05336nam 2200649Ia 450 991087733130332120200520144314.01-282-30826-297866123082600-470-14531-50-470-14552-8(CKB)1000000000376311(EBL)468912(OCoLC)741345815(SSID)ssj0000299747(PQKBManifestationID)11204772(PQKBTitleCode)TC0000299747(PQKBWorkID)10241575(PQKB)10652817(MiAaPQ)EBC468912(EXLCZ)99100000000037631119931012d1993 uy 0engur|n|---|||||txtccrReactions catalyzed by inorganic compounds /founding editor J.J. Zuckerman; editor, Arlan D. NormanNew York VCHc19931 online resource (686 p.)Inorganic reactions and methods ;v. 16Description based upon print version of record.0-471-18666-X Includes bibliographical references and indexes.Inorganic Reactions and Methods; Contents; How to Use this book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 16; Reactions Catalyzed by Inorganic Compounds; Introduction: Principles of Catalysis; Catalysis as a Kinetic Phenomenon; Basic Processes in Molecular Catalysis; Electron Transfer; Ligand Dissociation and Association Processes; Heterolytic Ligand Dissociation.; Homolytic Ligand Dissociation.; Promotion of Nucleophilic Reactions by Electron Withdrawal from Reactants; Catalysis of Electrophilic Reactions by Proton Loss from a Coordinated LigandOxidative Addition/Reductive Elimination ReactionsOne-Electron Oxidative Addition.; Two-Electron Oxidative Addition.; Free Radical Chain Mechanism of Oxidative Addition.; Insertion Reactions; Types of Catalysts; Introduction; Solid Catalysts; Metallic Catalysts; Metal Crystals and Films.; Supported Metal Catalysts.; Metal Oxide and Metal Sulfide Catalysts; Soluble Catalysts; Selectivity Advantages; Process Engineering and Product Recovery Problems; Supported Metal Complexes; Polymeric Supports; Metal Oxide Supports; Phase Transfer Catalysis; Catalysis in Microscopic PhasesProduction of Catalysts and SupportsGeneral Principles; Methods of Production of Nonmetal Catalysts and Supports; Precipitation and Gel Formation.; Impregnation.; Natural Materials, Leaching, Carbon supports.; Methods of Production of Supported Metal Catalysts; Relationships between Catalyst Production and Performance; Hydrogenation Reactions; Introduction; Dihydrogen Activation; Homolytic Cleavage to Give Metal-Hydrides; Heterolytic Cleavage to Give Metal-Hydrides; Molecular Hydrogen Complexes; Classes of Soluble Catalysts; Rhodium(I) Catalysts; Cobalt Cyanide SystemsCobalt Carbonyl CatalystsChromium(0) Carbonyl Catalysts; Ziegler Catalysts; Ruthenium(lI) Catalysts; Hydrogenation of Aliphatic C-C Functions; In Simple Olefins; Isolated Double Bonds.; Olefins Conjugated to Carbonyl, Nitrile, Nitro.; Vinyl Functions.; In Conjugated Dienes; In Unconjugated Dienes; In Acetylenes and Cumulenes; In Triple Bonds.; In Allenes and Cumulenes.; By Asymmetric Hydrogenation; Hydrogenation of Arenes; By Cobalt Catalysts; By Ruthenium Catalysts; by Rhodium Catalysts; By Palladium and Platinum Catalysts; By Miscellaneous Catalysts; Hydrogenation of C=O FunctionsIn AldehydesSaturated Aliphatic Aldehydes.; Aromatic Aldehydes.; Selectivity.; In Ketones; Hydrogenation to the Carbinol.; Hydrogenolysis and Miscellaneous Reactions.; Selectivity.; Stereochemistry and Asymmetric Hydrogenation.; In Carboxyl Derivatives; By Transfer Hydrogenation; Hydrogenation of Other Functional Groups; Nitrites; Hydrogenation to Primary Amines.; Coupling Reactions.; Reductive Hydrolysis.; Hydrogenolysis and Cyclizations.; Nitro Compounds; Hydrogenation to the Amine.; Selective and Partial Reductions.; Side Reactions in Polyfunctional Molecules.; MiscellaneousAddition ReactionsFor the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research.The work is indexed in a unique way by a structured system which maximizes its useInorganic Reactions and MethodsCatalysisChemical reactionsCatalysis.Chemical reactions.541.3/9541.395Zuckerman J. J(Jerold J.),1936-1987.857123Norman Arlen D1343789MiAaPQMiAaPQMiAaPQBOOK9910877331303321Reactions catalyzed by inorganic compounds3068185UNINA