03122nam 2200613Ia 450 991101921840332120200520144314.09786610520800978128052080812805208099783527603770352760377897835276059273527605924(CKB)1000000000376380(EBL)482353(OCoLC)69157038(SSID)ssj0000246017(PQKBManifestationID)11174066(PQKBTitleCode)TC0000246017(PQKBWorkID)10189190(PQKB)10840205(MiAaPQ)EBC482353(Perlego)2775134(EXLCZ)99100000000037638020041110d2004 uy 0engur|n|---|||||txtccrSilicon-mediated transformations of functional groups /Helmut VorbruggenWeinheim Wiley-VCHc20041 online resource (378 p.)Description based upon print version of record.9783527306688 3527306684 Includes bibliographical references and indexes.Silicon-mediated Transformations of Functional Groups; Contents; Preface; 1 Introduction; 2 Techniques for Preparative Silylations-Desilylations; 3 Preparation and Properties of Silyloxy Leaving Groups; 4 Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide; 5 Reactions of Aldehydes and Ketones; 6 Reactions of Alcohols, Esters, Silyl Ethers, Epoxides, and Haloalkanes; 7 Reactions of N-O Systems; 8 Reactions of S-O and Se-O Systems; 9 Cyclizations and Ring Enlargements; 10 Base-catalyzed, Acid-catalyzed and Thermal Eliminations of Trimethylsilanol. Peterson Reactions11 Formation of Carbon-Phosphorus Double Bonds12 Reductions and Oxidations; 13 Dehydration-Halogenation-Activation and Silylation of Inorganic and Organic Salts and Metallorganic Compounds; 14 Formation of Organic and Inorganic Polymers; Appendix; Subject Index; Author IndexIn the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbr?ggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of silylation for the protection of functional groups, this book covers the concept of protection while simultaneously silylating-activating various functional groups, such as amides and ureas. This novel methodology opens thus numerous synthetic pathwayswhile effecting the elimination of water in itFunctional groupsSiliconFunctional groups.Silicon.547.2Vorbruggen Helmut497308MiAaPQMiAaPQMiAaPQBOOK9911019218403321Silicon-mediated transformations of functional groups4419365UNINA