04852nam 2200661 a 450 991100681860332120200520144314.01-282-25314-X9786612253133978661225299097866122531400-08-094737-90-8155-1725-4(CKB)1000000000441159(EBL)428634(OCoLC)244207469(SSID)ssj0000071958(PQKBManifestationID)11107331(PQKBTitleCode)TC0000071958(PQKBWorkID)10094510(PQKB)10240098(MiAaPQ)EBC428634(EXLCZ)99100000000044115920070824d2008 uy 0engur|n|---|||||txtccrFluorinated ionomers /Walther GrotNorwich, NY William Andrew Pub.c20081 online resource (253 p.)PDL handbook seriesDescription based upon print version of record.0-8155-1541-3 Includes bibliographical references and index.Front Cover; Fluorinated Ionomers; Copyright Page; Contents; PDL Fluorocarbon Series Editor's Preface; Preface; Acknowledgements; Chapter 1. Introduction; 1.1 Polymers; 1.2 Physical Shapes; 1.3 References; Chapter 2. History; 2.1 References; Chapter 3. Manufacture; 3.1 Introduction; 3.2 Perfluorinated Ionomers; 3.3 Polymerization; 3.4 Fabrication; 3.5 Hydrolysis and Acid Exchange; 3.6 Finishing and Testing; 3.7 Liquid Compositions; 3.8 Fluorinated Ionomers with Phosphonic or Sulfonyl Imide Functional Groups; 3.9 Partially Fluorinated Ionomers3.10 Composite Materials of Ionomers and Inorganic Oxides3.11 Remanufactured Membranes; 3.12 References; Chapter 4. Properties; 4.1 Properties of the Precursor Polymers; 4.2 Properties of the Ionic Forms; 4.3 Morphology; 4.4 Transport Properties; 4.5 Optical Properties; 4.6 Thermal Properties; 4.7 Stability; 4.8 References; Chapter 5. Applications; 5.1 Electrolysis; 5.2 Sensors and Actuators; 5.3 Dialysis; 5.4 Gas and Vapor Diffusion; 5.5 Protective Clothing; 5.6 Catalysis; 5.7 References; Chapter 6. Fuel Cells and Batteries; 6.1 Introduction; 6.2 Operating Parameters; 6.3 Ionomer Stability6.4 Direct Methanol Fuel Cells (DMFCs)6.5 Manufacture of MEAs; 6.6 References; 6.7 Further Reading; Chapter 7. Commercial Membrane Types; 7.1 Unreinforced Perfluorinated Sulfonic Acid Films; 7.2 Reinforced Perfluorinated Membranes; Chapter 8. Economic Aspects; 8.1 Chlor-Alkali Cells; 8.2 Fuel Cells; 8.3 References; Chapter 9. Experimental Methods; 9.1 Infrared Spectra; 9.2 Hydrolysis, Surface Hydrolysis and Staining; 9.3 Other Reactions of the Precursor Polymer; 9.4 Ion Exchange Equilibrium; 9.5 Determination of EW by Titration or Infrared Analysis; 9.6 Determining Melt Flow9.7 Distinguishing the Precursor Polymer from Various Ionic Forms9.8 Fenton's Test for Oxidative Stability; 9.9 Examination of a Membrane; 9.10 Determining the Permselectivity; 9.11 Measuring Pervaporation Rates; 9.12 Simple Electrolytic Cells; 9.13 References; Chapter 10. Heat Sealing and Repair; 10.1 Reference; Chapter 11. Handling and Storage; 11.1 Handling the Film; 11.2 Pretreatment; 11.3 Installation; Chapter 12. Toxicology, Safety and Disposal; 12.1 Toxicology; 12.2 Safety; 12.3 Disposal; 12.4 References; Appendix A: A Chromic Acid Regeneration SystemAppendix B: Laboratory Chlor-alkali CellAppendix C: Solution Cast Nafion Film; Appendix D: Plastic-Based Bipolar Plates; Suppliers and Resources; Glossary and Web Sites; Index; Plastics Design Library Founding Editor: William A. WoishnisThe author of this unique handbook on fluorinated ionomers is also the inventor of the first commercial product known as Nafion® (DuPont). The book covers partially fluorinated and perfluorinated polymers containing sufficient ionic groups to dominate the transport properties of the polymer. The emphasis of this book is on the practical aspects of working with fluorinated ionomers. It is intended to help the scientist and engineer in the preparation, fabrication, use, and study of these products as well as in the development of new applications and compositions. Extensive coverage has PDL handbook series.IonomersOrganofluorine compoundsElectrolytic cellsIonomers.Organofluorine compounds.Electrolytic cells.668.9Grot Walther1822758MiAaPQMiAaPQMiAaPQBOOK9911006818603321Fluorinated ionomers4389122UNINA