05364nam 2200649Ia 450 991087663530332120200520144314.01-282-68623-297866126862383-527-62840-13-527-62378-7(CKB)1000000000707864(EBL)481468(OCoLC)316803727(SSID)ssj0000168330(PQKBManifestationID)11184183(PQKBTitleCode)TC0000168330(PQKBWorkID)10192045(PQKB)11776905(MiAaPQ)EBC481468(PPN)152354220(EXLCZ)99100000000070786420080625d2009 uy 0engur|n|---|||||txtccrHandbook of ring-opening polymerization /edited by Philippe Dubois, Olivier Coulembier, and Jean-Marie RaquezWeinheim Wiley-VCHc20091 online resource (428 p.)Description based upon print version of record.3-527-31953-0 Includes bibliographical references and index.Handbook of Ring-Opening Polymerization; Contents; Preface; List of Contributors; 1: Thermodynamics and Kinetics of Ring-Opening Polymerization; 1.1 Introduction; 1.2 Thermodynamics of the Ring-Opening Polymerization; 1.2.1 Equilibrium Monomer Concentration: Ceiling/Floor Temperatures; 1.2.2 Selected Particular Cases; 1.2.2.1 Polymerization in Heterogeneous Systems; 1.2.2.2 Monomer-Polymer-Solvent Interactions; 1.2.2.3 Thermodynamics of Oligomerization; 1.2.3 Thermodynamics of Macrocyclization; 1.2.4 Equilibrium Copolymerization; 1.2.5 Molar Mass Distribution in the Equilibrium Polymerization1.3 Kinetics of Ring-Opening Polymerization1.3.1 Thermodynamic and Kinetic Polymerizability; 1.3.2 Kinetics of Living Polymerization; 1.3.2.1 Kinetic Criteria of Living Polymerization; 1.3.2.2 Active Center Interconversions and the Determination of Absolute Rate Constants; 1.3.2.3 Departure from Livingness: Kinetics of Selected Side Reactions; 1.3.2.4 Kinetics of Copolymerization; 1.4 Concluding Remarks; References; 2: General Mechanisms in Ring-Opening Polymerization; 2.1 Introduction; 2.2 Anionic Ring-Opening Polymerization; 2.2.1 General Mechanism; 2.2.2 Activated Monomer Mechanism2.3 Cationic Ring-Opening Polymerization2.3.1 General Mechanism; 2.3.2 Activated Monomer Mechanism; 2.3.3 Isomerization Polymerization; 2.4 Radical Ring-Opening Polymerization; 2.5 Summary and Prospects; References; 3: Siloxane-Containing Polymers; 3.1 Introduction; 3.2 Polydimethylsiloxanes; 3.2.1 Anionic Polymerization; 3.2.1.1 General Considerations; 3.2.1.2 Recent Advances; 3.2.2 Cationic Polymerization; 3.2.2.1 General Considerations; 3.2.2.2 Recent Advances; 3.2.3 Emulsion Polymerization; 3.2.3.1 General Considerations; 3.2.3.2 Recent Advances; 3.2.4 Other Processes3.3 Functional Silicones3.3.1 Anionic Polymerization; 3.3.1.1 Homopolymerization of Symmetrical Cyclosiloxanes; 3.3.1.2 Homopolymerization of Asymmetrical Cyclosiloxanes; 3.3.1.3 Copolymerization; 3.3.2 Cationic Polymerization; 3.3.2.1 Homopolymerization of Symmetrical Cyclosiloxanes; 3.3.2.2 Homopolymerization of Asymmetrical Cyclosiloxanes; 3.3.2.3 Copolymerization; 3.3.3 Emulsion Polymerization; 3.4 Polycarbosiloxanes; 3.4.1 Five-Atom Rings; 3.4.2 Larger Cyclocarbosiloxanes; 3.5 Summary and Prospects; Acknowledgments; References; 4: Sulfur-Nitrogen-Phosphorus-Containing Polymers4.1 Introduction4.2 Mechanism and Methods in Ring-Opening Polymerization (ROP) of Halogenated Cyclotriphosphazenes; 4.3 Ring-Opening Polymerization and Chemistry of Nonhalogenated Phosphazene Rings; 4.4 Incorporation of Sulfur into Phosphazene Ring Systems, and Their Polymerization Chemistry; 4.4.1 Thiophosphazenes; 4.4.2 Thionylphosphazenes; 4.5 Summary and Prospects; Acknowledgments; References; 5: Polymerization of Cyclic Depsipeptides, Ureas and Urethanes; 5.1 Introduction; 5.2 Polydepsipeptides; 5.3 Monomers; 5.4 Ring-Opening Polymerization; 5.5 Enzymatic Polymerization5.6 Ring ExpansionThis comprehensive, truly one-stop reference discusses monomers, methods, stereochemistry, industrial applications and more. Chapters written by internationally acclaimed experts in their respective fields cover both basic principles and up-to-date information, ranging from the controlled ring-opening polymerization methods to polymer materials of industrial interest. All main classes of monomers including heterocyclics, cyclic olefins and alkynes, and cycloalkanes, are discussed separately as well as their specificities regarding the ring-opening polymerization techniques, the mechanisms, theRing-opening polymerizationHandbooks, manuals, etcPolymersRing-opening polymerizationPolymers.547.28547.7Dubois PhilippeProf.91900Coulembier Olivier1752757Raquez Jean-Marie1752758MiAaPQMiAaPQMiAaPQBOOK9910876635303321Handbook of ring-opening polymerization4188149UNINA