05928nam 2200841 a 450 991082225130332120240313201140.0978111835675311183567569781118356760111835676497811183567461118356748(CKB)2670000000350741(EBL)1173431(OCoLC)850147373(SSID)ssj0000871798(PQKBManifestationID)11478049(PQKBTitleCode)TC0000871798(PQKBWorkID)10824040(PQKB)11508052(SSID)ssj0000916944(PQKBManifestationID)11485387(PQKBTitleCode)TC0000916944(PQKBWorkID)10878082(PQKB)11722216(MiAaPQ)EBC1173431(DLC) 2013007823(Au-PeEL)EBL1173431(CaPaEBR)ebr10691475(CaONFJC)MIL484656(PPN)199180105(Perlego)1001766(EXLCZ)99267000000035074120130222d2013 uy 0engur|n|---|||||txtccrLiquid phase oxidation via heterogeneous catalysis organic synthesis and industrial applications /edited by Mario G. Clerici, Oxana A. Kholdeeva1st ed.Hoboken, N.J. Wiley20131 online resource (548 p.)Includes index.9780470915523 0470915528 Includes bibliographical references and index.Liquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis And Industrial Applications; Contents; Preface; Contributors; Abbreviations; 1 Environmentally Benign Oxidants; 1.1 Introduction; 1.2 Oxygen (Air); 1.3 Alkylhydroperoxides; 1.4 Hydrogen Peroxide; 1.5 Conclusions; References; 2 Oxidation Reactions Catalyzed by Transition-Metal-Substituted Zeolites; 2.1 Introduction; 2.2 Synthesis and Characterization of Zeolites; 2.2.1 Isomorphous Metal Substitution; 2.2.2 Synthesis of Titanium Silicalite-1 (TS-1); 2.2.3 Characterization of Titanium Silicalite-1 (TS-1)2.2.4 Ti-Beta, Synthesis and Characterization2.2.5 Other Ti Zeolites; 2.2.6 Other Metal Zeolites; 2.3 Catalytic Properties; 2.3.1 Hydroxylation of Alkanes; 2.3.2 Hydroxylation of Aromatic Compounds; 2.3.3 Oxidation of Olefinic Compounds; 2.3.4 Oxidation of Alcohol and Ether Compounds; 2.3.5 Reactions of Carbonyl Compounds; 2.3.6 Oxidation of N-Compounds; 2.3.7 Oxidation of S-Compounds; 2.4 Mechanistic Aspects; 2.4.1 The Nature of Active Species; 2.4.2 Hydroxylation; 2.4.3 Epoxidation; 2.4.4 Oxidation of Alcohols; 2.4.5 Ammoximation; 2.4.6 Decomposition of Hydrogen Peroxide2.4.7 Active Species, Adsorption and Catalytic Activity2.5 Stability of Metal-Substituted Zeolites to Reaction Conditions; 2.6 Conclusions; References; 3 Selective Catalytic Oxidation over Ordered Nanoporous Metallo-Aluminophosphates; 3.1 Introduction; 3.2 Synthesis; 3.2.1 Microporous Aluminophosphates; 3.2.2 Mesoporous Aluminophosphates; 3.3 Characterization; 3.4 Catalytic Properties; 3.4.1 Oxidation of Hydrocarbons; 3.4.2 Oxidation of Olefins; 3.4.3 Oxidation of Alcohols; 3.4.4 Oxidation of Phenols; 3.4.5 Ammoximation and Ammoxidation; 3.4.6 Baeyer-Villiger Oxidation3.4.7 Oxidation of Heterocycles3.5 Mechanistic Aspects; 3.6 Catalysts Stability; 3.7 Conclusion; References; 4 Selective Oxidations Catalyzed by Mesoporous Metal Silicates; 4.1 Introduction; 4.2 Synthesis and Characterization; 4.2.1 General Synthetic Approaches; 4.2.2 Characterization Techniques; 4.2.3 Sol-Gel Synthesis of Amorphous Mixed Oxides; 4.2.4 Thermolytic Molecular Precursor Method; 4.2.5 Templated Synthesis of Ordered Metal Silicates; 4.2.6 Postsynthesis Modifications; 4.2.7 Organic-Inorganic Hybrid Materials; 4.3 Catalytic Properties; 4.3.1 Oxidation of Alkanes4.3.2 Oxidation of Aromatic Compounds4.3.3 Oxidation of Olefins; 4.3.4 Oxidation of Alcohols; 4.3.5 Oxidation of Ketones and Aldehydes; 4.3.6 Oxidation of S-compounds; 4.3.7 Oxidation of Amines; 4.4 Mechanistic Aspects; 4.5 Stability; 4.5.1 Mechanisms of Deactivation; 4.5.2 Solving Problem of Hydrothermal Stability; 4.5.3 Hydrothermally Stable Catalysts: Scope and Limitations; 4.6 Conclusions and Outlook; References; 5 Liquid Phase Oxidation of Organic Compounds by Supported Metal-Based Catalysts with a Focus on Gold; 5.1 Introduction; 5.2 Catalyst Preparation and Characterization5.3 Catalytic Properties Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributionsOxidationOxidationIndustrial applicationsHeterogeneous catalysisHeterogeneous catalysisIndustrial applicationsOxidation.OxidationIndustrial applications.Heterogeneous catalysis.Heterogeneous catalysisIndustrial applications.541/.393Clerici Mario G1656237Kholdeeva Oxana A1656238MiAaPQMiAaPQMiAaPQBOOK9910822251303321Liquid phase oxidation via heterogeneous catalysis4008985UNINA