05291nam 22006134a 450 991087798690332120200520144314.01-280-19704-897866101970400-470-98861-41-4051-4479-3(CKB)1000000000341892(EBL)233026(OCoLC)475939152(SSID)ssj0000254830(PQKBManifestationID)11213137(PQKBTitleCode)TC0000254830(PQKBWorkID)10213123(PQKB)11234658(MiAaPQ)EBC233026(EXLCZ)99100000000034189220040809d2005 uy 0engur|n|---|||||txtccrSynthesis of naturally occurring nitrogen heterocycles from carbohydrates /El Sayed H. El Ashry, Ahmed El NemrOxford, UK ;Ames, Iowa Blackwell Pub.20051 online resource (466 p.)Description based upon print version of record.1-4051-2934-4 Includes bibliographical references and indexes.Synthesis of Naturally Occurring Nitrogen Heterocycles from Carbohydrates; Contents; Preface; Author details; List of abbreviations and acronyms used in this book; Introduction; 1. Five-membered nitrogen heterocycles; 1.1 Hydroxymethylpyrrolidines; 1.1.1 2-Hydroxymethylpyrrolidines; 1.1.1.1 Synthesis from D-glucose; 1.1.1.2 Synthesis from D-mannose; 1.1.1.3 Synthesis from L-arabinose; 1.1.1.4 Synthesis from D-xylose; 1.1.1.5 Synthesis from D-threose; 1.1.1.6 Synthesis from D-lyxonolactone; 1.1.1.7 Synthesis from D-gulonolactone; 1.1.2 Dihydro-2-hydroxymethylpyrrole (nectrisine)1.1.2.1 Synthesis from D-glucose1.1.2.2 Synthesis from D-arabinose; 1.1.2.3 Synthesis from D-glyceraldehyde; 1.1.2.4 Synthesis from L-threitol; 1.1.3 2,5-Dihydroxymethylpyrrolidines; 1.1.3.1 Synthesis from D-glucose; 1.1.3.2 Synthesis from D-glucosamine; 1.1.3.3 Synthesis from D-fructose; 1.1.3.4 Synthesis from L-sorbose; 1.1.3.5 Synthesis from D-arabinose; 1.1.3.6 Synthesis from L-xylose; 1.1.3.7 Synthesis from D-iditol; 1.1.3.8 Synthesis from D-mannitol; 1.1.3.9 Synthesis from D-glucosamic acid; 1.1.3.10 Synthesis from D-glyconolactone; 1.2 2-Carboxypyrrolidines; 1.2.1 Hydroxyprolines1.2.1.1 Synthesis from D-glucose1.2.1.2 Synthesis from D-mannitol; 1.2.1.3 Synthesis from L-arabinono- and L-lyxono-lactones; 1.2.1.4 Synthesis from D-ribonolactone; 1.2.1.5 Synthesis from D-gulonolactones; 1.2.1.6 Synthesis from D-gluconolactone; 1.2.1.7 Synthesis from D-glucoronolactone; 1.2.1.8 Synthesis from D-xylonolactone; 1.2.2 Bulgecins; 1.2.2.1 Synthesis from D-glucose; 1.2.2.2 Synthesis from D-glucuronolactone; 1.3 2-Aralkyl pyrrolidines; 1.3.1 (-)-Anisomycin; 1.3.1.1 Synthesis from D-galactose; 1.3.1.2 Synthesis from L-arabinose; 1.3.1.3 Synthesis from D-ribose1.3.1.4 Synthesis from L-threose1.3.1.5 Synthesis from L-threitol; 1.3.1.6 Synthesis from D-mannitol; 1.3.2 (+)-Preussin; 1.3.2.1 Synthesis from D-glucose; 1.3.2.2 Synthesis from D-mannose; 1.3.2.3 Synthesis from D-arabinose; 1.4 2-Aryl pyrrolidines; 1.4.1 Codonopsinine and codonopsine; 1.5 Miscellaneous; 1.5.1 Detoxins; 1.5.1.1 Synthesis from D-glucose; 1.5.1.2 Synthesis from L-ascorbic acid; 1.5.2 Gualamycin; 1.5.3 Lactacystin; 2. Five-membered heterocycles with two heteroatoms; 2.1 (+)-Hydantocidin; 2.1.1 Synthesis from D-fructose; 2.1.2 Synthesis from D-ribose2.1.3 Synthesis from D-threose2.1.4 Synthesis from D-ribonolactone; 2.2 Bleomycin; 2.2.1 Synthesis from D-glucosamine; 2.2.2 Synthesis from L-rhamnose; 2.2.3 Total synthesis of bleomycin A2; 2.3 Calyculins; 2.3.1 Synthesis from D-lyxose; 2.3.2 Synthesis from D-gulonolactone; 2.3.3 Synthesis from L-idonolactone; 2.3.4 Synthesis from D-ribonolactone; 2.3.5 Synthesis from D-erythronolactone; 2.4 Acivicin; 2.5 Bengazole; 3. Six-membered nitrogen heterocycles; 3.1 Hydroxymethylpiperidines; 3.1.1 Nojirimycin; 3.1.1.1 Synthesis from D-glucose; 3.1.1.2 Synthesis from L-sorbose3.1.1.3 Synthesis from L-threoseCarbohydrates are widely distributed in nature and widely available, and so are considered as a promising feedstock for the preparation of many organic chemical compounds. They are particularly useful in the preparation of nitrogen heterocycles because of their related structural characteristics and easy availability. Synthesis of Naturally Occurring Nitrogen Heterocycles from Carbohydrates will review the recent literature dealing with use of carbohydrates as raw materials in the synthesis of these materials. The text contains six chapters arranged according to the compleHeterocyclic compoundsSynthesisCarbohydratesHeterocyclic compoundsSynthesis.Carbohydrates.547/.590459El Ashry El Sayed H.1942-969036El-Nemr Ahmed1962-936000MiAaPQMiAaPQMiAaPQBOOK9910877986903321Synthesis of naturally occurring nitrogen heterocycles from carbohydrates2201514UNINA