01831nam 2200361 450 991072439190332120230630103050.0(CKB)5470000002600848(NjHacI)995470000002600848(EXLCZ)99547000000260084820230630d2013 uy 0gerur|||||||||||txtrdacontentcrdamediacrrdacarrierDie Canabae von Carnuntum - eine Modellstudie der Erforschung römischer Lagervorstädte Von der Luftbildprospektion zur siedlungsarchäologischen Synthese /Michael Doneus, Christian Gugl, Nives DoneusWien :Verlag der Österreichischen Akademie der Wissenschaften,2013.©20131 online resource (291 pages)Includes bibliographical references and index.Aufgrund jahrzehntelanger, systematischer luftbildarchäologischer Arbeiten konnte ein vorläufiger Gesamtplan der im Boden verborgenen antiken Reste des römischen Carnuntum hergestellt werden. Dieser zeigt archäologische Strukturen, die sich über mehrere Quadratkilometer erstrecken und von der dichten Bebauung des Stadtareals der canabae bis zu Strukturen der Wasserversorgung reichen. In Zusammenschau mit publizierten Altgrabungen konnte eine Neubewertung des bisherigen Forschungsstandes erfolgen und ein Stadtmodell der canabae erarbeitet werden.Carnuntum (Extinct city)936.4Doneus Michael801900Gugl ChristianDoneus NivesNjHacINjHaclBOOK9910724391903321Die Canabae von Carnuntum - eine Modellstudie der Erforschung römischer Lagervorstädte3084686UNINA08309nam 22005774a 450 991096289760332120250508105434.001915238799780191523878(MiAaPQ)EBC7037336(CKB)24235072800041(MiAaPQ)EBC422683(Au-PeEL)EBL422683(CaPaEBR)ebr10177963(CaONFJC)MIL75896(OCoLC)437109147(PPN)15919962X(Au-PeEL)EBL7037336(OCoLC)76951012(EXLCZ)992423507280004120051014d2006 uy 0engur|||||||||||txtrdacontentcrdamediacrrdacarrierChemical dynamics in condensed phases relaxation, transfer and reactions in condensed molecular systems /Abraham Nitzan1st ed.Oxford ;New York Oxford University Press2006xxii, 719 p. illOxford graduate textsIncludes bibliographical references and index.Intro -- Contents -- PART I: BACKGROUND -- 1 Review of some mathematical and physical subjects -- 1.1 Mathematical background -- 1.2 Classical mechanics -- 1.3 Quantum mechanics -- 1.4 Thermodynamics and statistical mechanics -- 1.5 Physical observables as random variables -- 1.6 Electrostatics -- 2 Quantum dynamics using the time-dependent Schrödinger equation -- 2.1 Formal solutions -- 2.2 An example: The two-level system -- 2.3 Time-dependent Hamiltonians -- 2.4 A two-level system in a time-dependent field -- 2.5 A digression on nuclear potential surfaces -- 2.6 Expressing the time evolution in terms of the Green's operator -- 2.7 Representations -- 2.8 Quantum dynamics of the free particles -- 2.9 Quantum dynamics of the harmonic oscillator -- 2.10 Tunneling -- 2A: Some operator identities -- 3 An Overview of Quantum Electrodynamics and Matter-Radiation Field Interaction -- 3.1 Introduction -- 3.2 The quantum radiation field -- 3A: The radiation field and its interaction with matter -- 4 Introduction to solids and their interfaces -- 4.1 Lattice periodicity -- 4.2 Lattice vibrations -- 4.3 Electronic structure of solids -- 4.4 The work function -- 4.5 Surface potential and screening -- 5 Introduction to liquids -- 5.1 Statistical mechanics of classical liquids -- 5.2 Time and ensemble average -- 5.3 Reduced configurational distribution functions -- 5.4 Observable implications of the pair correlation function -- 5.5 The potential of mean force and the reversible work theorem -- 5.6 The virial expansion-the second virial coefficient -- PART II: METHODS -- 6 Time correlation functions -- 6.1 Stationary systems -- 6.2 Simple examples -- 6.3 Classical time correlation functions -- 6.4 Quantum time correlation functions -- 6.5 Harmonic reservoir -- 7 Introduction to stochastic processes -- 7.1 The nature of stochastic processes.7.2 Stochastic modeling of physical processes -- 7.3 The random walk problem -- 7.4 Some concepts from the general theory of stochastic processes -- 7.5 Harmonic analysis -- 7A: Moments of the Gaussian distribution -- 7B: Proof of Eqs (7.64) and (7.65) -- 7C: Cumulant expansions -- 7D: Proof of the Wiener-Khintchine theorem -- 8 Stochastic equations of motion -- 8.1 Introduction -- 8.2 The Langevin equation -- 8.3 Master equations -- 8.4 The Fokker-Planck equation -- 8.5 Passage time distributions and the mean first passage time -- 8A: Obtaining the Fokker-Planck equation from the Chapman-Kolmogorov equation -- 8B: Obtaining the Smoluchowski