05417nam 22007094a 450 991082809800332120200520144314.09786612237539978128223753712822375359780470516683047051668297804705166760470516674(CKB)1000000000376503(EBL)454455(OCoLC)609844468(SSID)ssj0000353954(PQKBManifestationID)11251614(PQKBTitleCode)TC0000353954(PQKBWorkID)10302226(PQKB)10299653(MiAaPQ)EBC454455(Au-PeEL)EBL454455(CaPaEBR)ebr10317837(CaONFJC)MIL223753(OCoLC)122701726(FINmELB)ELB178412(Perlego)2755417(EXLCZ)99100000000037650320070402d2007 uy 0engur|n|---|||||txtccrChemistry and technology of carbodiimides /Henri Ulrich1st ed.Chichester, England ;Hoboken, NJ John Wiley & Sons20071 online resource (312 p.)Description based upon print version of record.9780470065105 0470065109 Includes bibliographical references and index.Chemistry and Technology of Carbodiimides; Contents; Preface; Acknowledgements; 1 General Introduction; 1.1 References; 2 Alkyl- and Arylcarbodiimides; 2.1 Introduction; 2.2 Synthesis of Alkyl- and Arylcarbodiimides; 2.2.1 From Thioureas, Isothioureas and Selenoureas; 2.2.2 By Dehydration of Ureas; 2.2.3 From Isocyanates or Isothiocyanates; 2.2.4 From Cyanamides; 2.2.5 By Nitrene Rearrangements; 2.2.6 From Haloformamidines or Carbonimidoyl Dihalides; 2.2.7 By Thermolysis Reactions; 2.2.8 By Miscellaneous Other Methods; 2.3 References I; 2.4 Reactions of Alkyl- and Arylcarbodiimides2.4.1 Oligomerization and Polymerization2.4.2 Cycloaddition Reactions; 2.4.3 Reaction of Ylides with Carbodiimides; 2.4.4 Insertion Reactions; 2.4.5 Nucleophilic Reactions; 2.4.6 Heterocycles from Carbodiimides; 2.4.7 Use of Carbodiimides In Condensation Reactions; 2.4.8 Miscellaneous Reactions; 2.5 References II; 3 Unsaturated Carbodiimides; 3.1 Introduction; 3.2 Synthesis of Unsaturated Carbodiimides; 3.2.1 From Thioureas; 3.2.2 From Unsaturated Isocyanates; 3.2.3 From Unsaturated Iminophosphoranes and Isocyanates or Isothiocyanates; 3.2.4 By Other Methods3.3 Reactions of Unsaturated Carbodiimides3.3.1 Polymerization Reactions; 3.3.2 Cycloaddition Reactions; 3.3.3 Other Reactions; 3.4 References; 4 Halogenated Carbodiimides; 4.1 Introduction; 4.2 Synthesis of Halogenated Carbodiimides; 4.2.1 From -Haloisocyanates; 4.2.2 By Halogenation of Carbodiimides; 4.2.3 From Carbonimidoyl Dichlorides or Imidoyl Chlorides; 4.2.4 By Other Methods; 4.3 Reactions of Halogenated Carbodiimides; 4.3.1 Cycloaddition Reactions; 4.3.2 Nucleophilic Reactions; 4.3.3 Other Reactions; 4.4 References; 5 Acyl-, Thioacyl- and Imidoylcarbodiimides; 5.1 Introduction5.2 Synthesis of Acyl-, Thioacyl- and Imidoylcarbodiimides5.2.1 From Thioureas; 5.2.2 From Ureas; 5.2.3 From Isocyanates; 5.2.4 From Carbonimidoyl Dichlorides or Chloroformamidines; 5.2.5 From Cyanamides; 5.2.6 From Other Carbodiimides; 5.2.7 By Other Methods; 5.3 Reactions of Acyl-, Thioacyl- and Imidoylcarbodiimides; 5.3.1 Cycloaddition Reactions; 5.3.2 Other Reaction; 5.4 References; 6 Silicon Substituted Carbodiimides; 6.1 Introduction; 6.2 Synthesis of Silicon Substituted Carbodiimides; 6.2.1 From Cyanamides; 6.2.2 From Ureas; 6.2.3 From Isocyanates and Isothiocyanates6.2.4 From Silylamines6.2.5 From Other Carbodiimides; 6.2.6 By Other Methods; 6.3 Reactions of Silicon Substituted Carbodiimides; 6.3.1 Oligomerization Reactions; 6.3.2 Cycloaddition Reactions; 6.3.3 Other Reactions; 6.4 References; 7 Nitrogen Substituted Carbodiimides; 7.1 Introduction; 7.2 Synthesis of Nitrogen Substituted Carbodiimides; 7.3 Reactions of Nitrogen Substituted Carbodiimides; 7.4 References; 8 Phosphorous Substituted Carbodiimides; 8.1 Introduction; 8.2 Synthesis of Phosphorous Substituted Carbodiimides; 8.2.1 From Thioureas; 8.2.2 From Iminophosphoranes8.2.3 From Carbonimidoyl DichloridesCarbodiimides play an important role as condensation agents in the synthesis of polypeptides, polynucleotides, polysaccharides and numerous other chemical transformations. Chemistry and Technology of Carbodiimides is the first book to examine both the chemistry and technology of carbodiimides. This book provides a comprehensive and in-depth coverage of the synthesis and reactions of this industrially important class of chemicals while focusing on industrial applications, including the M-sectors of biochemical synthesis, pharmaceuticals, polymers, ceramics, and herbicides. Written by a wCarbodiimidesCarbodiimides.661/.894Ulrich Henri1925-1658044MiAaPQMiAaPQMiAaPQBOOK9910828098003321Chemistry and technology of carbodiimides4011827UNINA