05196nam 2200637Ia 450 991082986350332120230421044556.01-281-75857-497866117585783-527-61517-23-527-61516-4(CKB)1000000000376621(EBL)482005(OCoLC)261225144(SSID)ssj0000096914(PQKBManifestationID)11116484(PQKBTitleCode)TC0000096914(PQKBWorkID)10113124(PQKB)10421445(MiAaPQ)EBC482005(EXLCZ)99100000000037662119951010d1996 uy 0engur|n|---|||||txtccrActive metals[electronic resource] preparation, characterization, applications /edited by Alois FürstnerWeinheim ;New York VCHc19961 online resource (486 p.)Description based upon print version of record.3-527-29207-1 Includes bibliographical references and indexes.Active Metals; Preface; Contents; List of Contributors; 1 Rieke Metals : Highly Reactive Metal Powders Prepared by Alkali Metal Reduction of Metal Salts; 1.1 Introduction; 1.1.1 Physical Characteristics of Highly Reactive Metal Powders; 1.2 Rieke Magnesium, Calcium, Strontium, and Barium; 1.2.1 Formation of Rieke Magnesium; 1.2.2 Formation of Rieke Calcium. Strontium. and Barium; 1.2.3 Grignard Reactions Using Rieke Metals; 1.2.4 1,3-Dicne-Magnesium Reagents; 1.2.4.1 Preparation; 1.2. 4.2 Regioselcctivity1.2.4.3 Carbocyclization of (1.4-Diphenyl-2-butene-1,4-diyl)magnesium with Organic Dihalides1.2.4.4 1,2-Dimethylenecycloalkan e.Magnesium Reagents; 1.2.4.5 Synthesis of Fused Carbocycles, β, γ-Unsaturated Ketones and 3-Cyclopentenols from Conjugated Diene-Magnesium Reagents; 1.2.4.6 Synthesis of Spiro γ-Lactones and Spiro δ-Lactones from 1,3-Diene-Magnesium Reagents; 1.2.4.7 Synthesis of γ-Lactams from Conjugated Diene-Magnesium Reagents; 1.3 Rieke Zinc; 1.3.1 The Preparation of Rieke Zinc; 1.3.2 Direct Oxidative Addition of Functionalized Alkyl and Aryl Halides1.3.3 Reactions of Organozinc Reagents with Acid Chlorides1.3.4 Reactions of Organozinc Reagents with α, β-Unsaturated Ketones; 1.3.5 Reactions with Allylic and Alkynyl Halides; 1.3.6 Cross-Coupling of Vinyl and Aryl Organozinc Reagents Using a Palladium Catalyst; 1.3.7 Intramolecular Cyclizations and Conjugate Additions Mediated by Rieke Zinc; 1.3.8 Formation of Tertiary and Secondary Alkylzinc Bromides; 1.3.9 Cyanide-Based Rieke Zinc; 1.4 Organocopper Reagents Utilizing Rieke Copper; 1.4.1 Introduction; 1.4.2 Background to the Development of Rieke Copper; 1.4.3 Phosphine-Based Copper1.4.4 Lithium 2-Thienylcyanocuprate-Based Copper1.4.5 Copper Cyanide-Based Active Copper; 1.4.6 Two-Equivalent Reduction of Copper(I) Complexes : A Formal Copper Anion; 1.5 Rieke Aluminum, Indium, and Nickel; 1.5.1 Aluminum; 1.5.2 Indium; 1 5.3 Nickel; 1.6 Synthesis of Specialized Polymers and New Materials via Rieke Metals; 1.6.1 Formation of Polyarylenes Mediated by Rieke Zinc; 1.6.2 Regiocontrolled Synthesis of Poly(3-alkylthiophenes) and Related Polymers Mediated by Rieke Zinc; 1.6.3 Synthesis of Poly(phenylcarbyne) Mediated by Rieke Calcium, Strontium, or Barium1.6.4 Chemical Modification of Halogenated Polystyrenes Using Rieke Calcium or Copper1.6.5 Polymer Supported Rieke Metal Reagents and their Applications in Organic Synthesis; 2 Allylic Barium Reagents; 2.1 Introduction; 2.2 Preparation of Stereochemically Homogeneous Allylic Barium Reagents; 2.2.1 Direct Insertion Method Using Reactive Barium; 2.2.2 Stereochemical Stability; 2.2.3 Silylation of Stereochemically Homogeneous Allylic Barium Reagents; 2.2.3.1 Procedure for Generation of Reactive Barium (Ba*); 2.2.3.2 Procedure for Protonation of the Geranyl Barium Reagent2.2.3.3 Silylation of (E)-2-Decenylbarium ChlorideReactions with metals are ubiquitous in organic synthesis and, particularly in the last few years, a large repertoire of methods for the activation of metals and for their use in organic synthesis has been developed. In Active Metals, topics ranging from morphology of metal clusters and nanometallurgy to organometallic chemistry, catalysis and the use of activated metals in