04796nam 2200685Ia 450 991082040420332120240516061141.01-118-00539-21-283-09864-497866130986411-118-00537-6(CKB)2550000000032875(EBL)693209(OCoLC)732956391(SSID)ssj0000536814(PQKBManifestationID)11359158(PQKBTitleCode)TC0000536814(PQKBWorkID)10550662(PQKB)10159419(MiAaPQ)EBC693209(Au-PeEL)EBL693209(CaPaEBR)ebr10466749(CaONFJC)MIL309864(MiAaPQ)EBC7103409(Au-PeEL)EBL7103409(EXLCZ)99255000000003287520101027d2011 uy 0engur|n|---|||||txtccrFoundations of organic chemistry unity and diversity of structures, pathways, and reactions /by David R. Dalton1st ed.Hoboken, N.J. Wileyc20111 online resource (1436 p.)New York Academy of Sciences Description based upon print version of record.0-470-47908-6 Includes bibliographical references and index.FOUNDATIONS OF ORGANIC CHEMISTRY; CONTENTS; PREFACE; ACKNOWLEDGMENTS; PART I: BACKGROUND; CHAPTER 1: An Introduction to Structure and Bonding; A: THE SOURCES OF CARBON COMPOUNDS; I. How Do We Know a Material Is Pure?; B. MORE ABOUT HYDROCARBONS; I. Combustion-Heats of Reaction; C. ON THE NATURE OF THE CHEMICAL BOND; I. Ionic and Nonpolar Covalent Bonds; II. Polar Covalent Bonds; III. Orbital Hybridization; IV. Allotropes of Carbon; V. Combination of Ionic and Covalent Bonding; NOTICE TO THE STUDENT; ADDITIONAL PROBLEMS; REFERENCECHAPTER 2: An Introduction to Spectroscopy and Selected Spectroscopic Methods in Organic ChemistryA. GENERAL INTRODUCTION; B. X-RAY CRYSTALLOGRAPHY; C. PHOTON SPECTROSCOPY; I. General Introduction; II. UV and VIS Spectroscopy; III. IR Spectroscopy; IV. Raman Spectroscopy; V. Microwave Spectroscopy; VI. Magnetic Resonance Spectroscopy; a. NMR; b. ESR; D. MS; I. Creation of Ions in the Mass Spectrometer: The Ionization Chamber; II. The Separation of Ions by Mass: The Mass Analyzer; III. Detecting the Ions; ADDITIONAL PROBLEMS; REFERENCECHAPTER 3: Structure: The Nomenclature of Hydrocarbons and the Shape of Things to ComeA. INTRODUCTION; B. NOMENCLATURE AND SPECTROSCOPY; I. Alkanes; a. Acyclic Alkanes; b. Cyclic Alkanes; II. Alkenes, Arenes, and Alkynes; a. Alkenes; b. Arenes; c. Alkynes; C. PHYSICAL AND CHEMICAL PROPERTIES; OXIDATION AND REDUCTION OF HYDROCARBONS; I. The Concept of Homology; II. Oxidation and Reduction; a. Oxidation; b. Reduction; ADDITIONAL PROBLEMS; REFERENCES; CHAPTER 4: An Introduction to Dynamics; A. INTRODUCTION; B. REVIEW OF SOME ENERGY CONSIDERATIONS; C. THE BARRIER BETWEEN REACTANTS AND PRODUCTSCHAPTER 5: Classes of Organic Compounds-A Survey: An Introduction to Solvents and to Acids and Bases and to Computational ChemistryA. INTRODUCTION; B. GENERAL CHARACTERISTICS OF FUNCTIONAL GROUP PLACEMENT; C. THE FUNCTIONAL GROUPS AND THEIR NAMES; I. Hydrocarbons; a. Alkanes; b. Alkenes; c. Alkynes; d. Arenes; II. Alkyl and Aryl Halides; III. Alcohols and Phenols; IV. Ethers; V. Thiols, Thioethers, Disulfides, and Their Oxides; VI. Amines, Hydrazines, and Other Nitrogenous Materials; VII. Phosphines, Phosphonium Salts, and Other Phosphorus DerivativesVIII. An Introduction to Organometallic CompoundsThis book differs from other organic chemistry textbooks in that it is not focused purely on the needs of students studying premed, but rather for all students studying organic chemistry. It directs the reader to question present assumptions rather than to accept what is told, so the second chapter is largely devoted to spectroscopy (rather than finding it much later on as with most current organic chemistry textbooks). Additionally, after an introduction to spectroscopy, thermodynamics and kinetics, the presentation of structural information of compounds and organic families advances from hydNew York Academy of Sciences Chemistry, OrganicTextbooksOrganic compoundsChemistry, OrganicOrganic compounds.547Dalton David R1714348MiAaPQMiAaPQMiAaPQBOOK9910820404203321Foundations of organic chemistry4108088UNINA