02273nam 2200481 450 991081945350332120200520144314.01-5231-1494-01-119-18898-91-119-18900-4(CKB)4330000000009209(MiAaPQ)EBC4815052(DLC) 2017005375(Au-PeEL)EBL4815052(CaPaEBR)ebr11354731(CaONFJC)MIL994743(OCoLC)975224226(EXLCZ)99433000000000920920170127d2017 uy| 0engurcnu||||||||rdacontentrdamediardacarrierLimits of detection in chemical analysis /Edward VoigtmanHoboken, New Jersey :John Wiley & Sons,2017.1 online resource (409 pages) illustrations (some color)Chemical analysis series1-119-18899-7 1-119-18897-0 Includes bibliographical references and index.Background -- Chemical measurement systems and their errors -- The response, net response and content domains -- Traditional limits of detection -- Modern limits of detection -- Receiver operating characteristics -- Statistics of an ideal model CMS -- If only the true intercept is unknown -- If only the true slope is unknown -- If the true intercept and true slope are both unknown -- If only the population standard deviation is unknown -- If only the true slope is known -- If only the true intercept is known -- If all three parameters are unknown -- Bootstrapped detection limits in a real CMS -- Four relevant considerations -- Neyman-Pearson hypothesis testing -- Heteroscedastic noises -- Limits of quantitation -- The sampled step function -- The sampled rectangular pulse -- The sampled triangular pulse -- The sampled Gaussian pulse -- Parting considerations.Chemistry, AnalyticChemistry, Analytic.543/.19Voigtman Edward1949-1711396MiAaPQMiAaPQMiAaPQBOOK9910819453503321Limits of detection in chemical analysis4102678UNINA