06092nam 2200697Ia 450 991083093410332120200910211026.01-282-34950-397866123495080-470-74553-30-470-74554-1(CKB)1000000000794246(EBL)454363(OCoLC)609843855(SSID)ssj0000298281(PQKBManifestationID)11261231(PQKBTitleCode)TC0000298281(PQKBWorkID)10343931(PQKB)10599084(MiAaPQ)EBC454363(PPN)152355286(EXLCZ)99100000000079424620090326d2009 uy 0engur|n|||||||||txtrdacontentcrdamediacrrdacarrierHandbook of thiophene-based materials[electronic resource] applications in organic electronics and photonics /Igor F. Perepichka, Dmitrii F. PerepichkaHoboken Wiley20091 online resource (887 p.)Description based upon print version of record.Print version published in 2-volume set.0-470-05732-7 Includes bibliographical references and index.Handbook of Thiophene-based Materials; Contents; Volume One: Synthesis and Theory; Volume Two: Properties and Applications; Foreword by Professor Fred Wudl; Preface; List of Contributors; 1 Functional oligothiophene-based materials: nanoarchitectures and applications; 1.1 Introduction; 1.2 Functionalized oligothiophenes; 1.2.1 Oligothiophenes containing surface-active groups; 1.2.2 Self-assembling hybrid oligothiophenes; 1.2.3 Oligothiophenes as pendant groups grafted to polymer backbones; 1.2.4 Oligothiophenes as liquid crystalline materials; 1.2.5 π-Dimeric model system1.2.6 Donor, acceptor and donor-acceptor (D-A) mixed systems1.2.7 Dye-functionalized oligothiophenes; 1.2.8 Oligothiophenes containing redox active groups; 1.2.9 Oligothiophenes containing recognition groups; 1.2.10 Biologically active oligothiophenes; 1.3 Fused thiophenes; 1.3.1 Benzothiophene analogues; 1.3.2 Heteroaromatic ring-fused oligothiophenes; 1.3.3 Thienothiophenes and higher homologues; 1.4 Macrocyclic thiophenes; 1.4.1 Macrocycles based only on thiophenes; 1.4.2 Mixed macrocycles based on thiophenes and other unsaturated units; 1.4.3 Thiophene-based porphyrinoid macrocycles1.5 Dendritic and hyperbranched oligothiophenes1.5.1 Star-shaped structures; 1.5.2 Tetrahedral oligothiophenes; 1.5.3 Functionalization of dendrimers with oligothiophenes at the periphery; 1.5.4 Oligothiophenes used as cores in dendrimers; 1.5.5 Functionalized all-thiophene dendrimers; 1.6 Conclusions and prospects; Acknowledgments; References; 2 Synthesis, characterization and properties of regioregular polythiophene-based materials; 2.1 Introduction; 2.1.1 Scope of the chapter; 2.1.2 Development of polythiophenes; 2.1.3 Nomenclature; 2.2 Consequences of regiochemistry2.3 Synthesis of regioregular polythiophenes2.3.1 Survey of regioregular syntheses; 2.3.2 Mechanism of nickel-mediated cross-coupling polymerization; 2.3.3 Polymer modification: chain and termini; 2.3.4 Polymer modification: substituent; 2.4 Purification and fractionation; 2.5 Molecular characterization; 2.5.1 NMR spectroscopy; 2.5.2 UV-Vis spectroscopy; 2.5.3 MALDI-TOF-MS; 2.5.4 Light scattering studies of aggregates; 2.6 Solid-state studies; 2.6.1 Solid-state NMR spectroscopy; 2.6.2 Solid-state UV-Vis spectroscopy; 2.6.3 Solid-state vibrational spectroscopy (IR, Raman)2.6.4 Solid-state X-ray studies2.6.5 Anisotropy; 2.6.6 Microscopy (AFM, STM); 2.6.7 Thermal analysis (DSC, TGA); 2.6.8 Charge carrier mobility; 2.7 Block copolymers containing regioregular polythiophenes; 2.8 Conclusions; References; 3 Fused oligothiophenes; 3.1 Introduction; 3.2 Synthesis and molecular properties of fused oligothiophenes; 3.2.1 Thienothiophenes; 3.2.2 Dithienothiophenes; 3.2.3 Linked bithiophenes; 3.2.4 Higher fused and linear oligothiophenes; 3.2.5 Cyclic and helical fused oligothiophenes; 3.3 Conclusion; References4 Thiophene-S,S-dioxides as a class of electron-deficient materials for electronics and photonicsThis essential resource consists of a series of critical reviews written by leading scientists, summarising the progress in the field of conjugated thiophene materials. It is an application-oriented book, giving a chemists' point of view on the state-of-art and perspectives of the field. While presenting a comprehensive coverage of thiophene-based materials and related applications, the aim is to show how the rational molecular design of materials can bring a new breadth to known device applications or even aid the development of novel application concepts. The main topics covered include synthetic methodologies to thiophene-based materials (including the chemistry of thiophene, preparation of oligomers and polymerisation approaches) and the structure and physical properties of oligo- and polythiophenes (discussion of structural effects on electronic and optical properties). Part of the book is devoted to the optical and semiconducting properties of conjugated thiophene materials for electronics and photonics, and the role of thiophene-based materials in nanotechnology.ThiophenesElectric propertiesConjugated polymersOrganic compoundsSynthesisThiophenesElectric properties.Conjugated polymers.Organic compoundsSynthesis.661.8661/.8Perepichka Igor F1639493Perepichka Igor F.Perepichka Dmitrii F.MiAaPQMiAaPQMiAaPQCaOLUBOOK9910830934103321Handbook of thiophene-based materials3982522UNINA