03338nam 22006615 450 991073947790332120251113193533.09783031367359303136735910.1007/978-3-031-36735-9(MiAaPQ)EBC30683651(Au-PeEL)EBL30683651(DE-He213)978-3-031-36735-9(PPN)272261351(CKB)27962373700041(OCoLC)1393308654(EXLCZ)992796237370004120230809d2023 u| 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierHeterocycles from Carbenes and Nitrenes Methods, Reactions and Synthetic Applications /edited by Michael P. Doyle, Xinfang Xu1st ed. 2023.Cham :Springer International Publishing :Imprint: Springer,2023.1 online resource (381 pages)Topics in Heterocyclic Chemistry,1861-9290 ;59Print version: Doyle, Michael P. Heterocycles from Carbenes and Nitrenes Cham : Springer International Publishing AG,c2023 9783031367342 Photo-induced Carbene Transformations to Heterocycles -- Heterocycles from Onium Ylides -- Heterocycles from Sulfur Ylides -- Heterocycles from Cascade Reactions via Carbene gem-difunctionalization -- Cyclopropanation of Heterocycles -- Heterocycles from Cycloaddition Reaction -- Alkynes as Carbene Precursors for the Synthesis of Heterocycles -- Heterocycles from Donor/Donor Carbenes -- Heterocycles by Nitrene Transfer Reactions.This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.Topics in Heterocyclic Chemistry,1861-9290 ;59ChemistryChemistry, OrganicHeterogeneous catalysisMaterialsChemical SynthesisOrganic ChemistryChemistryHeterogeneneous CatalysisChemistry.Chemistry, Organic.Heterogeneous catalysis.Materials.Chemical Synthesis.Organic Chemistry.Chemistry.Heterogeneneous Catalysis.547.59Doyle Michael P.1949-66351Xu XinfangProfessor1431609MiAaPQMiAaPQMiAaPQBOOK9910739477903321Heterocycles from carbenes and nitrenes3574229UNINA