equation from the overdamped Langevin equation -- 8C: Derivation of the Fokker-Planck equation from the Langevin equation -- 9 Introduction to quantum relaxation processes -- 9.1 A simple quantum-mechanical model for relaxation -- 9.2 The origin of irreversibility -- 9.3 The effect of relaxation on absorption lineshapes -- 9.4 Relaxation of a quantum harmonic oscillator -- 9.5 Quantum mechanics of steady states -- 9A: Using projection operators -- 9B: Evaluation of the absorption lineshape for the model of Figs 9.2 and 9.3 -- 9C: Resonance tunneling in three dimensions -- 10 Quantum mechanical density operator -- 10.1 The density operator and the quantum Liouville equation -- 10.2 An example: The time evolution of a two-level system in the density matrix formalism -- 10.3 Reduced descriptions -- 10.4 Time evolution equations for reduced density operators: The quantum master equation -- 10.5 The two-level system revisited -- 10A: Analogy of a coupled 2-level system to a spin ½ system in a magnetic field -- 11 Linear response theory -- 11.1 Classical linear response theory -- 11.2 Quantum linear response theory -- 11A: The Kubo identity -- 12 The Spin-Boson Model -- 12.1 Introduction -- 12.2 The model.12.3 The polaron transformation -- 12.4 Golden-rule transition rates -- 12.5 Transition between molecular electronic states -- 12.6 Beyond the golden rule -- PART III: APPLICATIONS -- 13 Vibrational energy relaxation -- 13.1 General observations -- 13.2 Construction of a model Hamiltonian -- 13.3 The vibrational relaxation rate -- 13.4 Evaluation of vibrational relaxation rates -- 13.5 Multi-phonon theory of vibrational relaxation -- 13.6 Effect of supporting modes -- 13.7 Numerical simulations of vibrational relaxation -- 13.8 Concluding remarks -- 14 Chemical reactions in condensed phases -- 14.1 Introduction -- 14.2 Unimolecular reactions -- 14.3 Transition state theory -- 14.4 Dynamical effects in barrier crossing-The Kramers model -- 14.5 Observations and extensions -- 14.6 Some experimental observations -- 14.7 Numerical simulation of barrier crossing -- 14.8 Diffusion-controlled reactions -- 14A: Solution of Eqs (14.62) and (14.63) -- 14B: Derivation of the energy Smoluchowski equation -- 15 Solvation dynamics -- 15.1 Dielectric solvation -- 15.2 Solvation in a continuum dielectric environment -- 15.3 Linear response theory of solvation -- 15.4 More aspects of solvation dynamics -- 15.5 Quantum solvation -- 16 Electron transfer processes -- 16.1 Introduction -- 16.2 A primitive model -- 16.3 Continuum dielectric theory of electron transfer processes -- 16.4 A molecular theory of the nonadiabatic electron transfer rate -- 16.5 Comparison with experimental results -- 16.6 Solvent-controlled electron transfer dynamics -- 16.7 A general expression for the dielectric reorganization energy -- 16.8 The Marcus parabolas -- 16.9 Harmonic field representation of dielectric response -- 16.10 The nonadiabatic coupling -- 16.11 The distance dependence of electron transfer rates -- 16.12 Bridge-mediated long-range electron transfer.16.13 Electron tranport by hopping -- 16.14 Proton transfer -- 16A: Derivation of the Mulliken-Hush formula -- 17 Electron transfer and transmission at molecule-metal and molecule-semiconductor interfaces -- 17.1 Electrochemical electron transfer -- 17.2 Molecular conduction -- 18 Spectroscopy -- 18.1 Introduction -- 18.2 Molecular spectroscopy in the dressed-state picture -- 18.3 Resonance Raman scattering -- 18.4 Resonance energy transfer -- 18.5 Thermal relaxation and dephasing -- 18.6 Probing inhomogeneous bands -- 18.7 Optical response functions -- 18A: Steady-state solution of Eqs (18.58): the Raman scattering flux -- Index -- A -- B -- C -- D -- E -- F -- G -- H -- I -- J -- K -- L -- M -- N -- O -- P -- Q -- R -- S -- T -- V -- W -- X.Graduate level textbook presenting some of the most fundamental processes that underlie physical, chemical and biological phenomena in complex condensed phase systems. Includes in-depth descriptions of relevant methodologies, and provides ample introductory material for readers of different backgrounds.Oxford graduate texts.Molecular dynamicsChemical reaction, Conditions and laws ofMolecular dynamics.Chemical reaction, Conditions and laws of.541/.394Nitzan Abraham597540MiAaPQMiAaPQMiAaPQBOOK9910962897603321Chemical dynamics in condensed phases1031201UNINA