05316nam 2200661 450 991083097280332120230422044854.01-281-84251-697866118425123-527-61400-13-527-61401-X(CKB)1000000000376617(EBL)481693(OCoLC)291093149(SSID)ssj0000121590(PQKBManifestationID)11147909(PQKBTitleCode)TC0000121590(PQKBWorkID)10110942(PQKB)10892339(MiAaPQ)EBC481693(EXLCZ)99100000000037661720160818h19991999 uy 0engur|n|---|||||txtccrChiral auxiliaries in cycloadditions /Karola Ruck-Braun, Horst KunzWeinheim, [Germany] :Wiley-VCH,1999.©19991 online resource (190 p.)Description based upon print version of record.3-527-29386-8 Includes bibliographical references at the end of each chapters and index.Chiral Auxiliaries in Cycloadditions; Table of Contents; 1 [2+1] Cycloadditions (Cyclopropanations); 1.1 Simmons-Smith Reactions; 1.2 Cyclopropanations with Carbene Equivalents; 1.3 Cyclopropanations with Ylide Reagents; 1.3.1 Chiral Ylide Reagents; 1.3.2 Chiral Alkenes; 1.4 Transition Metal-Catalyzed Reactions of Diazo Compounds; 1.5 References; 2 [2+2] Cycloadditions; 2.1 Reactions of Imines with Ketenes (Staudinger Reaction); 2.1.1 Chiral Ketenes; 2.1.2 Chiral Imines; 2.2 Reactions of Keteniminium Salts with Alkenes; 2.3 Reactions of Ketenes with Electronrich Alkenes; 2.3.1 Chiral Ketenes2.3.2 Chiral Vinylethers2.3.3 Miscellaneous Reactions; 2.4 Reactions of Isocyanates with Alkenes; 2.5 Photochemically Induced [2+2] Cycloadditions; 2.5.1 Paterno-Büchi Reactions; 2.5.2 Application of Chromium Carbene Complexes; 2.6 References; 3 [4+2] Cycloadditions (Diels-Alder Reactions); 3.1 Thermal Reactions; 3.1.1 Reactions of Chiral Dienophiles; 3.1.2 Reactions of Achiral Dienophiles with Chiral Dienes; 3.2 Lewis Acid-Catalyzed Reactions; 3.2.1 Reactions of Chiral Dienophiles; 3.2.2 Reactions of Achiral Dienophiles with Chiral Dienes; 3.3 Intramolecular [4+2] Cycloadditions3.3.1 Thermal Reactions3.3.2 Lewis Acid-Catalyzed Reactions; 3.4 References; 4 Hetero [4+2] Cycloadditions; 4.1 Reactions of Hetero-Dienophiles with Dienes; 4.1.1 Reactions of Activated Carbonyl Dienophiles/Aldehydes; 4.1.1 . 1 Reactions of Chiral Carbonyl Dienophiles with Achiral Dienes; 4.1.1.2 Reactions of Achiral Carbonyl Dienophiles with Chiral Heteroatom-substituted Dienes; 4.1.2 Reactions of Imines; 4.1.2.1 Reactions of Chiral Imines with Dienes; 4.1.2.2 Reactions of Chiral Imines with Heteroatom-substituted Dienes4.1.2.3 Reactions of Achiral Imines with Chiral Heteroatom-substituted Dienes4.1.3 Reactions of Nitroso Compounds; 4.1.3.1 Reactions of Chloronitroso Compounds; 4.1.4 Reactions of N-Acylnitroso Compounds; 4.1.4.1 Reactions of Chiral N-Acylnitroso Compounds with Dienes; 4.1.4.2 Reactions of Achiral N-Acylnitroso Compounds with Achiral Dienes; 4.1.5 Reactions of N-Sulfinyl Dienophiles; 4.1.6 Reactions of N=N Dienophiles; 4.2 Reactions of Hetero-Dienes with Dienophiles; 4.2.1 Reactions of Oxabutadienes; 4.2.1.1 Reactions of Chiral Oxabutadienes with Achiral Vinylethers4.2.1.2 Reactions of Achiral Oxabutadienes with Chiral Vinylethers4.2.2 Reactions of Achiral Nitroso Compounds; 4.2.3 Reactions of Nitroalkenes; 4.2.4 Reactions of 1-Aza-1,3-dienes; 4.2.5 Reactions of 2-Aza-1,3-dienes; 4.2.6 Reactions of Chiral N-Acyl-Imines; 4.2.7 Reactions of Thiabutadienes; 4.2.8 Intramolecular Hetero [4+2] Cycloadditions; 4.3 References; 5 [3+2] Cycloadditions; 5.1 Chiral Dipolarophiles; 5.1.1 Reactions of Nitrile Oxides; 5.1.2 Reactions of Nitrile Imines; 5.1.3 Reactions of Nitrones; 5.1.4 Reactions of Nitronates; 5.1.5 Reactions of Azomethine Ylides5.1.5.1 Reactions of Azomethine Ylides Derived from AIdiminesSince the days of Diels, Alder and Woodward, cycloadditions have been among the most versatile reactions for stereoselective synthesis ... All relevant information is collected in this well-structured, practical handbook. Arranged according to the cycloaddition type, the suitable auxiliaries, reactants, stereoselectivities, yields, and references for each key reaction are compiled in compact tables. Scientists interested in the theoretical background of stereoselective cycloadditions will find an excellent selection of in-depth literature references. ... with this comprehensivChiralityRing formation (Chemistry)Organic compoundsSynthesisChirality.Ring formation (Chemistry)Organic compoundsSynthesis.547.2547.504593Rück-Braun Karola1675347Kunz HorstMiAaPQMiAaPQMiAaPQBOOK9910830972803321Chiral auxiliaries in cycloadditions4040725UNINA