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Coll.00281623VI.7.B. 1713ISLAVI.7543002BKISLAUMASIAV91020040507USA011505PATRY9020040809USA011809COPAT39020050329USA011425COPAT69020070302USA011508ANNAMARIA9020100825USA011331ANNAMARIA9020100825USA011331ANNAMARIA9020100825USA011332ANNAMARIA9020100825USA011338ANNAMARIA9020100825USA011354ANNAMARIA9020100825USA011419ANNAMARIA9020100826USA010844Guida delle fonti per la storia dell'America Latina negli archivi della Santa Sede e negli archivi ecclesiastici d'Italia943187UNISA00957nam a2200265 i 450099100340637970753620020509121613.0940121s1991 it ||| | ita 8834802780b11156764-39ule_instPARLA181253ExLIstituto di FilosofiaitaTodescan, Franco175027Itinerari critici dell'esperienza giuridica /Franco TodescanTorino :Giappichelli,1991153 p. ;23 cm.Recta ratio ;16Filosofia del dirittoSaggiFilosofia politicaSaggi.b1115676423-02-1728-06-02991003406379707536LE005 Ist.Fil. XXXVI G 261LE004-6061le005-E0.00-l- 00000.i1129971x28-06-02Itinerari critici dell'esperienza giuridica749959UNISALENTOle00501-01-94ma -itait 0105417nam 2200697Ia 450 991101897050332120200520144314.09786610519941978128051994912805199409783527605484352760548797835276047083527604707(CKB)1000000000376391(EBL)481516(SSID)ssj0000096628(PQKBManifestationID)11515923(PQKBTitleCode)TC0000096628(PQKBWorkID)10081890(PQKB)10249626(MiAaPQ)EBC481516(OCoLC)85820648(Perlego)2750342(EXLCZ)99100000000037639120040624d2005 uy 0engur|n|---|||||txtccrAcetylene chemistry chemistry, biology, and material science /edited by F. Diederich, P.J. Stang, R.R. TykwinskiWeinheim Wiley-VCHc20051 online resource (530 p.)Description based upon print version of record.9783527307814 3527307818 Includes bibliographical references and index.Acetylene Chemistry; Preface; Contents; Symbols and Abbreviations; List of Contributors; 1 Theoretical Studies on Acetylenic Scaffolds; 1.1 Introduction; 1.2 Linear Acetylenic Scaffolds; 1.2.1 The Dicarbon Molecule and Acetylene; 1.2.2 Uncapped Pure sp Carbon Chains; 1.2.3 Capped All-sp Oligoacetylenic Chains; 1.2.4 Hybrid sp-sp(2) Oligoacetylenic Molecules; 1.2.5 Hybrid sp-sp(3) Oligoacetylenic Molecules; 1.3 Cyclic Acetylenic Scaffolds; 1.3.1 Hybrid sp-sp(3) Rings; 1.3.2 Hybrid sp-sp(2) Rings (Dehydroannulenes); 1.3.3 carbo-Heteroannulenes; 1.4 Star-Shaped Acetylenic Scaffolds1.4.1 Atomic Cores1.4.2 Rod Cores; 1.4.3 Cyclic Cores; 1.5 Cage Acetylenic Scaffolds; 1.6 Conclusion; Acknowledgements; 2 Synthesis of Heterocycles and Carbocycles by Electrophilic Cyclization of Alkynes; 2.1 Introduction; 2.2 Cyclization of Oxygen Compounds; 2.2.1 Cyclization of Acetylenic Alcohols; 2.2.2 Cyclization of Acetylenic Phenols; 2.2.3 Cyclization of Acetylenic Ethers; 2.2.4 Cyclization of Acetylenic Acids and Derivatives; 2.2.5 Cyclization of Acetylenic Aldehydes and Ketones; 2.3 Cyclization of Sulfur and Selenium Compounds; 2.4 Cyclization of Nitrogen Compounds2.4.1 Cyclization of Acetylenic Amines2.4.2 Cyclization of Acetylenic Amides; 2.4.3 Cyclization of Acetylenic Carbamates; 2.4.4 Cyclization of Acetylenic Sulfonamides; 2.4.5 Cyclization of Acetylenic Enamines and Imines; 2.4.6 Cyclization of Other Acetylenic Nitrogen Functional Groups; 2.5 Cyclization of Carbon onto Acetylenes; 2.5.1 Cyclization of Acetylenic Carbonyl Compounds and Derivatives; 2.5.2 Cyclization of Diacetylenes; 2.5.3 Cyclization of Aryl Acetylenes; 2.5.4 Cyclization of Acetylenic Organometallics; 2.6 Conclusions; 2.7 Representative Experimental Procedures2.7.1 Synthesis of α-Methylene-γ-butyrolactones by Carbonylation of 1-Alkyn-4-ols2.7.2 Synthesis of 1-Alkoxyisochromenes by Cyclization of 2-(1-Alkynyl)benzaldehydes; 2.7.3 Synthesis of 3-Aryl(vinylic)indoles by Palladium-catalyzed Cross-coupling of Aryl Halides or Vinylic Triflates and 2-(1-Alkynyl)trifluoroacetanilides; 2.7.4 Synthesis of Pyridines by the Gold-catalyzed Cross-coupling of Ketones and Propargyl Amine; 2.7.5 Synthesis of 4-Iodoisoquinolines by the Cyclization of Iminoalkynes; 2.7.6 Synthesis of Cyclic Amines by Acetylene-Iminium Ion Cyclizations; Acknowledgements3 Addition of Terminal Acetylides to CO and CN Electrophiles3.1 Introduction; 3.2 Background; 3.3 Additions with Stoichiometric Amounts of Metal Acetylides; 3.4 Nucleophilic CO Additions involving the Use of Zn(II) Salts; 3.5 Acetylene Additions to CN Electrophiles; 3.6 Conclusion; 3.7 Experimental Procedures; 3.7.1 General Procedure for the Enantioselective Alkynylation of Aldehydes by the Use of Stoichiometric Amounts of Zn(OTf)(2); 3.7.2 General Procedure for the Zn(OTf)(2)-Catalyzed Enantioselective Alkynylation of Aldehydes3.7.3 General Procedure for the Enantioselective Alkynylation of Ketones Catalyzed by Zn(salen) ComplexesAcetylenes are an important and valuable class of compounds in organic synthesis. This book expands on this historically well-established concept, while incorporating the many new developments that have widened the number of applications in this field. It remains the only handbook available that embodies all the important facets of acetylene chemistry. Following the first section on synthesis, the leading authors deal with advanced materials before turning to the properties and theory of acetylenes, while a final section looks at the biological aspects. With its range of experimental procedAcetyleneAlkynesAcetylene.Alkynes.547.41335.68bclDiederich Francois543126Stang Peter J1837984Tykwinski R. R(Rik R.)1837985MiAaPQMiAaPQMiAaPQBOOK9911018970503321Acetylene chemistry4416861UNINA