03911nam 22005413 450 991087711450332120240321080236.0978352782895135278289589783527828968352782896697835278289753527828974(MiAaPQ)EBC31214517(Au-PeEL)EBL31214517(CKB)30967958000041(Exl-AI)31214517(Perlego)4363678(OCoLC)1427666156(EXLCZ)993096795800004120240321d2024 uy 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierMechanically Interlocked Materials Polymers, Nanomaterials, MOFs, and More1st ed.Newark :John Wiley & Sons, Incorporated,2024.©2024.1 online resource (300 pages)9783527347933 3527347933 Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Force‐Promoted Transformations in Mechanically Linked Molecules -- 1.1 Introduction -- 1.2 SMFS in the Study of Non‐covalent Interactions -- 1.2.1 Rotaxanes -- 1.2.2 Poly‐(pseudo)rotaxanes -- 1.2.3 Catenanes -- 1.3 Strength of Mechanical Bonds -- 1.3.1 Polymers Containing a Rotaxane -- 1.3.2 Polymers Containing a Catenane -- 1.4 Changes in Optical Properties – Reversible and Irreversible Changes of Optical Properties by Movement of Macrocycle in a Rotaxane -- 1.5 Conclusions -- References -- Chapter 2 Colloidal Nanomaterials with Mechanically Interlocked Parts -- 2.1 Introduction -- 2.2 Installing and Actuating Mechanically Interlocked Molecular Architectures at Colloidal Nanoparticle Surfaces -- 2.3 Modulating Nanoparticle Physicochemical Properties Using Switchable Mechanically Interlocked Architectures -- 2.4 Interlocked Gates for Nanoparticle Pores: From Cargo Release to Nanoscale Communication -- 2.4.1 Optimizing Mechanisms for Cargo Release -- 2.4.2 Autonomous Drug Delivery Triggered By Endogenous Conditions -- 2.4.3 Cargo Release Using Tissue‐Penetrating External Triggers -- 2.4.4 Nanoscale Communication Between Responsive Nanoparticles -- 2.5 Mechanically Interlocked Molecular Links for Nanoparticle Assemblies -- 2.5.1 Pseudorotaxane‐linked Nanoparticle Assembly–Disassembly -- 2.5.2 Fully Interlocked Molecular Links for Nanoparticle Assemblies -- 2.6 From Switches to Motors and Beyond: The Future of Colloidal Nanomaterials with Mechanically Interlocked PartsGenerated by AI.This book, edited by Emilio M. Pérez, explores the field of mechanically interlocked molecules (MIMs) and their applications in materials science. It covers a variety of topics including the synthesis and properties of rotaxanes and catenanes, the interaction of MIMs with metal-organic frameworks (MOFs), and their use in molecular motors and nanotubes. The book also delves into the creation and utility of DNA-based interlocked structures, as well as synthetic mechanically interlocked polymers. Targeting researchers and professionals in chemistry and materials science, the book aims to provide an in-depth understanding of the dynamic mechanical properties of MIMs and their potential to advance technology in diverse fields.Generated by AI.Molecular machineryGenerated by AIMetal-organic frameworksGenerated by AIMolecular machineryMetal-organic frameworks547.1226Pérez Emilio M1762114MiAaPQMiAaPQMiAaPQBOOK9910877114503321Mechanically Interlocked Materials4201858UNINA