07475nam 2200685Ia 450 991081264220332120240313212726.01-84973-546-8(CKB)2670000000273238(EBL)1186165(OCoLC)814441525(SSID)ssj0000789014(PQKBManifestationID)12352704(PQKBTitleCode)TC0000789014(PQKBWorkID)10723979(PQKB)10977669(MiAaPQ)EBC1186165(Au-PeEL)EBL1186165(CaPaEBR)ebr10640420(CaONFJC)MIL871633(PPN)198470673(MiAaPQ)EBC7424803(Au-PeEL)EBL7424803(EXLCZ)99267000000027323820120815d2012 uy 0engur|n|---|||||txtccrSustainable preparation of metal nanoparticles methods and applications /edited by Rafael Luque, Rajender S. Varma1st ed.Cambridge Royal Society of Chemistry20121 online resource (243 p.)RSC Green ChemistryDescription based upon print version of record.1-84973-428-3 Includes bibliographical references and index.Sustainable Preparation of Metal Nanoparticles -- Contents -- Chapter 1 Introduction -- Acknowledgments -- References -- Chapter 2 Environmentally Friendly Preparation of Metal Nanoparticles -- 2.1 Introduction -- 2.2 Biogenic Nanoparticles -- 2.2.1 Biosynthesis of Nanoparticles -- 2.2.1.1 Fungi -- 2.2.1.2 Bacteria -- 2.2.1.3 Yeasts -- 2.2.1.4 Algae -- 2.2.1.5 Actinomycetes -- 2.2.1.6 Plants -- 2.2.1.7 Carbohydrates -- 2.2.1.8 Vitamins -- 2.3 Other Synthetic Approaches and Further Consideration -- 2.4 Conclusions -- References -- Chapter 3 Preparation of Metal Nanoparticles Stabilized by the Framework of Porous Materials -- 3.1 Introduction -- 3.2 Supported Metal Nanoparticles in Catalysis -- 3.2.1 Preparation Routes of Supported Metal Nanoparticles -- 3.2.1.1 Chemical Methods -- 3.2.1.2 Physical Methods -- 3.2.1.3 Physicochemical Methods -- 3.2.2 Types of Supported Metal Nanoparticles Depending on the Nature of Support Material -- 3.2.2.1 Zeolites, Silica-Based Materials -- 3.2.2.2 Metal Organic Frameworks (MOFs) -- 3.2.2.3 Hydroxyapatite (HAp) -- 3.2.2.4 Hydrotalcite (HT) -- 3.3 Future Goals Toward Modern Supported Metal Nanoparticles Catalysts -- References -- Chapter 4 Energy Conversion and Storage through Nanoparticles -- 4.1 Introduction -- 4.1.1 Quantum Con nement of Nanoparticles -- 4.1.2 Synthesis of Quantum Dots -- 4.1.3 The Basic Working Principles of Nanostructured Solar Cells -- 4.2 Quantum Dot Solar Cells -- 4.3 Hot Carriers and Multiple Exciton Generation Effects -- 4.4 Nanoparticle-Based Li Ion Battery -- 4.4.1 Introduction -- 4.4.2 Cathode -- 4.4.3 Anode -- 4.5 Summary -- Acknowledgement -- References -- Chapter 5 The Green Synthesis and Environmental Applications of Nanomaterials -- 5.1 Green Chemistry of the Synthesis of Nanomaterials -- 5.1.1 TiO2 Nanomaterials -- 5.1.2 Other Semiconductors.5.1.3 Metal and Metal Oxides Nanoparticles -- 5.1.4 Metallic and Bimetallic Nanoparticles -- 5.2 Environmental Applications of Nanomaterials -- 5.2.1 Photocatalytic Degradation of Organic Pollutants in Air, Water, and Soil -- 5.2.2 Dehalogenation using Metallic and Bimetallic Nanoparticles -- 5.2.2.1 Metallic Nanoparticles -- 5.2.2.2 Bimetallic Nanoparticles -- 5.2.2.2.1 Iron/Palladium Bimetallic Nanoparticles. -- 5.2.2.2.2 Iron/Nickel Bimetallic Nanoparticles. -- 5.2.2.2.3 Iron/Copper Bimetallic Nanoparticles. -- 5.2.2.2.4 Other Bimetallic Nanoparticles. -- 5.2.3 Photocatalysis for the Disinfection of Drinking Water -- 5.3 Immobilization of Nanoparticles for Sustainable