natural product synthesis are authoritatively discussed by leading experts in the field.Active Metals will allow you to fully benefit from the recent advances in the field by giving:* Detailed experimental pMetal activationActive metalsOrganometallic compoundsSynthesisMetal activation.Active metals.Organometallic compoundsSynthesis.546.3547.05Fürstner Alois945461MiAaPQMiAaPQMiAaPQBOOK9910829863503321Active metals2134486UNINA04464nam 22007215 450 991086419630332120250807135627.03-031-55960-610.1007/978-3-031-55960-0(MiAaPQ)EBC31353577(Au-PeEL)EBL31353577(CKB)32145928700041(MiAaPQ)EBC31355795(Au-PeEL)EBL31355795(DE-He213)978-3-031-55960-0(EXLCZ)993214592870004120240523d2024 u| 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierAutomatic Control with Experiments /by Victor Manuel Hernández-Guzmán, Ramón Silva-Ortigoza, Jorge Alberto Orrante-Sakanassi2nd ed. 2024.Cham :Springer International Publishing :Imprint: Springer,2024.1 online resource (987 pages)Advanced Textbooks in Control and Signal Processing,2510-38143-031-55959-2 Introduction -- Linear ordinary differential equations -- Basic tools for arbitrary order systems -- Time response-based design -- Frequency response-based design -- The state variables approach -- Advanced topics in control -- Discrete-time systems -- Control of PM brushed DC-motor -- Control of a ball and beam system -- Control of a magnetic levitation system -- Control of Pendubot -- Tilt angle estimation -- Control of wheeled pendulum -- Control of mechanical systems with flexibility -- Control of DC/DC power electronic converters.This book offers an enhanced and comprehensive understanding of control theory and its practical applications. The theoretical chapters on control tools have been meticulously revised and improved to provide a clearer and more insightful exploration of the fundamental concepts and ideas. The explanations have been refined, and new examples have been added to aid comprehension. Additionally, a new chapter on discrete-time systems has been included, delving into an important aspect of control theory. Advanced topics in control are also covered in greater detail, ensuring a comprehensive treatment of the subject matter. The section on experimental applications has been revamped to showcase the application of control ideas in various scenarios. Several chapters have been replaced with fresh content that focuses on controlling new and different experimental prototypes. These examples illustrate how control concepts can be effectively applied in real-world situations. Furthermore, this book introduces a new approach for control of non-minimum phase systems and explores the concept of differential flatness for multiple-input multiple-output systems. Additionally, a fascinating application involving a wheeled pendulum mobile robot has been included. While some chapters have been replaced, the second edition retains the chapters on the control of DC motors and the control of a magnetic levitation system. However, the material in the former chapter is mostly new, and the latter chapter is entirely supported by new control concepts and ideas.Advanced Textbooks in Control and Signal Processing,2510-3814Automatic controlSystem theoryControl theoryElectric power productionIndustrial engineeringProduction engineeringControl and Systems TheorySystems Theory, ControlElectrical Power EngineeringIndustrial and Production EngineeringAutomatic control.System theory.Control theory.Electric power production.Industrial engineering.Production engineering.Control and Systems Theory.Systems Theory, Control.Electrical Power Engineering.Industrial and Production Engineering.629.8312003Hernández-Guzmán Victor Manuel1224747Silva-Ortigoza Ramón770965Orrante-Sakanassi Jorge Alberto1741036MiAaPQMiAaPQMiAaPQBOOK9910864196303321Automatic Control with Experiments4166960UNINA