04855nam 2200685 a 450 991082231090332120240514074813.03-527-63963-21-283-37057-397866133705703-527-63962-43-527-63964-0(CKB)2550000000073826(EBL)822731(OCoLC)768732536(SSID)ssj0000612999(PQKBManifestationID)11931508(PQKBTitleCode)TC0000612999(PQKBWorkID)10583960(PQKB)10080418(MiAaPQ)EBC822731(Au-PeEL)EBL822731(CaPaEBR)ebr10518734(CaONFJC)MIL337057(EXLCZ)99255000000007382620120114d2011 uy 0engurcn|||||||||txtccrTerpyridine-based materials for catalytic, optoelectronic and life science applications /Ulrich S. Schubert, Andreas Winter, and George R. Newkome1st ed.Weinheim, Germany Wiley-VCH20111 online resource (544 p.)Description based upon print version of record.3-527-33038-0 Includes bibliographical references and index.Terpyridine-based Materials: For Catalytic, Optoelectronic and Life Science Applications; Contents; Preface; List of Abbreviations; 1: Introduction; 2: Synthesis, Properties, and Applications of Functionalized 2,2 ;-Terpyridines; 2.1: Introduction; 2.2: Basic Synthetic Strategies; 2.2.1: Ring-Assembly Methodologies; 2.2.2: Cross-Coupling Procedures; 2.3: Synthesis and Properties of 2,-Terpyridine Derivatives; 2.3.1: 4x2032;-Substituted 2, Terpyridinoxy Derivatives; 2.3.2: Miscellaneous 4;-Substituted 2,2032;-Terpyridine Derivatives3.3.1: Synthesis of RuII and OsII Bis(terpyridine) Complexes 3.3.2: RuII Ions and Terpyridine Ligands - A Happy Marriage?; 3.3.2.1: Photophysical Properties; 3.3.2.2: Mononuclear RuII Bis(terpyridine) Complexes; 3.3.2.3: Oligonuclear Complexes Containing RuII/OsII Bis(terpyridine) Units; 3.3.2.4: Dendritic and Star-Shaped Systems Containing RuII Bis(terpyridine) Units; 3.4: Iridium(III) Complexes with Terpyridine Ligands; 3.5: Platinum(II) Mono(terpyridine) Complexes; 4: Metallo-Supramolecular Architectures Based on Terpyridine Complexes; 4.1: Introduction4.2: Terpyridine-Containing Metallo-Macrocycles 4.3: The HETTAP Concept; 4.4: Racks and Grids; 4.5: Helicates; 4.6: Rotaxanes and Catenanes; 4.7: Miscellaneous Structures; 4.7.1: Cyclodextrin Derivatives; 4.7.2: Other Assemblies; 5: CO; -Conjugated Polymers Incorporating Terpyridine Metal Complexes; 5.1: Introduction; 5.2: Metallo-Supramolecular Polymerization; 5.3: Metallopolymers Based on CO; -Conjugated Bis(terpyridine)s; 5.3.1: Polymerization by Transition Metal Ion Coordination; 5.3.2: Self-Assembly of Metallopolymers; 5.3.3: Chiral Metallopolymers; 5.3.4: Non-Classical Metallopolymers5.3.5: Polymerization Using the ''Complex First'' Method 5.4: Main-Chain Metallopolymers Based on Terpyridine-Functionalized CO; -Conjugated Polymers; 6: Functional Polymers Incorporating Terpyridine-Metal Complexes; 6.1: Introduction; 6.2: Polymers with Terpyridine Units in the Side-Chain; 6.2.1: Materials Based on Flexible Organic Polymers; 6.2.2: Materials Based on CO; -Conjugated Polymers; 6.3: Polymers with Terpyridines within the Polymer Backbone; 6.3.1: Polymers from Organic Small-Molecule Building Blocks; 6.3.2: Chain-Extended Polymers from Polymeric Building Blocks6.3.3: Monotopic Macroligands by End-Group FunctionalizationIn recent years, the utilization of terpyridines both in macromolecular structure assembly and device chemistry has exploded, enabling, for example, supramolecular polymer architectures with switchable chemical and physical properties as well as novel functional materials for optoelectronic applications such as light-emitting diodes and solar cells. Further applications include the usage of terpyridines and their metal complexes as catalysts for asymmetric organic reactions and, in a biological context, as anti-tumor agents or biolabels. This book covers terpyridine-based materials topicsPyridinePyridine.547.593540sdnbVK 7150rvkVK 7200rvkSchubert U(Ulrich)864504Winter Andreas941979Newkome George R(George Richard)866143MiAaPQMiAaPQMiAaPQBOOK9910822310903321Terpyridine-based materials4103101UNINA