05160nam 2200601Ia 450 991067790340332120230801221453.03-527-64179-31-283-51406-097866138265103-527-64178-53-527-64180-7(CKB)2670000000133950(EBL)827028(OCoLC)772537351(SSID)ssj0000611974(PQKBManifestationID)11407114(PQKBTitleCode)TC0000611974(PQKBWorkID)10666260(PQKB)11587248(MiAaPQ)EBC827028(EXLCZ)99267000000013395020110728d2012 uy 0engur|n|---|||||txtccrGreen corrosion chemistry and engineering[electronic resource] opportunities and challenges /edited by Sanjay K. SharmaWeinheim Wiley-VCH ;Chichester John Wiley [distributor]20121 online resource (431 p.)"With a foreword by Nabuk Okon Eddy".3-527-32930-7 Green Corrosion Chemistry and Engineering; 1.5 Corrosion Rust; Contents; Foreword; Preface; Acknowledgments; About The Editor; List of Contributors; 1 Basics of Corrosion Chemistry; 1.1 Introduction; 1.2 Metallic Corrosion; 1.2.1 Basic Processes; 1.2.2 Potential-pH Diagram; 1.2.3 Corrosion Potential; 1.2.4 Anodic Metal Dissolution; 1.2.5 Cathodic Oxidant Reduction; 1.3 Metallic Passivity; 1.3.1 Passivity of Metals; 1.3.2 Passivation of Metals; 1.3.3 Passive Films; 1.3.4 Chloride-Breakdown of Passive Films; 1.4 Localized Corrosion; 1.4.1 Pitting Corrosion; 1.4.2 Crevice Corrosion1.4.3 Potential-Dimension Diagram1.5.1 Rust in Corrosion; 1.5.2 Ion-Selective Rust; 1.5.3 Electron-Selective Rust; 1.5.4 Redox Rust; 1.6 Atmospheric Corrosion; 1.6.1 Atmospheric Corrosion Chemistry; 1.6.2 Weathering Steel Corrosion; 1.6.3 Anticorrosion Rust; 1.7 Concluding Remarks; References; 2 Corrosion and Electrochemistry; 2.1 Introduction; 2.2 Thermodynamics and the Stability of Metals; 2.3 Free Energy and Electrode Potential; 2.4 Electrode Potential Measurements; 2.5 Equilibrium Electrode Potentials; 2.6 Use of Pourbaix Diagrams; 2.7 Dynamic Electrochemical Processes2.8 Concentration PolarizationReferences; Further Reading; 3 Application of Microelectrochemical Techniques in Corrosion Research; 3.1 Introduction; 3.2 Scanning Vibrating Electrode Technique; 3.2.1 The Technique and Principle; 3.2.2 Local Dissolution Behavior of the Welding Zone of Pipeline Steel; 3.2.3 Effects of Mill Scale and Corrosion Product Deposit on Corrosion of the Steel; 3.3 Localized Electrochemical Impedance Spectroscopy; 3.3.1 The Technique and Principle; 3.3.2 Corrosion of Steel at the Base of the Coating Defect3.3.3 Microscopic Metallurgical Electrochemistry of Pipeline Steels3.3.4 Characterization of Local Electrochemical Activity of a Precracked Steel Specimen; 3.4 Scanning Kelvin Probe; 3.4.1 The Technique and Principle; 3.4.2 Monitoring the Coating Disbondment; 3.5 Conclusive Remarks; Acknowledgments; References; 4 Protective Coatings: an Overview; 4.1 Introduction; 4.2 Selection of Paint Coatings; 4.3 Classification of Various Coatings; 4.4 Chemistry of Resins; 4.4.1 Alkyd Resins; 4.4.2 Modified Alkyds; 4.4.3 Epoxies; 4.4.4 Urethanes; 4.4.5 Isocyanates; 4.4.6 Aliphatic Isocyanates4.4.7 Polyols4.4.8 Acrylic Urethanes; 4.4.9 Moisture-Cured Polyurethanes; 4.4.10 Zinc-Based Coatings; 4.5 High-Performance Coatings; 4.5.1 The 100% Solventless Epoxies; 4.5.2 Concept of Underwater Coatings; 4.5.3 Polyvinylidenedifluride Coatings; 4.5.4 Polysiloxane Coatings; 4.5.5 Fire-Resistant Coatings; 4.5.6 Organic-Inorganic Hybrid (OIH) Waterborne Coatings; 4.6 Surface Preparation; 4.7 Paint Application; 4.8 Importance of Supervision, Inspection, and Quality Control during Paint Coatings; 4.9 Training and Certification Courses; 4.10 Summary; References5 New Era of Eco-Friendly Corrosion InhibitorsWith its unique focus on specifically addressing the problems for societies and economies associated with corrosion and their solution, this book provides an up-to-date overview of the progress in corrosion chemistry and engineering. International experts actively involved in research and development place particular emphasis on how to counter the economic and environmental consequences of corrosion with the help of science and technology, making this a valuable resource for researchers as well as decision makers in industry and politics. Further major parts of the book are devoted to corrosioCorrosion and anti-corrosivesEngineeringCorrosion and anti-corrosives.Engineering.620.11223Sharma Sanjay Kumar907812MiAaPQMiAaPQMiAaPQBOOK9910677903403321Green corrosion chemistry and engineering3070455UNINA