01657nam 2200421 450 991083020380332120231008135521.03-527-62077-X10.1002/9783527620777(CKB)4540000000000282(NjHacI)994540000000000282(EXLCZ)99454000000000028220231008d2005 uy 0engur|||||||||||txtrdacontentcrdamediacrrdacarrierOrganosilicon Chemistry Set From Molecules to Materials /Norbert Auner, Johann WeisWeinheim, Germany :Wiley-VCH,2005.©20051 online resource3-527-32347-3 Aryl ligands carrying oxygen, phosphorus or sulfur donor atoms in the side chain are introduced at silicon. Here we report on the synthesis of silyl chlorides and silyl triflates. The interaction between the silicon centre and the donor atom are discussed on the basis of NMR and X-ray crystallographic data. In the reaction of bis[2-(methoxymethyl)phenyl]methylsilyl triflate 8 with nucleophiles, reactivity of oxonium as well as of siliconium ions is observed.Organosilicon Chemistry Set Organosilicon compoundsSilicon compoundsOrganosilicon compounds.Silicon compounds.547.08Auner Norbert906518Weis JohannNjHacINjHaclBOOK9910830203803321Organosilicon Chemistry Set4082566UNINA