05179nam 2200637Ia 450 991083117740332120170809164509.01-281-76401-997866117640123-527-61296-33-527-61297-1(CKB)1000000000294602(EBL)481844(OCoLC)261223015(SSID)ssj0000155232(PQKBManifestationID)11149802(PQKBTitleCode)TC0000155232(PQKBWorkID)10098432(PQKB)11775606(MiAaPQ)EBC481844(PPN)242599362(EXLCZ)99100000000029460220010822e20022001 uy 0engur|n|---|||||txtccrFine chemicals through heterogenous catalysis[electronic resource] /Roger Arthur Sheldon, Hermann van BekkumWeinheim ;Toronto Wiley-VCH2002, c20011 online resource (639 p.)Description based upon print version of record.3-527-29951-3 Includes bibliographical references and index.Fine Chemicals through Heterogeneous Catalysis; Contents; 1 Introduction; 1.1 What are Fine Chemicals?; 1.2 The Environmental Factor; 1.3 The Development of Organic Synthesis and Catalysis; 1.4 Why Heterogeneous Catalysis?; 1.5 Types of Catalysts and Reactions; 1.5.1 Solid-Acid Catalysis; 1.5.2 Solid-Base Catalysis; 1.5.3 Catalytic Hydrogenation; 1.5.4 Catalytic Oxidations; 1.5.5 Catalytic C-C Bond Formation; 1.6 Alternative Approaches; 1.7 Heterogeneous Catalysis in Multi-step Synthesis: Vanillin; 2 Basic Principles/General; 2.1 General Considerations and Types of Catalyst2.1.1 Introduction2.1.2 Catalytically Active Surface Area; 2.1.3 Reactors Employed in the Fine-chemical Industry; 2.1.4 Slurry-phase Catalysts; 2.1.5 Fixed-bed Catalysts; 2.1.6 Integration of the Catalyst and the Reactor; 2.1.7 Solid Catalysts Employed in the Fine-chemical Industry; 2.1.8 Metal Catalysts; 2.1.9 Solid-Acid Catalysts; 2.2 Preparation of Solid Catalysts; 2.2.1 Demands on Solid Catalysts; 2.2.2 Preparation Procedures [2]; 2.2.3 Conclusions; 2.3 Characterization of Solid Catalysts; 2.3.1 Total Surface Area and Pore-size Distribution2.3.2 Catalytically Active Surface Area Per Unit Weight of Catalyst2.3.3 Extent of Reduction of Metal Catalysts; 2.3.4 Solid-acid Catalysts; 2.3.5 Dispersion of Active Component(s) Over the Support; 2.3.6 Conclusions; 2.4 Reactors; 2.4.1 Introduction; 2.4.2 Three-phase Catalytic Reactions (G-L-S); 2.4.3 Characteristics of Three-phase Catalytic Reactors for Fine-chemicals Production; 2.4.3.1 Reactors with Moving Catalyst; 2.4.3.2 Reactors with a Fixed Bed of Catalyst; 2.4.3.3 Comparison-Reactor Choice; 2.4.4 Design Aspects of Stirred Tank Batch Reactor2.4.5 Scale-up of Stirred-Tank Batch Reactors-Runaway Reactions3 Solid-acid Catalysts-General; 3.1 Acidic Clays; 3.1.1 Introduction; 3.1.2 Structure; 3.1.3 Main Properties and Catalytic Applications; 3.1.4 Pillared Interlayer Clays (PILC); 3.1.5 Conclusions; 3.2 Zeolites as Catalysts; 3.2.1 Introduction; 3.2.2 Acid Zeolites; 3.2.2.1 Framework Composition; 3.2.2.2 Extra-framework Composition; 3.2.3 Basicity in Zeolites; 3.2.3.1 Basic Zeolites-Framework Composition; 3.2.3.2 Basic Zeolites-Extra-framework Composition; 3.2.4 Redox Molecular Sieves; 3.2.4.1 Oxidation Sites in Framework Positions3.2.4.2 Oxidation Sites in Extra-framework Positions3.2.5 Conclusions; 3.3 Sulfonated Polysiloxanes; 3.3.1 Motivation and Expected Advantages; 3.3.2 Synthetic Approaches; 3.3.2.1 Grafting of Silanes to Silica; 3.3.2.2 Copolycondensation and Sol-Gel Processing; 3.3.2.3 Sulfonation of Arylsiloxanes; 3.3.2.4 Oxidation of Sulfur-functionalized Siloxanes; 3.3.3 Characterization of the Polysiloxanes; 3.3.3.1 General; 3.3.3.2 Analytical Determination of Capacity; 3.3.3.3 NMR Spectroscopy; 3.3.3.4 Thermal Stability; 3.3.4 Applications and Reactions; 3.3.5 Summary; 3.4 Silica-occluded Heteropolyacids3.4.1 IntroductionNowadays, the chemical industry is under increased pressure to develop cleaner production processes and technologies. Much effort is devoted to the development of heterogeneous catalysts and their application in industrial-scale organic synthesis. This handbook concentrates on current attempts, focusing on fine chemical production.With contributions from an impressive array of international experts, this is essential reading for everyone interested in the advances in this field.Heterogeneous catalysisOrganic compoundsSynthesisHeterogeneous catalysis.Organic compoundsSynthesis.541.395660.2995Sheldon Roger A605461Bekkum Herman van518783MiAaPQMiAaPQMiAaPQBOOK9910831177403321Fine chemicals through heterogenous catalysis4040369UNINA