05325nam 2200637Ia 450 991083094480332120230725053826.00-470-82827-71-283-37244-497866133724440-470-82515-40-470-82514-6(CKB)2550000000063641(EBL)693333(SSID)ssj0000477694(PQKBManifestationID)11325327(PQKBTitleCode)TC0000477694(PQKBWorkID)10502846(PQKB)10783849(MiAaPQ)EBC693333(OCoLC)729726195(EXLCZ)99255000000006364120110126d2011 uy 0engur|n|---|||||txtccrComplex macromolecular architectures[electronic resource] synthesis, characterization, and self-assembly /editors, Nikos Hadjichristidis ... [et al.]Singapore John Wiley & Sons (Asia) Pte Ltd.20111 online resource (858 p.)Description based upon print version of record.0-470-82513-8 Includes bibliographical references and index.Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly; Contents; List of Contributors; Preface; About the Editors; Part One: Synthesis; 1 Cyclic and Multicyclic Topological Polymers; 1.1 Introduction; 1.2 The Progress on the Synthesis of Ring Polymers; 1.2.1 Ring-Expansion Polymerization; 1.2.2 Cyclization by Telechelic Polymer Precursors; 1.3 Functional Ring Polymers and Topology Effects Thereby; 1.3.1 Polymer Catenanes Using a Ring Polymer Precursor Having an H-Bonding Unit; 1.3.2 Single-Molecule Spectroscopy Using a Ring Polymer Having a Chromophore Unit1.3.3 Crystallization Dynamics Using a Defect-Free Ring Polymer1.4 New Developments in the Construction of Multicyclic Polymer Topologies; 1.4.1 Fused Multicyclic Polymers; 1.4.2 Spiro Multicyclic Polymers; 1.4.3 Bridged Multicyclic Polymers; 1.5 Conclusions and Perspectives; References; 2 Ultrarapid Approaches to Mild Macromolecular Conjugation; 2.1 Introduction; 2.2 RAFT-HDA Chemistry; 2.3 Ultrafast RAFT-HDA Chemistry; 2.4 Cycloadditions with Strained or Activated Alkynes; 2.5 Thiol-Ene/Thiol-Yne Chemistry; 2.6 Thiol-Isocyanate Chemistry; 2.7 Thio-Bromo Chemistry2.8 Inverse Electron Demand Diels-Alder2.9 Cycloadditions Involving Nitrile Oxides; 2.10 Oxime Formation; 2.11 Tetrazole-Ene Reaction; 2.12 Concluding Remarks; References; 3 Synthesis and Self-Assembly of Hydrogen-Bonded Supramolecular Polymers; 3.1 Introduction; 3.1.1 Dynamics of Hydrogen Bonds; 3.1.2 Other Experimental Methods in Supramolecular Polymer Science; 3.2 Synthetic Strategies Towards Hydrogen-Bonded Supramolecular Polymers; 3.2.1 Carbocationic Polymerization; 3.2.2 Anionic Polymerization; 3.2.3 Ring-Opening Metathesis Polymerization (ROMP)3.2.4 Controlled Radical Polymerization (CRP)3.2.5 Polycondensation Methods; 3.2.6 Ring-Opening Polymerization (ROP); 3.2.7 Other Postmodification Methods; 3.3 Self-Assembly of Supramolecular Polymers via Hydrogen Bonds; 3.3.1 Microphase-Separated H-Bonded Polymers: Towards Pseudoblock Copolymers; 3.3.2 Ordering on Surfaces; 3.3.3 Small-Molecule Ordering into Polymers via H Bonds; 3.3.4 Applications of H-Bonded Supramolecular Polymers; 3.4 Conclusions and Outlook; Acknowledgment; References; 4 Recent Synthetic Developments in Miktoarm Star Polymers with More than Three Different Arms4.1 Introduction4.2 Miktoarm Star-Branched Polymers up to 2000; 4.3 Novel and Versatile Methodology Based on an "Iterative Approach" for Miktoarm Star Polymer Syntheses; 4.3.1 Iterative Methodology with Regeneration of DPE Function; 4.3.2 Iterative Methodology with Regeneration of Two or More DPE Functions; 4.3.3 Iterative Methodology with Regeneration of 1,3-Butadiene Function; 4.3.4 Iterative Methodology with Regeneration of Benzyl Bromide Function; 4.3.5 Convergent Synthesis of Miktoarm Star-Branched Polymers Using Polymer Anions4.4 Miktoarm Star Polymers by Other Methodologies Based on Living Anionic PolymerizationThe field of CMA (complex macromolecular architecture) stands at the cutting edge of materials science, and has been a locus of intense research activity in recent years. This book gives an extensive description of the synthesis, characterization, and self-assembly of recently-developed advanced architectural materials with a number of potential applications. The architectural polymers, including bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil bMacromoleculesPolymerizationMacromolecules.Polymerization.547.7547/.7SCI013040bisacshHadjichristidis Nikos1943-1700510MiAaPQMiAaPQMiAaPQBOOK9910830944803321Complex macromolecular architectures4098961UNINA