05478nam 2200721Ia 450 991101977950332120200520144314.09786612549281978352762980035276298079781282549289128254928697835276298173527629815(CKB)2670000000009655(EBL)487748(OCoLC)609856718(SSID)ssj0000397935(PQKBManifestationID)11278450(PQKBTitleCode)TC0000397935(PQKBWorkID)10356938(PQKB)10538961(MiAaPQ)EBC487748(Perlego)2761124(EXLCZ)99267000000000965520090724d2010 uy 0engur|n|---|||||txtccrHandbook of hydrogen storage new materials for future energy storage /edited by Michael HirscherWeinheim Wiley-VCH Verlag GmbH & Co.c20101 online resource (375 p.)Description based upon print version of record.9783527322732 3527322736 Includes bibliographical references and index.Handbook of Hydrogen Storage: New Materials for Future Energy Storage; Foreword; Contents; Preface; List of Contributors; 1 Storage of Hydrogen in the Pure Form; 1.1 Introduction; 1.2 Thermodynamic State and Properties; 1.2.1 Variables of State; 1.2.2 T-s-Diagram; 1.2.2.1 Joule-Thomson Coefficient; 1.2.3 Properties; 1.3 Gaseous Storage; 1.3.1 Compression and Expansion; 1.3.2 Tank Systems; 1.3.3 High Pressure Infrastructure; 1.4 Liquid Storage; 1.4.1 Liquefaction; 1.4.2 Thermodynamic Analysis; 1.4.2.1 Pressure Build-Up; 1.4.2.2 Boil-Off; 1.4.2.3 Cooling and Filling; 1.4.2.4 Back-Gas1.4.3 Tank Systems1.4.4 Distribution Facilities; 1.5 Hybrid Storage; 1.5.1 Supercritical Storage; 1.5.2 Hydrogen Slush; 1.6 Comparison of Energy Densities; 1.7 Conclusion; References; 2 Physisorption in Porous Materials; 2.1 Introduction; 2.2 Carbon Materials; 2.3 Organic Polymers; 2.4 Zeolites; 2.5 Coordination Polymers; 2.6 Conclusions; References; 3 Clathrate Hydrates; 3.1 Introduction; 3.2 Clathrate Hydrate Structures; 3.3 Hydrogen Clathrate Hydrate; 3.4 Kinetic Aspects of Hydrogen Clathrate Hydrate; 3.5 Modeling of Hydrogen Clathrate Hydrates; 3.6 Future of Hydrogen Storage; References4 Metal Hydrides4.1 Introduction; 4.2 Elemental Hydrides; 4.2.1 Ionic or Saline Hydrides; 4.2.2 Covalent Hydrides; 4.2.3 Metallic Hydrides; 4.3 Thermodynamics of Metal Hydrides; 4.3.1 Introduction; 4.3.2 Low Concentration; 4.3.3 High Concentration; 4.4 Intermetallic Compounds; 4.4.1 Thermodynamics; 4.4.1.1 Miedema's Model; 4.4.1.2 Semi-Empirical Band Structure Model; 4.4.2 Crystal Structure; 4.4.3 Electronic Structure; 4.5 Practical Considerations; 4.5.1 Synthesis; 4.5.2 Activation; 4.5.3 Hysteresis; 4.5.4 Plateau Slope; 4.5.5 Reversible Capacity; 4.5.6 Hydrogenation Kinetics4.5.7 Cycle Life4.5.8 Decrepitation; 4.6 Metal Hydrides Systems; 4.6.1 AB5; 4.6.2 TiFe; 4.6.3 AB2 Laves Phases; 4.6.4 BCC Solid Solution; 4.7 Nanocrystalline Mg and Mg-Based Alloys; 4.7.1 Hydrogen Sorption Kinetics; 4.7.2 Reduction of the Heat of Formation; 4.7.3 Severe Plastic Deformation Techniques; 4.8 Conclusion; 4.8.1 Alloys Development; 4.8.2 Synthesis; 4.8.3 System Engineering; References; 5 Complex Hydrides; 5.1 Introduction; 5.2 Complex Borohydrides; 5.2.1 Introduction; 5.2.2 Stability of Metal Borohydrides; 5.2.3 Decomposition of Complex Borohydrides5.2.4 Lithium Borohydride, LiBH45.2.4.1 Synthesis and Crystal Structure; 5.2.4.2 Decomposition of LiBH4; 5.2.5 Sodium Borohydride, NaBH4; 5.2.5.1 Synthesis and Crystal Structure; 5.2.5.2 Decomposition of NaBH4; 5.2.6 Potassium Borohydride KBH4; 5.2.7 Beryllium Borohydride Be(BH4)2; 5.2.8 Magnesium Borohydride Mg(BH4)2; 5.2.8.1 Synthesis and Crystal Structure; 5.2.8.2 Decomposition; 5.2.9 Calcium Borohydride Ca(BH4)2; 5.2.9.1 Synthesis and Crystal Structure; 5.2.9.2 Decomposition; 5.2.10 Aluminum Borohydride Al(BH4)3; 5.2.10.1 Synthesis and Crystal Structure; 5.2.10.2 Decomposition5.2.11 Zinc Borohydride Zn(BH4)2Owing to the limited resources of fossil fuels, hydrogen is proposed as an alternative and environment-friendly energy carrier. However, its potential is limited by storage problems, especially for mobile applications. Current technologies, as compressed gas or liquefied hydrogen, comprise severe disadvantages and the storage of hydrogen in lightweight solids could be the solution to this problem.Since the optimal storage mechanism and optimal material have yet to be identified, this first handbook on the topic provides an excellent overview of the most probable candidates, highlighting boHydrogenStorageMaterialsEnergy storageHydrogenStorageMaterials.Energy storage.665.81665.81 22540sdnbERG 770bstubVE 9850rvkZP 4150rvkHirscher Michael1763936MiAaPQMiAaPQMiAaPQBOOK9911019779503321Handbook of hydrogen storage4422918UNINA