02546nam 2200625 a 450 991096260840332120251117063834.09781788018302178801830397818475509271847550924(CKB)1000000000791329(EBL)1185543(SSID)ssj0000379365(PQKBManifestationID)11271602(PQKBTitleCode)TC0000379365(PQKBWorkID)10366565(PQKB)11751198(MiAaPQ)EBC1185543(Au-PeEL)EBL1185543(CaPaEBR)ebr10621251(OCoLC)843641287(PPN)198478321(MiAaPQ)EBC7423245(Au-PeEL)EBL7423245(Perlego)787341(iGPub)CSPLUS0082225(EXLCZ)99100000000079132920040702d2003 uy 0engur|n|---|||||txtccrFree energy relationships in organic and bio-organic chemistry /Andrew Williams1st ed.Cambridge, U.K. RSCc20031 online resource (313 p.)Description based upon print version of record.9780854046768 0854046763 Includes bibliographical references and index.01PRELIM; 02PREFA; 03CONT; 04CHAP01; 05CHAP02; 06CHAP03; 07CHAP04; 08CHAP05; 09CHAP06; 10CHAP07; 11APPEN1; 12APPEN2; 13APPEN3; 14APPEN4; 15INDEXIntroducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for thLinear free energy relationshipLinear free energy relationship.547.139Williams Andrew1937-1896520MiAaPQMiAaPQMiAaPQBOOK9910962608403321Free energy relationships in organic and bio-organic chemistry4551205UNINA