05339nam 2200673Ia 450 991084153620332120220119105907.01-280-54177-61-280-44861-X97866104486160-470-23187-40-471-79030-30-471-79029-X(CKB)1000000000355432(EBL)257567(OCoLC)71625321(SSID)ssj0000103043(PQKBManifestationID)11127536(PQKBTitleCode)TC0000103043(PQKBWorkID)10060817(PQKB)10741551(MiAaPQ)EBC257567(PPN)23192951X(EXLCZ)99100000000035543220050927d2006 uy 0engur|n|---|||||txtccrAnalytical electrochemistry[electronic resource] /Joseph Wang3rd ed.Hoboken, NJ Wiley-VCHc20061 online resource (268 p.)Description based upon print version of record.0-471-46079-6 0-471-67879-1 Includes bibliographical references and index.ANALYTICAL ELECTROCHEMISTRY; CONTENTS; Preface; Abbreviations and Symbols; 1 Fundamental Concepts; 1.1 Why Electroanalysis?; 1.2 Faradaic Processes; 1.2.1 Mass-Transport-Controlled Reactions; 1.2.1.1 Potential-Step Experiment; 1.2.1.2 Potential-Sweep Experiments; 1.2.2 Reactions Controlled by the Rate of Electron Transfer; 1.2.2.1 Activated Complex Theory; 1.3 Electrical Double Layer; 1.4 Electrocapillary Effect; 1.5 Supplementary Reading; Problems; References; 2 Study of Electrode Reactions and Interfacial Properties; 2.1 Cyclic Voltammetry; 2.1.1 Data Interpretation2.1.1.1 Reversible Systems2.1.1.2 Irreversible and Quasi-reversible Systems; 2.1.2 Study of Reaction Mechanisms; 2.1.3 Study of Adsorption Processes; 2.1.4 Quantitative Applications; 2.2 Spectroelectrochemistry; 2.2.1 Experimental Arrangement; 2.2.2 Principles and Applications; 2.2.3 Electrochemiluminescence; 2.2.4 Optical Probing of Electrode-Solution Interfaces; 2.3 Scanning Probe Microscopy; 2.3.1 Scanning Tunneling Microscopy; 2.3.2 Atomic Force Microscopy; 2.3.3 Scanning Electrochemical Microscopy; 2.4 Electrochemical Quartz Crystal Microbalance; 2.5 Impedance Spectroscopy; ExamplesProblemsReferences; 3 Controlled-Potential Techniques; 3.1 Chronoamperometry; 3.2 Polarography; 3.3 Pulse Voltammetry; 3.3.1 Normal-Pulse Voltammetry; 3.3.2 Differential-Pulse Voltammetry; 3.3.3 Square-Wave Voltammetry; 3.3.4 Staircase Voltammetry; 3.4 AC Voltammetry; 3.5 Stripping Analysis; 3.5.1 Anodic Stripping Voltammetry; 3.5.2 Potentiometric Stripping Analysis; 3.5.3 Adsorptive Stripping Voltammetry and Potentiometry; 3.5.4 Cathodic Stripping Voltammetry; 3.5.5 Abrasive Stripping Voltammetry; 3.5.6 Applications; 3.6 Flow Analysis; 3.6.1 Principles; 3.6.2 Cell Design3.6.3 Mass Transport and Current Response3.6.4 Detection Modes; Examples; Problems; References; 4 Practical Considerations; 4.1 Electrochemical Cells; 4.2 Solvents and Supporting Electrolytes; 4.3 Oxygen Removal; 4.4 Instrumentation; 4.5 Working Electrodes; 4.5.1 Mercury Electrodes; 4.5.2 Solid Electrodes; 4.5.2.1 Rotating Disk and Rotating Ring Disk Electrodes; 4.5.2.2 Carbon Electrodes; 4.5.2.2.1 Glassy Carbon Electrodes; 4.5.2.2.2 Carbon Paste Electrodes; 4.5.2.2.3 Carbon Fiber Electrodes; 4.5.2.2.4 Diamond Electrodes; 4.5.2.3 Metal Electrodes; 4.5.3 Chemically Modified Electrodes4.5.3.1 Self-Assembled Monolayers4.5.3.2 Carbon-Nanotube-Modified Electrodes; 4.5.3.3 Sol-gel Encapsulation of Reactive Species; 4.5.3.4 Electrocatalytically Modified Electrodes; 4.5.3.5 Preconcentrating Electrodes; 4.5.3.6 Permselective Coatings; 4.5.3.7 Conducting Polymers; 4.5.4 Microelectrodes; 4.5.4.1 Diffusion at Microelectrodes; 4.5.4.2 Microelectrode Configurations; 4.5.4.3 Composite Electrodes; Examples; Problems; References; 5 Potentiometry; 5.1 Principles of Potentiometric Measurements; 5.2 Ion-Selective Electrodes; 5.2.1 Glass Electrodes; 5.2.1.1 pH Electrodes5.2.1.2 Glass Electrodes for Other CationsThird Edition covers the latest advances in methodologies, sensors, detectors, and mIcrochipsThe greatly expanded Third Edition of this internationally respected text continues to provide readers with a complete panorama of electroanalytical techniques and devices, offering a balancebetween voltammetric and potentiometric techniques. Emphasizing electroanalysis rather than physical electrochemistry, readers gain a deep understanding of the fundamentals of electrodereactions and electrochemical methods. Moreover, readers learn to apply their newfoundknowledge and skills to solve reaElectrochemical analysisChemistry, AnalyticQuantitativeElectrochemical analysis.Chemistry, AnalyticQuantitative.543.4543/.4Wang Joseph1948-1608845MiAaPQMiAaPQMiAaPQBOOK9910841536203321Analytical electrochemistry4138020UNINA