03205nam 22006255 450 991076816410332120231129101903.09783031322501(electronic bk.)978303132249510.1007/978-3-031-32250-1(MiAaPQ)EBC30551654(Au-PeEL)EBL30551654(OCoLC)1381094105(DE-He213)978-3-031-32250-1(BIP)090181838(PPN)270612521(CKB)26769600300041(EXLCZ)992676960030004120230523d2023 u| 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierModes of Cooperative Effects in Dinuclear Complexes /edited by Philippe Kalck1st ed. 2023.Cham :Springer International Publishing :Imprint: Springer,2023.1 online resource (241 pages)Topics in Organometallic Chemistry,1616-8534 ;70Print version: Kalck, Philippe Modes of Cooperative Effects in Dinuclear Complexes Cham : Springer International Publishing AG,c2023 9783031322495 Dinuclear Reactivity of One Metal Exalted by the Second One -- Chemical Transformations in Heterobimetallic Complexes Facilitated by the Second Coordination Sphere -- Role of a Redox-Active Ligand Close to a Dinuclear Activating Framework -- Bimetallic oxidative addition or reductive elimination on M-M’ -- Magnetism in Binuclear Compounds: Theoretical Insights.This book presents recent advances in dinuclear complexes in which the metal-metal cooperative effect operates for obtaining substrate activation and high performance catalysts. Catalysis continues to be a fast expanding area to design efficient tools in synthesis and in industrial chemistry. It allows performing syntheses with short reaction times, atom economy, reduced consumption of energy and loss of reagents, and low level of wastes. Dinuclear complexes are known to be more efficient than the mononuclear analogues for the reaction rates and the selectivities. This book analyses the latest research, focusing on the key concepts, in building and using these dinuclear complexes. The book is aimed at researchers, graduate students and chemists at all levels in academia and industry.Topics in Organometallic Chemistry,1616-8534 ;70Organometallic chemistryChemical structureCatalystsOrganometallic ChemistryStructure And BondingCatalyst SynthesisOrganometallic chemistry.Chemical structure.Catalysts.Organometallic Chemistry.Structure And Bonding.Catalyst Synthesis.541.2242541.2242Kalck Philippe1452894Kalck PhilippeedtMiAaPQMiAaPQMiAaPQ9910768164103321Modes of Cooperative Effects in Dinuclear Complexes3655317UNINA