05513nam 2200745 a 450 991100680610332120200520144314.00-08-094728-X1-282-76962-697866127696271-282-01358-097866120135840-8155-1653-31-60119-517-6(CKB)1000000000415842(EBL)428641(OCoLC)234087480(SSID)ssj0000071611(PQKBManifestationID)11107103(PQKBTitleCode)TC0000071611(PQKBWorkID)10090159(PQKB)11766860(MiAaPQ)EBC428641(MiAaPQ)EBC4952442(Au-PeEL)EBL4952442(CaONFJC)MIL201358(OCoLC)968119562(PPN)187265658(EXLCZ)99100000000041584220070227d2007 uy 0engur|n|---|||||txtccrCompounding precipitated silica in elastomers /Norman HewitttNorwich, NY William Andrew Pub.c20071 online resource (603 p.)Plastics design libraryDescription based upon print version of record.0-8155-1528-6 Includes bibliographical references and index.Front Cover; Compounding Precipitated Silica in Elastomers; Copyright Page; Table of Contents; Acknowledgements; Preface; Chapter 1. SILICA AS A REINFORCING FILLER; 1.1 Introduction; 1.2 Manufacture of Precipitated Silica; 1.3 Silica and Carbon Black; 1.4 Silica Surface Area; 1.5 Silica Free Water; 1.6 Silica Free Water, Affect on Visible Dispersion; 1.7 Silica Surface Silanol Groups; 1.8 Silica pH; 1.9 Soluble Salts in Silica; 1.10 Physical Form and Sensity of Silica; 1.11 Other Silica Properties; 1.12 Silane Treated Silicas; Chapter 2. COMPOUNDING PRECIPITATED SILICA IN NATURAL RUBBER2.1 Introduction2.2 Silica and Carbon Black; 2.3 Activation: Zinc Oxide; 2.4 Cure Activation: Glycols; 2.5 Acceleration with Secondary Accelerators in Normal Sulfur Systems; 2.6 Acceleration: Single Accelerators in Normal Sulfur Systems; 2.7 Acceleration: Single Accelerators; Vulcanizate Properties; 2.8 Acceleration: Low Sulfur/Sulfur Donor Systems; 2.9 Reversion; 2.10 Antioxidant Systems: Non-staining; 2.11 Plasticization; 2.12 Tear Resistance; 2.13 Tear Resistance: Contour Curve Studies of Silica Content Effects; 2.14 Tear Resistance: Silica Primary Particle Size; 2.15 Tear ResistanceNon-Marking Solid tires2.16 Shelf Aged Stiffness and Green Strength; 2.17 Peroxide Cure; 2.18 Peroxide Curing: Silica Reinforcement and Structure; 2.19 Peroxide Curing: Silica Surface Area; 2.20 Peroxide Cure: Silane Coupling; 2.21 Silane Coupling: Sulfur Cure Systems; 2.22 Zinc-Free Cure Systems; 2.23 Zinc-Free Cure Systems: Polyisoprene (IR); 2.24 Brass Adhesion; 2.25 Brass Adhesion Mechanism; 2.26 Adhesion to Textile Fabrics; the HRH System; 2.27 Fabric Adhesion: Dynamic Testing; 2.28 Heat Resistance; Natural Rubber Formulary; Chapter 3. COMPOUNDING PRECIPITATED SILICA IN EMULSION SBR3.1 Introduction3.2 Silica and Carbon Black; 3.3 Cure Systems: Activation with Glycols; 3.4 Cure System: Zinc Oxide Activation; 3.5 Cure System: Magnesium Oxide Activation; 3.6 Cure System: Lead oxide (Litharge) Activation; 3.7 Cure System: Stearic Acid; 3.8 Cure Systems: Primary, Secondary Accelerators; 3.9 Cure Systems: Single Accelerators; 3.10 Cure Systems: Sulfur Concentration; 3.11 Plasticization; 3.12 Antioxidants; 3.13 Tear Resistance: Silica Primary Particle Size; 3.14 Tear Resistance: Silica Content; 3.15 Fabric Adhesion; 3.16 Heat Resistance; 3.17 Silane Coupling3.18 Silane Coupling: CompetitionEmulsion SBR Formulary; Chapter 4. COMPOUNDING PRECIPITATED SILICA IN SOLUTION SBR AND BR; 4.1 Introduction; 4.2 Silica and Carbon Black; 4.3 Zinc-Free Cure Systems; 4.4 Zinc-Free Cure Systems: Accelerators & Sulfur; 4.5 Zinc-Free Cure Systems: Polymer Effects; 4.6 Zinc-Free Cure Systems: Zinc Oxide and HMT; 4.7 Zinc-Free Cure Systems: Effects of Additives; 4.8 Zinc-Free Cure Systems: Sulfur Content; 4.9 Zinc-Free Cure System: Antioxidants; 4.10 Zinc-Free Cure Systems: Processing; 4.11 Zinc-Free Systems: Plasticizers4.12 Zinc-Free Systems: Additive PlasticizersThis valuable guide to compounding elastomers with precipitated silica covers principles, properties, mixing, testing and formulations from a practical perspective. This handbook and reference manual will serve those who work on part design, elastomer formulation, manufacturing and applications of elastomers. Ample discussion of compound specifications adds to the usefulness of this book to practitioners. Comparisons of carbon black and silica compounds throughout the book allow readers to select the most suitable formulation for applications ranging from tires to electrical insulation to shoePlastics Design LibraryElastomersRubberSilicaElastomers.Rubber.Silica.678Hewitt Norman1822866MiAaPQMiAaPQMiAaPQBOOK9911006806103321Compounding precipitated silica in elastomers4391165UNINA