05231nam 22006014a 450 991083042380332120170815114005.01-280-26934-097866102693410-470-09267-X0-470-09268-8(CKB)111090529069406(EBL)189502(OCoLC)55143512(SSID)ssj0000120485(PQKBManifestationID)11130257(PQKBTitleCode)TC0000120485(PQKBWorkID)10081534(PQKB)11418655(MiAaPQ)EBC189502(PPN)158673077(EXLCZ)9911109052906940620031002d2004 uy 0engur|n|---|||||txtccrChemical thermodynamics of materials[electronic resource] macroscopic and microscopic aspects /Svein Stolen, Tor Grande ; with a chapter on thermodynamics and materials modelling by Neil L. AllanHoboken, NJ J. Wileyc20041 online resource (410 p.)Description based upon print version of record.0-471-49230-2 Includes bibliographical references and index.Chemical Thermodynamics of Materials; Contents; Preface; 1 Thermodynamic foundations; 1.1 Basic concepts; Thermodynamic systems; Thermodynamic variables; Thermodynamic processes and equilibrium; 1.2 The first law of thermodynamics; Conservation of energy; Heat capacity and definition of enthalpy; Reference and standard states; Enthalpy of physical transformations and chemical reactions; 1.3 The second and third laws of thermodynamics; The second law and the definition of entropy; Reversible and non-reversible processesConditions for equilibrium and the definition of Helmholtz and Gibbs energiesMaximum work and maximum non-expansion work; The variation of entropy with temperature; The third law of thermodynamics; The Maxwell relations; Properties of the Gibbs energy; 1.4 Open systems; Definition of the chemical potential; Conditions for equilibrium in a heterogeneous system; Partial molar properties; The Gibbs-Duhem equation; References; Further reading; 2 Single-component systems; 2.1 Phases, phase transitions and phase diagrams; Phases and phase transitions; Slopes of the phase boundariesPhase diagrams and Gibbs phase ruleField-induced phase transitions; 2.2 The gas phase; Ideal gases; Real gases and the definition of fugacity; Equations of state of real gases; 2.3 Condensed phases; Variation of the standard chemical potential with temperature; Representation of transitions; Equations of state; References; Further reading; 3 Solution thermodynamics; 3.1 Fundamental definitions; Measures of composition; Mixtures of gases; Solid and liquid solutions - the definition of chemical activity; 3.2 Thermodynamics of solutions; Definition of mixing properties; Ideal solutionsExcess functions and deviation from ideality3.3 Standard states; Henry's and Raoult's laws; Raoultian and Henrian standard states; 3.4 Analytical solution models; Dilute solutions; Solution models; Derivation of partial molar properties; 3.5 Integration of the Gibbs-Duhem equation; References; Further reading; 4 Phase diagrams; 4.1 Binary phase diagrams from thermodynamics; Gibbs phase rule; Conditions for equilibrium; Ideal and nearly ideal binary systems; Simple eutectic systems; Regular solution modelling; Invariant phase equilibria; Formation of intermediate phasesMelting temperature: depression or elevation?Minimization of Gibbs energy and heterogeneous phase equilibria; 4.2 Multi-component systems; Ternary phase diagrams; Quaternary systems; Ternary reciprocal systems; 4.3 Predominance diagrams; References; Further reading; 5 Phase stability; 5.1 Supercooling of liquids - superheating of crystals; 5.2 Fluctuations and instability; The driving force for chemical reactions: definition of affinity; Stability with regard to infinitesimal fluctuations; Compositional fluctuations and instability; The van der Waals theory of liquid-gas transitionsPressure-induced amorphization and mechanical instabilityA comprehensive introduction, examining both macroscopic and microscopic aspects of the subject, the book applies the theory of thermodynamics to a broad range of materials; from metals, ceramics and other inorganic materials to geological materials. Focusing on materials rather than the underlying mathematical concepts of the subject, this book will be ideal for the non-specialist requiring an introduction to the energetics and stability of materials. Macroscopic thermodynamic properties are linked to the underlying miscroscopic nature of the materials and trends in important properties areThermodynamicsThermodynamics.541.369Stølen Svein1659278Grande Tor1659279MiAaPQMiAaPQMiAaPQBOOK9910830423803321Chemical thermodynamics of materials4013857UNINA