05342nam 2200649 450 991080910930332120230803195600.01-118-79279-31-118-79283-11-118-79280-7(CKB)2670000000547024(EBL)1651187(SSID)ssj0001212533(PQKBManifestationID)11718083(PQKBTitleCode)TC0001212533(PQKBWorkID)11225739(PQKB)11537365(OCoLC)878149555(MiAaPQ)EBC1651187(Au-PeEL)EBL1651187(CaPaEBR)ebr10851638(CaONFJC)MIL584539(OCoLC)874321198(EXLCZ)99267000000054702420140406h20142014 uy 0engur|n|---|||||txtccrProgress in inorganic chemistryVolume 58 /edited by Kenneth D. KarlinHoboken, New Jersey :John Wiley & Sons,2014.©20141 online resource (525 p.)Progress in Inorganic ChemistryDescription based upon print version of record.1-118-79282-3 Includes bibliographical references and indexes.Progress in Inorganic Chemistry; Contents; Chapter 1: Tris(dithiolene) Chemistry: A Golden Jubilee; I. INTRODUCTION; II. LIGANDS; A. Arene Dithiolates; B. Alkene Dithiolates; 1. Sulfur; 2. Carbon Disulfide; 3. Phosphorus Pentasulfide; 4. Other Sulfur Sources; C. Dithiones; III. COMPLEXES; A. Metathesis; B. Redox; C. Transmetalation; IV. STRUCTURES; A. Beginnings; 1. Neutral Complexes; 2. Reduced Complexes; 3. Isoelectronic Series; B. Redux; 1. Trigonal Twist; 2. Dithiolene Fold; 3. Oxidized Ligands; V. THEORY; A. Hückel; B. Fenske-Hall; VI. ELECTROCHEMISTRY; VII. MAGNETOMETRYVIII. SPECTROSCOPYA. Vibrational; B. Electronic; C. Nuclear Magnetic Resonance; D. Electron Paramagnetic Resonance; 1. Spin Doublet; 2. Spin Quartet; E. X-Ray Absorption Spectroscopy; 1. Metal Edges; 2. Sulfur K-Edge; F. Mössbauer; IX. SUMMARY; A. Group 4 (IV B); B. Group 5 (V B); C. Group 6 (VI B); D. Group 7 (VII B); E. Group 8 (VIII B); F. Group 9 (VIII B) and Beyond; X. CONCLUSIONS; ACKNOWLEDGMENTS; ABBREVIATIONS; REFERENCES; Chapter 2: How to Find an HNO Needle in a (Bio)-Chemical Haystack; I. INTRODUCTION; A. Azanone and Its Elusive Nature; II. CHEMICAL AND BIOLOGICAL RELEVANCE OF HNOA. Chemical Relevance of HNO as a Reaction Intermediate1. HNO Donors; 2. Reactions in Which Azanone Has Been Proposed As an Intermediate; B. Azanone Biological Relevance: Friend or Foe?; III. AZANONE DETECTION METHODS; A. Trapping vs Real-Time Detection; B. Colorimetric Methods; 1. Manganese Porphyrins as Trapping Agents; 2. Miscellaneous Colorimetric Methods; C. Thiol Blocking; D. Phosphines; E. Electron Paramagnetic Resonance; F. Mass Spectrometry; G. Fluorescence-Based Methods; H. Electrochemical Real-Time Detection; IV. CONCLUSIONS AND FUTURE PERSPECTIVES; ACKNOWLEDGMENTS; ABBREVIATIONSREFERENCESChapter 3: Photoactive Metal Nitrosyl and Carbonyl Complexes Derived from Designed Auxiliary Ligands: An Emerging Class of Photochemotherapeutics; I. INTRODUCTION; II. METAL NITROSYL AND CARBONYL COMPLEXES AS NITRIC OXIDE AND CARBON MONOXIDE DONORS; III. PHOTOACTIVE METAL NITROSYL COMPLEXES; A. Metal Nitrosyl Complexes With Monodentate Ligands; B. Metal Nitrosyl Complexes Derived from Polydentate Ligands With Extended Structure; C. Metal Nitrosyl Complexes Derived from Polydentate Ligands With Carboxamide Groups; D. Polymer Matrices With Incorporated Metal Nitrosyl ComplexesIV. PHOTOACTIVE METAL CARBONYL COMPLEXESA. Homoleptic Metal Carbonyls; B. Metal Carbonyl Complexes With Amino Acid Ligands; C. Manganese(I) Tricarbonyl Complexes; D. Metal Carbonyl Complexes Derived from Polydentate Ligands; V. CONCLUSION; ACKNOWLEDGMENT; ABBREVIATIONS; REFERENCES; Chapter 4: Metal-Metal Bond-Containing Complexes as Catalysts for C-H Functionalization; I. INTRODUCTION; A. Overview of Metal-Metal Multiple Bonds; B. Early Examples of M-M Bond-Containing Complexes in Catalysis; C. Metal-Metal Bonding; D. Structural