05277nam 2200637Ia 450 991014429800332120170924232338.01-280-52073-697866105207323-527-60383-23-527-60579-7(CKB)1000000000376381(EBL)482195(OCoLC)68941580(SSID)ssj0000240350(PQKBManifestationID)11191355(PQKBTitleCode)TC0000240350(PQKBWorkID)10265805(PQKB)10655801(MiAaPQ)EBC482195(EXLCZ)99100000000037638120040618d2004 uy 0engur|n|---|||||txtccrRuthenium in organic synthesis[electronic resource] /Shun-Ichi Murahashi (Ed.)Weinheim ;[Great Britain] Wiley-VCHc20041 online resource (401 p.)Description based upon print version of record.3-527-30692-7 Includes bibliographical references and index.Ruthenium in Organic Synthesis; Contents; Preface; List of Contributors; 1 Introduction; 2 Hydrogenation and Transfer Hydrogenation; 2.1 Introduction; 2.2 Hydrogenation; 2.2.1 Unfunctionalized Olefins; 2.2.2 Functionalized Olefins; 2.2.3 Unfunctionalized Ketones and Aldehydes; 2.2.4 Functionalized Ketones; 2.2.5 Imines; 2.2.6 Others; 2.3 Transfer Hydrogenation; 2.3.1 Olefins; 2.3.2 Ketones and Aldehydes; 2.3.3 Imines; 2.3.4 Others; 2.4 Concluding Remarks; 3 Oxidation Reactions; 3.1 Introduction; 3.2 Dehydrogenative Oxidation; 3.2.1 Oxidation of Alcohols; 3.2.2 Oxidative Amination of Alcohols3.2.3 Oxidation of Secondary and Primary Amines3.3 Oxidation with RuO(4); 3.4 Oxidation with Ruthenium Complex Catalysts and Oxidants; 3.4.1 Oxidation of Alcohols; 3.4.2 Oxidation of Alkenes; 3.4.3 Oxidation of Amines; 3.4.4 Oxidation of Amides and β-Lactams; 3.4.5 Oxidation of Phenols; 3.4.6 Oxidation of Hydrocarbons; 3.5 Conclusions; 4 Carbon-Carbon Bond Formations via Ruthenacycle Intermediates; 4.1 Introduction; 4.2 C-C Bond Formations Involving Ruthenacyclopentadiene/Ruthenacyclopentatriene; 4.2.1 Alkyne Cyclotrimerizations4.2.2 Cyclocotrimerizations of Alkynes with Other Unsaturated Molecules and Related Reactions4.2.3 Miscellaneous Reactions; 4.3 C-C Bond Formations Involving Ruthenacyclopentene; 4.3.1 Coupling Reactions Between Alkynes and Alkenes; 4.3.2 Three-Component Couplings of Alkynes, Alkenes, and Other Unsaturated Molecules; 4.3.3 Intramolecular Coupling of Alkynes with Enones and Vinylcyclopropanes; 4.4 C-C Bond Formations Involving Ruthenacyclopentane; 4.5 C-C Bond Formations Involving Ruthenacyclopentenedione and Ruthenacyclobutenone; 4.6 Conclusion5 Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates5.1 Introduction; 5.2 Synthesis, Structure, and Reactivity of π-Allylruthenium Complexes; 5.2.1 π-Allylruthenium(II) Complexes; 5.2.2 π-Allylruthenium(IV) Complexes; 5.2.3 π-Allylruthenium Clusters; 5.2.4 Reactivity and Catalytic Activity of (π-C(3)H(5))Ru(CO)(3)X (X = Cl or Br); 5.3 Catalytic Reactions via π-Allylruthenium Intermediates; 5.3.1 C-C Bond Formation via π-Allylruthenium Intermediates; 5.3.2 Miscellaneous Reactions via π-Allylruthenium Intermediates; 6 Ruthenium-Catalyzed Olefin Metathesis; 6.1 Introduction6.2 Ruthenium Olefin Metathesis Catalysts6.2.1 Mechanistic Considerations; 6.2.2 Case Study: Developing a Ruthenium-Carbene Catalyst for Acrylonitrile Metathesis; 6.3 Applications of Ruthenium-Catalyzed Olefin Metathesis in Organic Synthesis; 6.3.1 Ring-Closing Metathesis; 6.3.2 Cross Metathesis; 6.3.3 Combination Metathesis Processes; 6.4 Summary; 7 Ruthenium-Catalyzed Cyclopropanation; 7.1 Introduction; 7.2 Asymmetric Catalytic Cyclopropanation; 7.2.1 Styrene; 7.2.2 Other Olefins; 7.3 Non-Asymmetric Catalytic Cyclopropanation; 7.4 Carbene-Complexes and Mechanisms; 7.5 Conclusions8 Nucleophilic Additions to Alkynes and Reactions via Vinylidene IntermediatesIn this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry.From the contents:Introduction (S.-I. Murahashi)Hydrogenation and Transfer Hydrogenation (M. KOrganometallic chemistryOrganoruthenium compoundsRutheniumElectronic books.Organometallic chemistry.Organoruthenium compounds.Ruthenium.547.05632Murahashi Shunʼichi1937-916470MiAaPQMiAaPQMiAaPQBOOK9910144298003321Ruthenium in organic synthesis2054460UNINA00591nac# 22001811i 450 UON0017527120231205103110.41920030730d1999 |0itac50 baIT|||| |||||b|||||||||| RicercheStudi StoriciRomaCarocci001UON002169342001 ˆL'‰ eredità contesastorie di successioni nel Mezzogiorno prenapoleonicoAnnunziata Berrino210 RomaCarocci1999. 164 p. ; 22 cm.53ITSOL20240220RICAUON00175271Ricerche60003UNIOR