05494nam 2200649 a 450 991101916510332120200520144314.09786612817458978128281745612828174509780470938416047093841297804709384090470938404(CKB)2670000000048470(EBL)624392(SSID)ssj0000419149(PQKBManifestationID)11299202(PQKBTitleCode)TC0000419149(PQKBWorkID)10382102(PQKB)11270984(MiAaPQ)EBC624392(OCoLC)676970662(Perlego)2761372(EXLCZ)99267000000004847019860220d1986 uy 0engur|n|---|||||txtccrHandbook of aqueous electrolyte thermodynamics theory & application /Joseph F. Zemaitis, Jr. ... [et al.]New York, N.Y. Design Institute for Physical Property Data sponsored by the American Institute of Chemical Engineersc19861 online resource (876 p.)Description based upon print version of record.9780816903504 0816903506 Includes bibliographical references and index.Handbook of Aqueous Electrolyte Thermodynamics Theory & Application; TABLE OF CONTENTS; I INTRODUCTION; II THERMODYNAMICS OF SOLUTIONS; Basic Thermodynamic Functions; Solutions - Basic Definitions and Concepts; Equilibrium - Necessary Conditions; Activities, Activity Coefficients and Standard States; III EQUILIBRIUM CONSTANTS; Ionic and/or Reaction Equilibrium in Aqueous Solutions; Solubility Equilibria Between Crystals and Saturated Solutions; Vapor-Liquid Equilibria in Aqueous Solutions; Temperature Effects on the Equilibrium ConstantEstimating Temperature Effects on Heat Capacity and Other Thermodynamic PropertiesEquilibrium Constants from Tabulated Data; Pressure Effects on the Equilibrium Constant; Appendix 3.1 - Criss and Cobble Parameters; IV ACTIVITY COEFFICIENTS OF SINGLE STRONG ELECTROLYTES; History; Limitations and Improvements to the Debye-Huckel Limiting Law; Further Refinements; Bromley's Method; Meissner's Method; Pitzer's Method; Chen's Method; Short Range Interaction Model; Long Range Interaction Model; Temperature Effects; Bromley's Method; Meissner's Method; Pitzer's Method; Chen's Method; ApplicationBromley's MethodMeissner's Method; Pitzer's Method; Chen's Method; NBS Smoothed Experimental Data; Test Cases:; HCl; KCl; KOH; NaCl; NaOH; CaCl2; Na2SO4; MgSO4; Bromley's Extended Equation; MgSO4 Test Case; Comparison of Temperature Effect Methods; Bromley; Meissner; Pitzer and Chen; Experimental Data; Test Cases:; HCl at 50° Celsius; KCl at 80° Celsius; KOH at 80° Celsius; NaCl at 100 and 300° Celsius; NaOH at 35° Celsius; CaCl2 at 108.85 and 201.85° Celsius; Na2SO4 at 80° Celsius; MgSO4 at 80° Celsius; Appendix 4.1 - Values for Guggenheim's β ParameterTable 1: β Values for Uni-univalent ElectrolytesTable 2: β and B Values of Bi-univalent and Uni-bivalent Electrolytes from Freezing Points; Methods for Calculating β; Appendix 4.2 - Bromley Interaction Parameters; Table 1: B Values at 25°C Determined by the Method of Least Squares on Log γ to I=6.0 (or less if limited data); Table 2: Individual Ion Values of B and δ in Aqueous Solutions at 25°C; Table 3: Bivalent Metal Sulfates at 25°C; Appendix 4.3 - Meissner Parameters; Table: Average Values of Parameter q in Equation (4.46) for Selected Electrolytes; Appendix 4.4 - Pitzer ParametersTable 1: Inorganic Acids, Bases and Salts of 1-1 TypeTable 2: Salts of Carboxylic Acids (1-1 Type); Table 3: Tetraalkylammonium Halides; Table 4: Sulfonic Acids and Salts (1-1 Type); Table 5: Additional 1-1 Type Organic Salts; Table 6: Inorganic Compounds of 2-1 Type; Table 7: Organic Electrolytes of 2-1 Type; Table 8: 3-1 Electrolytes; Table 9: 4-1 Electrolytes; Table 10: 5-1 Electrolytes; Table 11: 2-2 Electrolytes; Appendix 4.5 - Pitzer Parameter Derivatives; Table 1: Temperature Derivatives of Parameters for 1-1 Electrolytes Evaluated from Calorimetric DataTable 2: Temperature Derivatives of Parameters for 2-1 and 1-2 Electrolytes Evaluated from Calorimetric DataExpertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable ""do-it-yourself"" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful reseaElectrolytesThermal propertiesElectrolytesThermal properties.541.3/746Zemaitis Joseph F.b. 1940.986789American Institute of Chemical Engineers.MiAaPQMiAaPQMiAaPQBOOK9911019165103321Handbook of aqueous electrolyte thermodynamics2255234UNINA