05249nam 2200649Ia 450 991084055840332120170810194951.01-280-52119-897866105211973-527-60661-03-527-60689-0(CKB)1000000000377554(EBL)481986(OCoLC)70114872(SSID)ssj0000167298(PQKBManifestationID)11163657(PQKBTitleCode)TC0000167298(PQKBWorkID)10169082(PQKB)11759175(MiAaPQ)EBC481986(PPN)249486733(EXLCZ)99100000000037755420040717d2005 uy 0engur|n|---|||||txtccrHandbook of condensation thermoplastic elastomers[electronic resource] /Stokyo FakirovWeinheim ;[Great Britain] Wiley-VCH20051 online resource (645 p.)Description based upon print version of record.3-527-30976-4 Includes bibliographical references and index.Handbook of Condensation Thermoplastic Elastomer; Preface; Contents; Contributors; PART I INTRODUCTION; Chapter 1 Creation and Development of Thermoplastic Elastomers, and Their Position Among Organic Materials; 1. Birth and development of TPEs: a brief survey; 2. Main routes to thermoplastic elastomer preparation; 2.1. Living anionic polymerization; 2.2. Living cationic polymerization; 2.3. Controlled radical polymerization; 2.4. Polycondensation and polyaddition; 2.5. Chemical modification and grafting; 2.6. Preparation by blending; 2.7. Preparation by dynamic vulcanization3. Techniques used in the characterization of TPEs3.1. Chromatography; 3.2. Spectrometric techniques; 3.3. Scattering techniques; 3.4. Microscopies; 3.5. Controlled degradation; 3.6. Thermal techniques; 4. Properties and processing of TPEs; 4.1. Injection molding; 4.2. Compression molding; 4.3. Extrusion; 4.4. Blow processings; 4.5. Thermoforming; 4.6. Reactive processings; 4.7. Degradation in processing; 5. Position of TPEs among organic materials and their applications; 6. Future trends; ReferencesChapter 2 Polycondensation Reactions in Thermoplastic Elastomer Chemistry: State of the Art, Trends, and Future Developments1. Introduction; 2. Preparation of block copolymers by polycondensation. A critical review; 2.1. General considerations; 2.2. Direct polycondensation of α,ω-difunctional oligomers; 2.3. Polycondensation of an α,ω-difunctional oligomer with the precursors of another block; 2.4. Oligomer-coupling reactions; 2.5. Characterization techniques. Side reactions; 3. New structures; 3.1. Block copolymers containing liquid crystalline structures3.2. Liquid crystalline sequences as part of the backbone3.3. Liquid crystalline sequences as side chains; 3.4. Metallo-supramolecular block copolymers; 3.5. Block copolymers prepared from metal-containing macrocycles; 3.6. The use of microorganisms; 4. Conclusions; References; PART II POLYESTER-BASED THERMOPLASTIC ELASTOMERS; Chapter 3 Polyester Thermoplastic Elastomers: Synthesis, Properties, and Some Applications; 1. Introduction; 2. Chemical structure of polyester elastomers; 3. Poly(alkylene oxide) flexible segment-based polyester elastomers4. Modified poly(butylene terephthalate) rigid segment-based polyester elastomers5. Branched polyester elastomers; 6. Synthesis of poly(ether ester) block copolymers; 7. Other multiblock polyester elastomers; 8. Polyester thermoplastic elastomers from blends; 9. A new processing aspect: weldability of polyester elastomers; 10. Polyester elastomers for biomedical application; 11. Conclusions and outlook; References; Chapter 4 Terpoly(Ester-b-Ether-b-Amide) Thermoplastic Elastomers: Synthesis, Structure, and Properties; 1. Introduction; 2. Chemical structure of terpoly(ester-b-ether-b-amide)s3. Synthesis of triblock -(GT-b-PO4-b-PA)(n)- polymersReporting on the work of an international team of scientists actively involved in the study of thermoplastic elastomers (TPE) based on polyesters, polyamides, and polyurethanes, this book is the first to provide a detailed description of condensation TPE with close attention paid to polyamide-based systems. Reflecting the increasing importance of TPE as engineering plastics, the authors discuss the widened application opportunities by preparing systems with various chemical compositions and molecular structures as (semi-) interpenetrating networks. The contents also cover the chemical aspects,ElastomersThermoplasticsCondensation products (Chemistry)Elastomers.Thermoplastics.Condensation products (Chemistry)620.194Fakirov Stoyko1727551Fakirov Stoyko1727551MiAaPQMiAaPQMiAaPQBOOK9910840558403321Handbook of condensation thermoplastic elastomers4134918UNINA