03386nam 2200529 a 450 991081660460332120241003190337.01-61324-078-3(CKB)2560000000071249(EBL)3019555(SSID)ssj0000468469(PQKBManifestationID)12167767(PQKBTitleCode)TC0000468469(PQKBWorkID)10497964(PQKB)11409001(MiAaPQ)EBC3019555(Au-PeEL)EBL3019555(CaPaEBR)ebr10671120(OCoLC)704275145(EXLCZ)99256000000007124920081020d2009 uy 0engur|n|---|||||txtccrThe dipole-quadrupole theory of surface enhanced Raman scattering /A.M. Polubotko1st ed.New York Nova Science Publishersc20091 online resource (146 p.)Description based upon print version of record.1-60692-579-2 Includes bibliographical references (p. [129]-131) and index.Intro -- THE DIPOLE-QUADRUPOLE THEORY OF SURFACE ENHANCED RAMAN SCATTERING -- CONTENTS -- PREFACE -- INTRODUCTION -- MAIN SPECIFIC FEATURES OF THE SERS PHENOMENON -- SOME OF THE EXISTING THEORIES -- SOME PROPERTIES OF THE ELECTROMAGNETIC FIELD NEAR A ROUGH METAL SURFACE -- EXPRESSIONS FOR THE SER CROSS-SECTIONS OF ARBITRARY AND SYMMETRICAL MOLECULES -- SELECTION RULES FOR SYMMETRICAL MOLECULES -- CLASSIFICATION OF THE CONTRIBUTIONS BY THE DEGREE OF ENHANCEMENT -- MOST ENHANCED BANDS IN SERS -- CONTRIBUTIONS AND APPEARANCE OF FORBIDDEN BANDS IN THE SER SPECTRA OF SYMMETRICAL MOLECULES -- CONTRIBUTIONS CAUSED BY ONE MINOR AND ONE MAIN MOMENTS -- DISTURBANCE OF THE SYMMETRY OF MOLECULES UPON ADSORPTION AND TWO POSSIBLE MECHANISMS OF THE APPEARANCE OF FORBIDDEN BANDS IN THE SER SPECTRA -- ANALYSIS OF THE SER SPECTRA -- ANALYSIS OF THE SER SPECTRA OF MOLECULES WITH D3h AND D6h SYMMETRY GROUPS -- ANOMALIES IN THE SER SPECTRA OF BENZENE ABSORBED ON LITHIUM AND HEXA FLUOROBENZENE ABSORBED ON SILVER -- ELECTRODYNAMIC FORBIDDANCE OF THE QUADRUPOLE ENHANCEMENT MECHANISM INMOLECULES WITH CUBIC SYMMETRY GROUPS -- DISCUSSION OF EXPERIMENTAL RESULTS -- ABOUT THE ELECTRODYNAMIC FORBIDDANCE OF THE QUADRUPOLE SERS MECHANISM IN OTHER MOLECULES -- ANOMALIES OF THE SER SPECTRA OF SYMMETRICAL MOLECULES ADSORBED ON TRANSITION METAL SUBSTRATES -- POSSIBLE REASON OF THE COMPETITION OF THE RAMAN BANDS (INFLUENCE OF THE COMPLEX DIELECTRIC CONSTANT) -- SINGLE MOLECULE DETECTION BY THE SERS METHOD AND ITS RELATION TO THE QUADRUPOLES THEORY -- CHARGE TRANSFER ENHANCEMENT MECHANISM -- EXPLANATION OF EXPERIMENTAL PHENOMENA ACCOMPANYING SERS -- CONCLUSION -- APPENDIX 1:WAVE FUNCTIONS OF ARBITRARY MOLECULES -- APPENDIX 2:THE TABLES OF IRREDUCIBLE REPRESENTATIONS OF SOME POINT GROUPS -- REFERENCES -- INDEX.Raman effect, Surface enhancedQuadrupolesRaman effect, Surface enhanced.Quadrupoles.535.8/46Polubotko A. M1642033MiAaPQMiAaPQMiAaPQBOOK9910816604603321The dipole-quadrupole theory of surface enhanced Raman scattering3986537UNINA