05237nam 2200673Ia 450 991084134880332120230721022543.01-282-68358-697866126835893-527-62705-73-527-62706-5(CKB)1000000000790149(EBL)481402(SSID)ssj0000335699(PQKBManifestationID)11273394(PQKBTitleCode)TC0000335699(PQKBWorkID)10276897(PQKB)11181664(MiAaPQ)EBC481402(OCoLC)705353464(EXLCZ)99100000000079014920011031d2009 uy 0engur|n|---|||||txtccrChemically modified electrodes[electronic resource] /edited by Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, and Philip N. RossWeinheim Wiley-VCHc20091 online resource (281 p.)Advances in electrochemical science and engineering ;11Description based upon print version of record.3-527-31420-2 Includes bibliographical references and index.Advances in Electrochemical Science and Engineering; Contents; Preface; List of Contributors; 1 Nanostructured Electrodes with Unique Properties for Biological and Other Applications; 1.1 Introduction; 1.2 High Surface Area Electrodes; 1.2.1 Attachment of Nanoparticles onto Electrodes; 1.2.2 Templating using Membranes; 1.2.3 Templating using Lyotropic Liquid Crystals; 1.2.4 Colloidal Templates; 1.3 Catalytic Properties; 1.4 Exploiting Nanoscale Control to Interface Electrodes with Biomolecules; 1.4.1 Plugging Nanomaterials into Proteins - Nanoparticles1.4.2 Plugging Nanomaterials into Proteins - Carbon Nanotubes1.4.3 Plugging Nanomaterials into Proteins - Molecular Wires; 1.4.3.1 Nanostructuring Electrodes to Achieve Intimate Connectivity with Biomolecules; 1.4.3.2 Nanostructuring Electrodes using Rigid Molecules; 1.4.3.3 The use of Molecular Wires in Electrochemistry such that Long-Distance Electron Transfer can be Exploited for a Variety of Applications; 1.5 Switchable Surfaces; 1.5.1 Switching Properties of Monolayer Systems; 1.5.2 Control and Enhancement of Electrochemical Reactions using Magnetic Nanostructures on Electrodes1.6 ConclusionsReferences; 2 Electrochemically Active Polyelectrolyte-Modified Electrodes; 2.1 Introduction; 2.1.1 Chemically Modified Electrodes; 2.1.2 Redox Hydrogels; 2.1.3 Redox Polyelectrolyte Monolayers; 2.1.4 Redox Polymer Brushes and Grafted DNA; 2.1.5 Layer-by-Layer Polyelectrolyte Multilayers; 2.2 Structure; 2.2.1 Polyelectrolye Interpenetration; 2.2.2 Compensation of Polyelectrolyte Charges; 2.2.3 Film Inner Structure; 2.2.4 Effect of the Assembly pH; 2.2.5 Theoretical Description; 2.3 Electrochemical Response; 2.3.1 Ideal Response; 2.3.2 Peak Position and Donnan Potential2.3.3 Coupling Between the Acid-Base and Redox Equilibria2.3.4 Peak Width; 2.3.5 Nonreversible Electrochemistry: Charge Transport; 2.4 Dynamics of Solvent and Ion Exchange; 2.4.1 Ion Exchange; 2.4.2 Solvent Exchange; 2.4.3 Specific Ionic Effects; 2.4.4 Break-In; 2.5 Molecular Description of Redox Polyelectrolyte-Modified Electrodes; 2.5.1 Formulation of the Molecular Theory; 2.5.2 Comparison with Phenomenological Models, Advantages and Limitations; 2.6 Applications; 2.6.1 Amperometric Enzymatic Electrodes; 2.6.2 Electrochromic Devices; 2.7 Conclusions; References3 Electrochemistry on Carbon-Nanotube-Modified Surfaces3.1 Introduction; 3.2 Structure and Properties of Carbon Nanotubes; 3.2.1 Structure and Electronic Properties; 3.2.2 Chemical Properties; 3.2.3 Electrochemical Properties; 3.3 Towards the Design of CNT-Modified Electrodes; 3.3.1 Synthesis of CNTs; 3.3.2 CNT Purification Methods; 3.3.3 Chemical and Biochemical Functionalization; 3.3.3.1 Covalent Modification; 3.3.3.2 Noncovalent Modification; 3.3.3.3 Chemical Modification for CNT Sorting; 3.3.3.4 Chemical Doping, Intercalation and Artificial Defects3.3.4 CNT Deposition on Electrode SurfacesWith contributions from an international group of expert authors, this book includes the latest trends in tailoring interfacial properties electrochemically. The chapters cover various organic and inorganic compounds, with applications ranging from electrochemistry to nanotechnology and biology.Of interest to physical, surface and electrochemists, materials scientists and physicists.Advances in electrochemical science and engineering ;11.ElectrodesElectrochemistryElectrodes.Electrochemistry.541.3724660.297Alkire R. C.1941-1278456Kolb Dieter M884241Lipkowski Jacek1613178Ross P. N(Philip N.)92313MiAaPQMiAaPQMiAaPQBOOK9910841348803321Chemically modified electrodes4144422UNINA