01557cam a22002897i 450099100301114970753620250430125931.0940712s1819 it a b 000 0 ita db14267858-39ule_instCICOGNARA-1210ExLBibl. Interfacoltà T. PellegrinoitaCattaneo, Gaetano<1771-1841>467024Osservazioni sopra un frammento antico di bronzo di greco lavoro rappresentante Venerepubblicate in occasione delle nozze faustissime della marchesa Cristina Trivulzio col conte Giuseppe Archinti.Milano:dall'Imp. Regia Stamperia,1819.[8], 48 p., [2] c. di tav. :ill.; 2° (33 cm).Il nome dell'A. si ricava dalla prefazione.Incisioni calcografiche.Riproduzione in microfiche dell'originale conservato presso la Biblioteca Apostolica VaticanaIndicazioni bibliografiche nelle note.Leopoldo Cicognara Program :Biblioteca Cicognara[microform] : literary sources in the history of art and kindred subjectsCatalogo ragionato dei libri d'arte e d'antichità / Leopoldo Cicognara.b1426785801-04-2228-07-16991003011149707536LE002 SB Raccolta Cicognara, mcrf 34910le002E0.00no 110000.i1573875928-07-16Osservazioni sopra un frammento antico di bronzo di greco lavoro rappresentante Venere1388843UNISALENTOle00228-07-16mg -itait 0105359nam 2200721Ia 450 991101945140332120200520144314.09786610722853978128072285112807228519783527609352352760935097835276093763527609377(CKB)1000000000376262(EBL)482339(SSID)ssj0000096889(PQKBManifestationID)11121969(PQKBTitleCode)TC0000096889(PQKBWorkID)10112652(PQKB)10307487(MiAaPQ)EBC482339(OCoLC)156998666(Perlego)2750368(EXLCZ)99100000000037626220061017d2006 uy 0engur|n|---|||||txtccrActivation of small molecules organometallic and bioinorganic perspectives /edited by William B. TolmanWeinheim Wiley-VCHc20061 online resource (383 p.)Description based upon print version of record.9783527313129 3527313125 Includes bibliographical references and index.Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle"3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent TungstenThe first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.MoleculesIonsInorganic compoundsInorganic compoundsSynthesisMolecules.Ions.Inorganic compounds.Inorganic compoundsSynthesis.541.2235.60bclTolman William B1840151MiAaPQMiAaPQMiAaPQBOOK9911019451403321Activation of small molecules4419654UNINA