Manifestations of M-M BondingE. Physical and Spectroscopic Properties of M-M Bond-Containing Compounds This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 58 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers. The chapters of this volume are devoted to the following topics: Tris(dithiolene) Chemistry: A Golden Jubilee How to find an HNO needle in a (bio)-chemical Haystack Photoactive Metal Nitrosyl and Carbonyl Complexes Derived from Designed AuxiliaryProgress in Inorganic ChemistryChemistry, InorganicChemistry, Inorganic.546.7Karlin Kenneth D.MiAaPQMiAaPQMiAaPQBOOK9910809109303321Progress in inorganic chemistry790883UNINA03668nam 22005053 450 991100655890332120230403184058.01-5231-3030-X1-282-99144-29786612991448(CKB)3390000000015341(MiAaPQ)EBC5266440(Au-PeEL)EBL5266440(CaONFJC)MIL299144(OCoLC)747720974(Exl-AI)5266440(EXLCZ)99339000000001534120210901d2010 uy 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierRadioelement Mapping1st ed.Lanham :International Atomic Energy Agency,2010.©2010.1 online resource (123 pages)92-0-106110-2 Cover -- Foreword -- Contents -- 1. Introduction -- 1.1. Background -- 1.2. Objective -- 1.3. Scope -- 1.4. Structure -- 2. Benefits And Uses Of A Global Radioelement Baseline Database -- 2.1. Uranium Exploration -- 2.2. Uranium Mine And Mill Waste -- 2.3. Nuclear Emergency Preparedness -- 2.4. Geoscience Applications -- 2.5. Health And Environmental Applications -- 3. Methodology To Establish A Radioelement Base Lineusing Gamma Spectrometry -- 3.1. Principles Of Gamma Ray Spectrometry -- 3.2. Establishment Of Gamma Ray Spectrometer Calibration Facilities -- 3.3. Standardization Among Gamma Ray Spectrometer Calibration Facilities -- 3.4. Back Calibration Of Existing Surveys -- 3.5. Merging Of Surveys -- 3.6. Responses Of Anthropogenic Radioelements -- 4. Methodology To Establish Radioelement Baselines Using Geochemistry -- 4.1. Principles Of Applied Geochemistry -- 4.2. Analytical Methods -- 4.3. Media Types -- 4.4. Data Management And Interpretation -- 5. Status Of Radioelement Mapping -- 5.1. Airborne Gamma Ray Spectrometric Surveys -- 5.2. Sample Based Geochemical Surveys -- 6. Application Of Radioelement Baselines To Uranium Exploration, Mining, Milling And Remediation -- 6.1. Use Of Baselines To Aid In Uranium Exploration -- 6.2. Baselines Prior To Mine Or Mill Construction -- 6.3. Monitoring During Operations -- 6.4. Assessment Of Contamination Episodes -- 6.5. Use Of Baselines To Monitor The Remediation Process -- 7. Conclusions -- Appendix I - Worldwide Coverage And Catalogue Of Public Domaingamma Spectrometry Surveys -- Appendix II - Worldwide Gamma Ray Spectrometer Calibration Sites -- References -- Bibliography -- Contributors To Drafting And Review.The publication is based on the coordinated work of highly experienced, international experts with the aim of developing a global radioelement map with comparable results from different states. It is intended to support the identification of prospective areas for uranium exploration and mining, and also for environmental actions associated with uranium production and other human activities. The utility of the publication is expected to motivate many states to standardize the status of their radioelement mapping based on the global development and experience.RADIOELEMENT MAPPINGGamma ray spectrometryGenerated by AIGeochemical surveysGenerated by AIGamma ray spectrometryGeochemical surveysAgency International Atomic Energy1351396Agency International Atomic Energy1351396MiAaPQMiAaPQMiAaPQBOOK9911006558903321Radioelement Mapping4391696UNINA