05488nam 2200649Ia 450 991064312260332120170815114114.01-282-30808-497866123080860-470-14524-20-470-14545-5(CKB)1000000000376304(EBL)468908(SSID)ssj0000299749(PQKBManifestationID)11212862(PQKBTitleCode)TC0000299749(PQKBWorkID)10243469(PQKB)11307601(MiAaPQ)EBC468908(OCoLC)181161102(EXLCZ)99100000000037630419880519d1989 uy 0engur|n|---|||||txtccrFormation of bonds to C, Si, Ge, Sn, PbPart 2[electronic resource] /founding editor, J.J. Zuckerman ; editor, A.P. HagenNew York, N.Y. VCHc19891 online resource (541 p.)Inorganic reactions and methods ;10/2Description based upon print version of record.0-471-18661-9 Includes bibliographical references and indexes.Inorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 10; The Formation of Bonds to the Group-IVB Elements (C, Si, Ge, Sn, Pb) (Part 2); Formation of Bonds between Elements of Group IVB (C, Si, Ge, Sn, Pb) and Group IllB (B, Al, Ga, In, TI); Introduction; Formation of Carbon-Boron Bonds; Industrial Preparation of Boron Carbide.; Industrial Preparation of Boron-Carbide Powders.; Densification of Powders.; Laboratory Preparation of Boron Carbide (from the Elements or Boron Halides)by Direct Synthesis.by Reduction of BCI3 by H2 in the Presence of Carbon.; by Chemical Vapor Deposition (CVD).; by Reduction of Boric Anhydride at Low Temperatures.; by Plasma Synthesis.; by Physical Vapor Deposition (PVD).; Crystal Growth.; Boron Carbide Fibers.; from Boron Halides; by Reaction with More Polar Organometallics (Metal-Metal Exchange, Excluding Amino-, Oxo- and Thioboron Halides).; by Reaction with an Organoboron-Active-Metal Reagent.; by Substitution of Hydrocarbons.; by Addition to Olefinic and Acetylenic Linkages (Haloboration).; by Reaction with Diazoalkanes.by Redistribution Reactions with Organoboranes.from Boron Alkoxides with More Polar Organometallics; Alkyl- and Arylboronic Acids.; Alkyl- and Arylborinic Acids.; to form Organoboranes with Three B-C Bonds.; from Boron Hyrides; by Addition to Olefins and Acetylenes (Hydroboration).; by Addition to Polar Organometallics to Form Organoborates.; by Redistribution of Organoboron Hydrides.; from Organoboranes; by Redistribution.; by lsomerization and Displacement.; by Pyrolytic Elimination of H2.; by Addition of Olefinic and Acetylenic Linkages (Carboboration).; from Larger Boranes and Carboranesby Hydroboration of a Polyborane.by Modified Metal Halide-Catalyzed Alkylations with Organic Halides at a Boron Site.; by B,B Addition of Polyboranes to Alkynes.; by Boron Hydrides with Acetylides, Cyanides, or lsocyanides.; by CO Displacements from Polyboranes.; by Other Reactions Using Polyboranes.; Formation of Carbon-Al Bonds; from the Elements; from Al Metal and Its Alloys; by the Interaction of H2 Olefin and Al Metal.; by the Action of Organic Halides on Al.; by the Reaction of Organomercurials with Al.; from Al Halides or Organoaluminum Halides; by Reaction with Polar Organometallics.by Redistribution with Organoaluminums.by the Interaction with an Active-Metal Hydride and Olefin.; by the Dehalogenation of RnAIX3- n with Active Metals.; from Al Hydrides or Complex Al Hydrides; by Addition to Olefins or Acetylenes (Hydroalumination).; by Transfer of Al Hydride from One Olefin to Another-Al Alkyl-Olefin Displacement.; by Redistribution with Organoaluminums.; by Exchange with Other Organometallics.; from Other Organoaluminum Compounds; by Addition of R-AI Bonds to Olefins or Acetylenes (Carbalumination).by Substitution of Acidic Carbon-Hydrogen Bonds by Carbon-Al Bonds (Alumination).For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifiying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulneInorganic Reactions and MethodsChemical kineticsEffect of temperature onInorganic compoundsSynthesisChemical kineticsEffect of temperature on.Inorganic compoundsSynthesis.541.3/9541.39Zuckerman J. J(Jerold J.),1936-1987.857123Hagen A. P857124MiAaPQMiAaPQMiAaPQBOOK9910643122603321Formation of bonds to C, Si, Ge, Sn, Pb3004836UNINA