04736nam 2200649 450 991081587770332120200520144314.01-118-96982-01-118-96981-21-118-96980-4(CKB)4330000000007772(EBL)4659671(Au-PeEL)EBL4659671(CaPaEBR)ebr11252448(CaONFJC)MIL950704(PPN)227225678(OCoLC)957655619(MiAaPQ)EBC4659671(EXLCZ)99433000000000777220160229h20162016 uy| 0engur|n|---|||||rdacontentrdamediardacarrierRheology and processing of polymer nanocomposites /edited by Sabu Thomas, Rene Muller, Jiji AbrahamHoboken, New Jersey :John Wiley & Sons, Incorporated,[2016]©20161 online resource (619 p.)Description based upon print version of record.1-118-96979-0 Includes bibliographical references and index.Cover; Title Page; Copyright; Contents; List of Contributors; Chapter 1 Materials for Polymer Nanocomposites; 1.1 Introduction; 1.2 Nanocomposite Framework; 1.2.1 Nanoscale Fillers; 1.2.2 Choice of Polymeric Matrices; 1.3 Recent Developments and Opportunities in the Area of Polymer Nanocomposites; 1.4 Challenges in the Area of Polymer Nanocomposites; 1.5 Relationships of Macroscopic Rheological Properties to Nanoscale Structural Variables; 1.6 Conclusion; Acknowledgments; References; Chapter 2 Manufacturing Polymer Nanocomposites; 2.1 Introduction; 2.2 Nanofillers2.2.1 Structure and Properties of Clay2.2.2 Structure and Properties of Organically Modified Clay; 2.2.3 Structure and Properties of CNTs; 2.3 Polymer Matrices; 2.4 Preparation of Nanocomposites; 2.4.1 In Situ Polymerization; 2.4.2 Solution Blending; 2.4.3 Melt Compounding; 2.4.4 Other Methods; 2.4.5 Supercritical CO2 Assisted Compounding; 2.5 Characterization; 2.6 Conclusions; References; Chapter 3 Rheology and Processing of Polymer Nanocomposites: Theory, Practice, and New Challenges; 3.1 Introduction; 3.2 Viscoelasticity of Nanocomposites; 3.2.1 General Trends; 3.2.2 Percolation Treshold3.2.3 Equilibrium Shear Modulus3.2.4 Validity of TTS Principle; 3.2.5 Quantifying Dispersion via Melt Rheology; 3.2.6 Payne Effect; 3.3 Flow Properties of Nanocomposites; 3.3.1 Steady-State Flow Curves: Relative Viscosity and Normal Stress Difference; 3.3.2 Flow-Induced Structure in Nanocomposites; 3.3.3 Elongational Flow; 3.4 Theory and Modeling of Nanocomposites Rheology; 3.4.1 Steady-State Viscosity; 3.4.2 Dynamic Rheology; 3.4.3 Elongational Rheology; 3.4.4 Payne Effect; 3.5 Processing of Nanocomposites; 3.5.1 Influence of Blending Procedure; 3.5.2 Usual Processing Methods3.5.3 New Processing Routes3.6 Conclusion and Futures Challenges; Acknowledgments; References; Chapter 4 Mixing of Polymers Using the Elongational Flow Mixer (RMX®); 4.1 Introduction; 4.2 Polymer Blends; 4.2.1 Capillary Number, Ca; 4.2.2 Rheology and Processing of Polymer Blends; 4.3 Polymer Nanocomposites; 4.3.1 Dispersion of Solid Additives; 4.4 Elongational Flow Mixer (RMX®); 4.4.1 RMX® Assembly and Operating Principles; 4.4.2 RMX® Flow Analysis by Numeric Simulation; 4.4.3 Estimation of Rheological Parameters in the RMX® via Capillary Rheometry; 4.5 RMX® Mixing of Polymer Blends4.5.1 Influence of the RMX® Parameters on Mixing4.5.2 Influence of the Viscosity Ratio, p; 4.5.3 Energy of Mixing: Performance Comparison; 4.5.4 Viscous Heating; 4.5.5 Effect of a Compatibilizer; 4.5.6 Rheology/Morphology Relationship; 4.6 Mixing of Polymer Nanocomposites; 4.7 Concluding Remarks; References; Chapter 5 Rheology and Processing of Polymer/Layered Silicate Nanocomposites; 5.1 Introduction; 5.2 Nanostructure Development; 5.2.1 Melt Intercalation; 5.2.2 Interlayer Structure of OMLFs and Intercalation; 5.3 Novel Compounding Methods for Delamination of OMLFs5.3.1 Solid-State Shear ProcessingRheologyPlasticityPolymersNanocomposites (Materials)Rheology.Plasticity.Polymers.Nanocomposites (Materials)620.1/92Thomas SabuMuller René1955-Abraham JijiMiAaPQMiAaPQMiAaPQBOOK9910815877703321Rheology and processing of polymer nanocomposites4015679UNINA