05057nam 2200721 450 991080966270332120230116163845.01-118-78824-91-118-78830-31-118-78844-3(CKB)2550000001256705(EBL)1662194(SSID)ssj0001180140(PQKBManifestationID)11634792(PQKBTitleCode)TC0001180140(PQKBWorkID)11186454(PQKB)10274239(DLC) 2013046295(Au-PeEL)EBL1662194(CaPaEBR)ebr10856817(CaONFJC)MIL588428(Au-PeEL)EBL7147552(PPN)190552727(OCoLC)863383849(MiAaPQ)EBC1662194(EXLCZ)99255000000125670520140414h20142014 uy 0engur|n|---|||||txtccrThe organometallic chemistry of the transition metals /Robert H. Crabtree6th edition.Hoboken, New Jersey :Wiley,2014.©20141 online resource (522 p.)Description based upon print version of record.1-118-13807-4 1-306-57177-4 Includes bibliographical references at the end of each chapters and index.Cover; Title page; Copyright page; Contents; Preface; List of Abbreviations; 1: Introduction; 1.1 Why Study Organometallic Chemistry?; 1.2 Coordination Chemistry; 1.3 Werner Complexes; Stereochemistry; Chelate Effect; Werner's Coordination Theory; 1.4 The Trans Effect; 1.5 Soft versus Hard Ligands; 1.6 The Crystal Field; High Spin versus Low Spin; Inert versus Labile Coordination; Jahn-Teller Distortion; Low- versus High-Field Ligands; Magnetism and Nuclearity; Other Geometries; Isoconfigurational Ions; 1.7 The Ligand Field; 1.8 The sdn Model and Hypervalency; 1.9 Back BondingFrontier Orbitalsπ-Donor Ligands; 1.10 Electroneutrality; Oxidation State Trends; Periodic Trends; 1.11 Types of Ligand; Ambidentate Ligands; Actor and Spectator Ligands; Multifunctional Ligands29; Organometallic versus Coordination Compounds; References; Problems; 2: Making Sense of Organometallic Complexes; 2.1 The 18-Electron Rule; Covalent Electron Counting Model; Ionic Electron Counting Model; Electron Counts for Common Ligands and Hapticity; Bridging Ligands; Zero-Electron Ligands; 2.2 Limitations of The 18-Electron Rule; Steric Stabilization of Reactive SpeciesKinetic Stability from Bulky SubstituentsPreparation of Metal Alkyls; Cyclometalation; Oxidative Addition; Insertion; Bridging Alkyls; Metalacycles; η1 and η2-Acyl and Vinyls; 3.2 Other σ-Bonded Ligands; Group 14 Elements; Groups 15-17; Oxophilicity and Functional Group Tolerance; 3.3 Metal Hydrides; Characterization; Synthesis; Reactions; Hydricity; Bridging Hydrides; 3.4 Sigma Complexes; Dihydrogen Complexes20; Characterization; Reactions; Agostic Species; 3.5 Bond Strengths; Supramolecular Interactions; References; Problems; 4: Carbonyls, Phosphines, and Substitution; 4.1 Metal CarbonylsPreparation of CarbonylsReactions of Carbonyls; Bridging Carbonyls; Isonitriles; Thiocarbonyls; Nitrosyls; Cyanide; Other CO Analogs; 4.2 Phosphines; Structure and Bonding; Tolman Electronic Parameter and Cone Angle; Bite Angle; 4.3 N-Heterocyclic Carbenes (NHCs); 4.4 Dissociative Substitution; Kinetics; Stereochemistry and Trans Effect; Electronic and Steric Factors; 4.5 Associative Substitution; Kinetics; Trans Effect; Solvent Participation; Ligand Rearrangements; 4.6 Redox Effects and Interchange Substitution; 17e and 19e Species; The Interchange Mechanism; 4.7 Photochemical SubstitutionCarbonylsFully updated and expanded to reflect recent advances, the sixth edition of this bestselling text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features: New sections on Multifunctional Ligands, Oxidation Catalysis, and Green ChemistryExpOrganometallic chemistryOrganotransition metal compoundsCompostos organometàl·lics de transicióthubLlibres electrònicsthubOrganometallic chemistry.Organotransition metal compounds.Compostos organometàl·lics de transició547/.056Crabtree Robert H.1948-66039MiAaPQMiAaPQMiAaPQBOOK9910809662703321Organometallic chemistry of the transition metals78832UNINA