02327nam 2200529 a 450 991077830970332120200520144314.01-78801-830-31-84755-092-4(CKB)1000000000791329(EBL)1185543(SSID)ssj0000379365(PQKBManifestationID)11271602(PQKBTitleCode)TC0000379365(PQKBWorkID)10366565(PQKB)11751198(MiAaPQ)EBC1185543(Au-PeEL)EBL1185543(CaPaEBR)ebr10621251(OCoLC)843641287(PPN)198478321(EXLCZ)99100000000079132920040702d2003 uy 0engur|n|---|||||txtccrFree energy relationships in organic and bio-organic chemistry[electronic resource] /Andrew WilliamsCambridge, U.K. RSCc20031 online resource (313 p.)Description based upon print version of record.0-85404-676-3 Includes bibliographical references and index.01PRELIM; 02PREFA; 03CONT; 04CHAP01; 05CHAP02; 06CHAP03; 07CHAP04; 08CHAP05; 09CHAP06; 10CHAP07; 11APPEN1; 12APPEN2; 13APPEN3; 14APPEN4; 15INDEXIntroducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for thLinear free energy relationshipLinear free energy relationship.547.139Williams Andrew1937-1525059MiAaPQMiAaPQMiAaPQBOOK9910778309703321Free energy relationships in organic and bio-organic chemistry3766185UNINA