05557nam 2200709Ia 450 991087784430332120200520144314.01-280-27032-297866102703230-470-36296-00-470-85579-70-470-85580-0(CKB)111087027148366(EBL)153812(OCoLC)807996068(SSID)ssj0000291044(PQKBManifestationID)11217254(PQKBTitleCode)TC0000291044(PQKBWorkID)10249037(PQKB)10569495(MiAaPQ)EBC153812(EXLCZ)9911108702714836620020522d2002 uy 0engur|n|---|||||txtccrHydrolysis, oxidation and reduction /edited by Stan M. Roberts and Geraldine PoignantChichester, West Sussex, England ;New York Wileyc20021 online resource (245 p.)Catalysts for fine chemical synthesis ;v. 1Description based upon print version of record.0-471-98123-0 Includes bibliographical references and index.Catalysts for Fine Chemical Synthesis Volume 1; Contents; Series Preface; Preface to Volume 1; Abbreviations; PART I: REVIEW; 1 The Integration of Biotransformations into the Catalyst Portfolio; 1.1 Hydrolysis of esters, amides, nitriles and oxiranes; 1.2 Reduction reactions; 1.2.1 Reduction of carbonyl compounds; 1.2.2 Reduction of alkenes; 1.3 Oxidative transformations; 1.4 Carbon-carbon bond-forming reactions; 1.5 Conclusions; References; PART II: PROCEDURES; 2 General Information; 3 Asymmetric Epoxidation; 3.1 Introduction; References; 4 Epoxidation of a, b-Unsaturated Carbonyl Compounds4.1 Non-asymmetric epoxidation4.2 Asymmetric epoxidation using poly-D-leucine; 4.2.1 Synthesis of leucine N-carboxyanhydride; 4.2.2 Synthesis of immobilized poly-D-leucine; 4.2.3 Asymmetric epoxidation of (E)-benzylideneacetophenone; 4.2.4 Conclusion; 4.3 Asymmetric epoxidation using chiral modified diethylzinc; 4.3.1 Epoxidation of 2-isobutylidene-1-tetralone; 4.3.2 Conclusion; 4.4 Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph(3)PO/cumene hydroperoxide system; 4.4.1 Merits of the system; References; 5 Epoxidation of Allylic Alcohols5.1 Non-asymmetric epoxidation5.2 Asymmetric epoxidation using a chiral titanium complex; 5.2.1 Epoxidation of cinnamyl alcohol; 5.2.2 Epoxidation of (E)-2-methyl-3-phenyl-2-propenol; 5.2.3 Epoxidation of (E)-2-hexen-1-ol; 5.2.4 Conclusion; 5.3 Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate); 5.3.1 Synthesis of branched poly (octamethylene-L-(+)-tartrate); 5.3.2 Asymmetric epoxidation of (E)-undec-2-en-1-ol; References; 6 Epoxidation of Unfunctionalized Alkenes and a, b-Unsaturated Esters6.1 Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex6.1.1 Epoxidation of (Z)-methyl styrene; 6.1.2 Epoxidation of (Z)-ethyl cinnamate; 6.1.3 Conclusion; 6.2 Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst; 6.2.1 Epoxidation of (E)-stilbene; 6.2.2 Conclusion; 6.3 Enantioselective epoxidation of (E)-b-methylstyrene by D(2)-symmetric chiral trans-dioxoruthenium (VI) porphyrins; 6.3.1 Preparation of the trans-dioxoruthenium(VI) complexes with D(2)-symmetric porphyrins (H(2)L(1-3))6.3.2 Enantioselective epoxidation of (E)-b-methylstyrene6.3.3 Conclusion; References; 7 Asymmetric Hydroxylation and Aminohydroxylation; 7.1 Asymmetric aminohydroxylation of 4-methoxystyrene; 7.1.1 Conclusion; 7.2 Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile; 7.2.1 (R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide; 7.2.2 Conclusion; References; 8 Asymmetric Sulfoxidation; 8.1 Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides; 8.1.1 Asymmetric oxidation of 4-bromothioanisole; 8.1.2 Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide; References9 Asymmetric Reduction of Ketones Using Organometallic CatalystsCatalysts are increasingly used by chemists engaged in fine chemical synthesis within both industry and academia. Today, there exists a huge choice of high-tech catalysts, which add enormously to the repertoire of synthetic possibilities. However, catalysts are occasionally capricious, sometimes difficult to use and almost always require both skill and experience in order to achieve optimal results. This series aims to be a practical help for advanced undergraduate, graduate and postgraduate students, as well as experienced chemists in industry and academia working in organic and organometalliCatalysts for fine chemical synthesis ;v. 1.EnzymesBiotechnologyOrganic compoundsSynthesisHydrolysisOxidation-reduction reactionEnzymesBiotechnology.Organic compoundsSynthesis.Hydrolysis.Oxidation-reduction reaction.660.634660/.28443Roberts Stanley M754844Poignant Geraldine43932MiAaPQMiAaPQMiAaPQBOOK9910877844303321Hydrolysis, oxidation and reduction4191098UNINA