03020nam 2200457Ia 450 991071126090332120180711120938.0GOVPUB-C13-e3867f03f2279c337479d4f190518f84(CKB)5470000002481411(OCoLC)809181763(OCoLC)995470000002481411(EXLCZ)99547000000248141120120905d2012 ua 0engtxtrdacontentnrdamediancrdacarrierAccelerated weathering of firefighter protective clothing delineating the impact of thermal, moisture, and ultraviolet light exposures /Shonali Nazare and Rick D. Davis, Jyun-Siang Peng and Joannie ChinGaithersburg, MD :U.S. Dept. of Commerce, National Institute of Standards and Technology,2012.1 online resource (30 pages) illustrationsNIST technical note ;1746"CODEN: NTNUE2"--Page iii."June 2012."Contributed record: Metadata reviewed, not verified. Some fields updated by batch processes.LRC Report No. 46688.Includes bibliographical references.Previously, the chemical and mechanical deterioration of polyaramid and polybenzimidazole-based protective clothing fabrics that resulted from concurrent thermal, moisture, and simulated sunlight exposure were quantified. This manuscript discusses the individual impacts of ultraviolet (UV) light irradiation at ambient conditions and moisture and elevated temperature in the absence of irradiation on the performance properties of outer shell (OS) fabrics used in firefighters' turnout gear. The mechanical properties which most often determine the protective performance of firefighters' turnout gear, including unidirectional stretching, tear resistance, and elastic properties, were tested before and after an accelerated weathering process. To assess and compare the protective performance of outer shell fabric samples against UV irradiation, the UV protection factor (UPF) was calculated. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy analysis was used to elucidate the chemical changes induced by the weathering process. The data suggests that the deterioration in the physical properties of polyaramids and polybenzimidazoles are mainly due to photo-oxidative reactions, which result in chemical and mechanical deterioration of the fabrics. However, the UV exposure has a lesser detrimental effect on the UPF value.Accelerated weathering of firefighter protective clothing Nazaré Shonali1400409Chin JoannieDavis Rick D.Peng Jyun-SiangNFPNFPOCLCONFPOCLCQBOOK9910711260903321Accelerated weathering of firefighter protective clothing3525507UNINA