05647nam 2200709 450 991082167380332120230807214439.01-119-00642-21-119-00622-81-119-00632-5(CKB)3710000000397660(EBL)1895902(SSID)ssj0001460052(PQKBManifestationID)12562797(PQKBTitleCode)TC0001460052(PQKBWorkID)11465735(PQKB)11732885(MiAaPQ)EBC1895902(DLC) 2014047257(Au-PeEL)EBL1895902(CaPaEBR)ebr11043787(CaONFJC)MIL770114(OCoLC)897510777(EXLCZ)99371000000039766020150509h20152015 uy 0engurcnu||||||||txtccrStereoselective multiple bond-forming transformations in organic synthesis /edited by Jean Rodriguez and Damien Bonne ; foreword by Dieter Enders ; contributors, Muriel Amatore [and thirty-nine others]Hoboken, New Jersey :Wiley,2015.©20151 online resource (472 p.)Description based upon print version of record.1-118-67271-2 Includes bibliographical references at the end of each chapters and index.Cover; Title Page; Copyright; Contents; List of Contributors; Foreword; Preface; Chapter 1 Definitions and Classifications of MBFTs; 1.1 Introduction; 1.2 Definitions; 1.3 Conclusion and Outlook; References; Part I Stereoselective Synthesis of Heterocycles; Chapter 2 Five-Membered Heterocycles; 2.1 Introduction; 2.2 Monocyclic Targets; 2.2.1 1,3-Dipolar Cycloaddition; 2.2.2 Michael Addition-Initiated Domino Process; 2.2.3 Multicomponent Reactions; 2.2.4 Carbohalogenation Reactions; 2.2.5 Radical Processes; 2.3 Fused Polycyclic Targets; 2.3.1 Cycloaddition Reactions2.3.2 Domino Cyclization Reactions 2.4 Bridged Polycyclic Targets; 2.5 Conclusion and Outlook; References; Chapter 3 Six-Membered Heterocycles; 3.1 Introduction; 3.2 Monocyclic Targets; 3.2.1 Nitrogen-Only Heterocycles; 3.2.2 Oxygen-Containing Heterocycles; 3.3 Fused Polycyclic Targets; 3.3.1 Nitrogen-Only Fused Polycyclic Targets; 3.3.2 Oxygen-Containing Fused Polycyclic Targets; 3.3.3 Sulfur-Containing Fused Polycyclic Targets; 3.4 Bridged Polycyclic Targets; 3.4.1 General Procedure for the Preparation of 2,6-DABCO-Derived Compounds 138; 3.5 Polycyclic Spiro Targets; 3.6 Summary and OutlookReferences Chapter 4 Other Heterocycles; 4.1 Introduction; 4.2 Synthesis of Medium-Sized Monocyclic, Fused and Bridged Polycyclic Heterocycles; 4.2.1 Ring Synthesis by Ring Transformation via Rearrangements/Ring Expansions; 4.2.2 Ring Synthesis by Annulation; 4.3 Summary and Outlook; References; Part II Stereoselective Synthesis of Carbocycles; Chapter 5 Three- and Four-Membered Carbocycles; 5.1 Introduction; 5.2 Cyclopropane Derivatives; 5.2.1 Organocatalysis and Related Reactions [Michael-Initiated Ring-Closure (MIRC) Reactions]; 5.2.2 Organometallics and Metal Catalysis5.2.3 Lewis Acid-Promoted Sequences 5.2.4 Pericyclic Domino Strategies; 5.2.5 Radical Domino Strategies; 5.3 Cyclobutane Derivatives; 5.3.1 Organocatalyzed Cyclobutanations; 5.3.2 Organometallics and Metal Catalysis; 5.3.3 Acid- or Base-Promoted Transformations; 5.3.4 Multicomponent Reactions (MCRs); 5.4 Summary and Outlook; References; Chapter 6 Five-Membered Carbocycles; 6.1 Introduction; 6.2 Monocyclic Targets; 6.2.1 Metal-Catalyzed Reactions; 6.2.2 Organocatalytic Reactions; 6.2.3 Miscellaneous Reactions; 6.3 Fused Polycyclic Targets; 6.3.1 Metal-Catalyzed Reactions6.3.2 Organocatalytic Reactions 6.3.3 Lewis Acid-Catalyzed Reactions; 6.3.4 Miscellaneous Reactions; 6.4 Bridged Polycyclic Targets; 6.5 Conclusion and Outlook; References; Chapter 7 Stereoselective Synthesis of Six-Membered Carbocycles; 7.1 Introduction; 7.2 Metal-Catalyzed Stereoselective Multiple Bond-Forming Transformations; 7.2.1 Introduction; 7.2.2 Cycloadditions; 7.2.3 Metal-Catalyzed Cascades as Formal [2+2+2] Cycloadditions; 7.2.4 Metal-Catalyzed Cycloisomerization Cascades; 7.3 Enantioselective Organocatalyzed Synthesis of Six-Membered Rings7.3.1 Organocatalyzed Miscellaneous ReactionsMake synthesis more green, efficient, and economical Stereoselective multiple bond-forming transformations (MBFTs), which use one synthetic operation to selectively create at least two chemical bonds, decrease the total number of steps and increase atom economy while maximizing structural complexity and the functional diversity. In consequence, they reduce the amount of waste, money, and negative environmental impact of chemical processes. Combining such an important research topic with green chemistry, this book helps chemists identify sustainable stereoselective MBFTs. Along with the discuOrganic compoundsSynthesisStereochemistryChemical reactionsOrganic compoundsSynthesis.Stereochemistry.Chemical reactions.547.2Rodriguez JeanBonne Damien1979-Enders DieterAmatore MurielMiAaPQMiAaPQMiAaPQBOOK9910821673803321Stereoselective multiple bond-forming transformations in organic synthesis4096432UNINA