Environmental Applications -- 5.3.1 Need for Particle Immobilization -- 5.3.2 Goals and Strategies of Particle Immobilization -- 5.3.3 Application Examples of Immobilized Systems using Nanoparticles -- 5.4 Conclusions -- Acknowledgements -- References -- Chapter 6 Green Nanotechnology - a Sustainable Approach in the Nanorevolution -- 6.1 Introduction -- 6.2 Synthesis of Gold Nanoparticles Using Phytochemicals -- 6.2.1 Gold Nanoparticles from Cinnamon Phytochemicals (Cin-AuNPs) -- 6.2.2 Gold Nanoparticles from Cumin Phytochemicals (Cum-AuNPs) -- 6.2.3 Gold Nanoparticles from Tea Phytochemicals (T-AuNPs) -- 6.3 Dual Roles of Reduction and Stabilization -- 6.4 Biomedical Applications -- 6.4.1 Thereapeutic Efficacy of EGCG-198AuNPs -- 6.5 Sustainability -- Acknowledgements -- References -- Chapter 7 Biofuels and High Value Added Chemicals from Biomass Using Sustainably Prepared Metallic and Bimetallic Nanoparticles -- 7.1 Introduction -- 7.2 Synthetic Procedures -- 7.2.1 Synthesis of Metallic Nanoparticles -- 7.2.2 Synthesis of Bimetallic Nanoparticles -- 7.3 Applications of Metallic and Bimetallic Nanoparticles for Biomass Conversion -- 7.3.1 Oxidation of Alcohols and Sugars.7.3.2 Conversion of Sugars -- 7.3.3 Production of Hydrocarbons -- 7.3.4 Conversion of Cellulose -- 7.3.5 Decarboxylation of Fatty Acids -- 7.3.6 Biodiesel Production -- 7.3.7 Design of Fuel Cells -- 7.4 Future Perspectives -- References -- Chapter 8 Toxicology of Designer/Engineered Metallic Nanoparticles -- 8.1 Introduction -- 8.2 Biophysicochemical Interactions (Nano/Bio Interface) -- 8.2.1 Engineered Nanoparticles -- 8.2.1.1 Physicochemical Factors -- 8.2.1.2 Biological Factors -- 8.2.1.3 Environmental Factors -- 8.3 Designer Metal-Oxide Nanoparticles (Doped Metal-Oxide Nanoparticles) -- 8.4 Research Gaps and Collaboration Needed -- 8.5 Summary and Outlook -- Acknowledgements -- References -- Chapter 9 Introduction to Nanosafety -- 9.1 Introduction: Safety and Nanoparticles -- 9.1.1 Risks in Handling Nanoparticles -- 9.1.2 Factors that In uence Nanoparticle Toxicity -- 9.1.3 Inhalation of Engineered Nanoparticles -- 9.2 Risk-Reduction Strategies -- 9.2.1 Prevention through Design and Good Laboratory Practices -- 9.3 Safety and Prevention in the Nanotechnology Laboratory -- 9.3.1 Control Banding -- 9.3.2 Nanoparticle Emission Assessment Technique -- 9.4 Conclusions -- References -- Subject Index.This timely publication bridges and presents the latest trends and updates in three hot topics of current and future society: nanomaterials, energy and environment. It provides the state-of-the-art as well as current challenges and advances in the sustainable preparation of metal nanoparticles and their applications. The book fills a critical gap in a multidisciplinary area of high economic, social and environmental importance. Currently, there are no books published that deal with these ever increasing important topics, as most books in this area focus on a particular topic (eg. nanomaterialsRSC Green ChemistryNanoparticlesMetallographySustainabilityNanoparticles.Metallography.Sustainability.620.1/699620.1699Luque Rafael884952Varma Rajender S93003MiAaPQMiAaPQMiAaPQBOOK9910812642203321Sustainable preparation of metal nanoparticles3942424UNINA