05124nam 2200637Ia 450 991087783400332120200520144314.01-282-02535-X97866120253583-527-62617-43-527-62618-2(CKB)1000000000707185(EBL)481835(OCoLC)352789988(SSID)ssj0000225331(PQKBManifestationID)11197655(PQKBTitleCode)TC0000225331(PQKBWorkID)10230334(PQKB)10174231(MiAaPQ)EBC481835(EXLCZ)99100000000070718520080227d2008 uy 0engur|n|---|||||txtccrThe power of functional resins in organic synthesis /edited by Judit Tulla-Puche and Fernando AlbericioWeinheim Wiley-VCHc20081 online resource (685 p.)Description based upon print version of record.3-527-31936-0 Includes bibliographical references and index.The Power of Functional Resins in Organic Synthesis; Contents; Preface; Part One: Introduction; 1: The (Classic Concept of) Solid Support; 1.1 Introduction; 1.2 Linkers/Handles; 1.3 Solid Supports; 1.3.1 Gel-Type Support; 1.3.1.1 Polystyrene (PS) Resins; 1.3.1.2 Poly(Ethylene Glycol)-Polystyrene (PEG-PS) Resins; 1.3.1.3 Hydrophilic PEG-Based Resins; 1.3.2 Modified Surface Type Supports; 1.3.2.1 Cellulose Membranes; 1.3.2.2 Polyolefinic Membranes; 1.3.2.3 Pellicular Solid Supports; Acknowledgments; References; 2: Molecularly Imprinted Polymers; 2.1 Introduction2.2 The Concept of Molecular Imprinting2.2.1 Non-covalent Molecular Imprinting; 2.2.2 Covalent Molecular Imprinting; 2.2.3 Semi-covalent Molecular Imprinting; 2.2.4 Metal Ion Mediated Molecular Imprinting; 2.3 Formats of Molecularly Imprinted Polymers; 2.3.1 Irregularly Shaped Particles; 2.3.2 Beads; 2.3.2.1 Homogeneous Polymerization; 2.3.2.2 Heterogeneous Polymerization; 2.3.2.3 Two-Step Swelling Polymerization; 2.3.2.4 Core-Shell Polymerization; 2.3.2.5 Silica Composite Beads; 2.3.3 Films and Membranes; 2.4 Design of MIPs; 2.4.1 Functional Monomers; 2.4.2 Cross-linking Monomers2.4.3 The Porogen2.4.4 Initiation of Polymerization; 2.4.5 Optimization of Imprinting Conditions; 2.5 Characterization of Molecularly Imprinted Polymers; 2.5.1 Characterization of Binding Properties of MIPs; 2.5.2 Characterization of Chemical and Physical Properties of MIPs; 2.6 Applications of Molecularly Imprinted Polymers; 2.6.1 Liquid Chromatography; 2.6.2 Solid-Phase Extraction; 2.6.3 Solid-Phase Binding Assay; 2.6.4 Sensors; 2.6.4.1 Optical Sensors; 2.6.4.2 Mass Sensitive Sensors; 2.6.4.3 Electrochemical Sensors; 2.6.5 Synthetic Enzymes; 2.7 Conclusions; References3: Nanoparticles Functionalized with Bioactive Molecules: Biomedical Applications3.1 Introduction; 3.2 MNPs; 3.2.1 Gold Nanoparticles; 3.2.1.1 Synthesis and Properties; 3.2.1.2 Functionalization of GNPs with Bioactive Compounds and Biomedical Applications of Functionalized GNPs; 3.2.2 Nanoshells and Metal Heterodimers; 3.2.3 Iron Oxide NPs; 3.2.3.1 Synthesis and Properties; 3.2.3.2 Functionalization of IONPs; 3.2.4 Silver NPs; 3.2.5 Quantum Dots; 3.2.6 Nanowires; 3.3 CNTs; 3.4 Organic Nanoparticles (ONPs); 3.4.1 Synthesis and Properties of ONPs; 3.4.2 Functionalization Strategies3.4.3 ONPs Types and Applications3.4.3.1 Fluorescent ONPs; 3.4.3.2 Cancer-Aimed ONPs; 3.4.3.3 Delivery of ONPs through the Blood-Brain Barrier (BBB); 3.4.3.4 Nucleic Acids/Gene Delivery; 3.4.3.5 Other Biomedical Uses of ONPs; 3.5 Conclusions; Acknowledgments; List of Abbreviations; References; Part Two: Solid-Supported Reagents and Scavengers; 4: Oxidizing and Reducing Agents; 4.1 Introduction; 4.2 Considerations Concerning the Nature of the Solid Support Used for Polymer-Supported Redox Reagents; 4.3 Oxidizing Resins; 4.3.1 Novel Oxidative Resins4.3.1.1 Solid-Supported Hypervalent Iodine ReagentsWhile many books cover solid phase synthesis and combinatorial synthesis, this one is unique in its exclusive coverage of the other aspects of solid-phase synthesis. As such, it contains everything you need to know -- from supported reagents, to scavengers, resins, and the synthesis of biomolecules and natural products.An invaluable companion for all chemists and biochemists working in university research and industry. Gums and resins, SyntheticOrganic compoundsSynthesisGums and resins, Synthetic.Organic compoundsSynthesis.547.2540sdnbVK 5500rvkAlbericio Fernando555734Tulla-Puche Judit1755944MiAaPQMiAaPQMiAaPQBOOK9910877834003321The power of functional resins in organic synthesis4192969UNINA