03538nam 2200601 a 450 991083037400332120230721030006.01-280-91673-797866109167330-470-13923-40-470-13922-6(CKB)1000000000356660(EBL)304930(OCoLC)476082236(SSID)ssj0000225735(PQKBManifestationID)11202219(PQKBTitleCode)TC0000225735(PQKBWorkID)10234555(PQKB)11047712(MiAaPQ)EBC304930(EXLCZ)99100000000035666020070315d2007 uy 0engur|n|---|||||txtccrA practical guide to magnetic circular dichroism spectroscopy[electronic resource] /W. Roy MasonHoboken, N.J. Wiley-Intersciencec20071 online resource (237 p.)Description based upon print version of record.0-470-06978-3 Includes bibliographical references and index.A PRACTICAL GUIDE TO MAGNETIC CIRCULAR DICHROISM SPECTROSCOPY; CONTENTS; PREFACE; 1. Introduction; 2. Polarized Light; 2.1. Linear Polarization and Plane Polarized Waves; 2.2. Circular Polarization and Circularly Polarized Waves; 2.3. Absorption Probabilities; 3. Theoretical Framework: Definition of MCD Terms; 3.1. Born-Oppenheimer/Franck-Condon Approximation; 3.2. Rigid-Shift Approximation; 3.3. A(1)-, B(0)-, and C(0)-Term Parameters; 3.4. A Terms; 3.5. C Terms; 3.6. B Terms; 3.7. Pseudo A Terms: Overlapping B Terms; 3.8. Overlapping C Terms; 3.9. Ground-State Near Degeneracy5.3. The Wigner-Eckart Theorem and Reduced Matrix Elements (RMEs)5.4. MCD-Term Equations Involving RMEs; 5.5. Evaluation of RMEs for MCD Terms; 5.6. Evaluation of Matrix Elements for LCAO-MO Functions; 5.7. Spin-Orbit Coupling Considerations; 5.8. Herzberg-Teller Approximation for Vibronic Transitions; 6. Case Studies I. Diamagnetic Systems: A and B Terms; 6.1. A and B Terms for Diamagnetic Atoms and Molecules; 6.2. Atomic Mercury Vapor; 6.3. The Sodide Ion Na(-) in a Solid NH(3) Matrix; 6.4. Square Complexes of D(4h) Symmetry; 6.4.1. Ligand Field Spectra for PtCl4(2-)(4)6.9.2. Rydberg Transitions for CH(3)I and CD(3)I in the Vacuum UVThe book is a technical guide for chemists and spectroscopists, and presents a concise description of magnetic circular dichroism (MCD) spectroscopy and how it has advanced the interpretation of molecular electronic spectra.Provides a practical guide to utilizing MCD spectroscopy for chemists starting in the fieldWritten by an expert with over twenty years of experience in the fieldHelps the reader to visualize the optical spectroscopic effects presented by MCD measurementsIncludes practical considerations for experimental MCD measurements based on the author's experience<lMolecular spectroscopyMolecular spectraMagnetic circular dichroismMolecular spectroscopy.Molecular spectra.Magnetic circular dichroism.543.54543/.54Mason W. Roy1679506MiAaPQMiAaPQMiAaPQBOOK9910830374003321A practical guide to magnetic circular dichroism spectroscopy4047794UNINA