52.2 Identification of Defects -- 5.52.3 Electrical Response -- 5.53 Chemical Message -- 5.54 The Case of Silica-Natural Rubber Composites -- 5.54.1 Morphology of the Dispersed Filler -- 5.54.2 Spin Probe Procedure -- 5.55 Chemical Message -- 5.56 The Case of Cis Diamino Dichloro Platinum (Cisplatin) Antitumor Drug [Pt(NH)3Cl2]: Mechanism of Combinational Chemo-radiotherapy -- 5.57 Discussion of the Case -- 5.58 Chemical Message -- 5.59 The Case of Graphite Particles that Induce Reactive Oxygen Species in Cells.5.60 Discussion of the Case -- 5.61 Chemical Message -- 5.62 The Interaction of Graphite Defects with Oxygen Treated by Structural Studies -- 5.63 Discussion of the Case -- 5.63.1 Electrochemistry -- 5.63.2 Electron Spin Resonance Measurements -- 5.64 Chemical Message -- 5.65 The Case of Persistent Free Radicals in the Atmosphere -- 5.66 Discussion of the Case -- 5.67 Chemical Message -- Tables of Characters Used in the Reported Molecules are in Appendix -- Tanabe and Sugano Diagrams -- Character Tables for Relevant Symmetry Groups -- Properties of Vectors -- Properties of Matrices -- References.Lecture Notes in Chemistry Inorganic compoundsStructureInorganic compoundsStructure.541.22Morazzoni Franca1069812MiAaPQMiAaPQMiAaPQBOOK9910483788603321Symmetry in inorganic and coordination compounds2557128UNINA01054nam0 22002651i 450 UON0046137520231205105125.98720151124d1958 |0itac50 baporPT|||| 1||||Francisco de Sá de Mirandaelementos iconográficosErnesto SoaresLisboaO Mundo do Livro195819 p., [4] c. di tav.ritr.17 cm.SÁ DE MIRANDA FRANCISCO DEUONC069825FIPTLisboaUONL003135869.09Letteratura portoghese. Storia, descrizione, studi critici21SOARESErnestoUONV151600467053O Mundo do LivroUONV274773650ITSOL20240220RICASIBA - SISTEMA BIBLIOTECARIO DI ATENEOUONSIUON00461375SIBA - SISTEMA BIBLIOTECARIO DI ATENEOSI Port IV 0079 SI MR 57303 7 0079 Francisco de Sá de Miranda1397453UNIOR