04158nam 22006495 450 991062432010332120251009105919.09783031150661(electronic bk.)978303115065410.1007/978-3-031-15066-1(MiAaPQ)EBC7131999(Au-PeEL)EBL7131999(CKB)25280505600041(PPN)266350550(DE-He213)978-3-031-15066-1(OCoLC)1379090988(EXLCZ)992528050560004120221104d2022 u| 0engurcnu||||||||txtrdacontentcrdamediacrrdacarrierStable Supported Gold Nanoparticle Catalyst for Environmentally Responsible Propylene Epoxidation /by Nidhi Kapil1st ed. 2022.Cham :Springer International Publishing :Imprint: Springer,2022.1 online resource (212 pages)Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5061Includes index.Print version: Kapil, Nidhi Stable Supported Gold Nanoparticle Catalyst for Environmentally Responsible Propylene Epoxidation Cham : Springer International Publishing AG,c2022 9783031150654 Introduction -- Propylene Oxide and Its Production -- Propylene Epoxidation Reactor Design -- Synthesis of Gold Cluster-Based Catalyst and Effect of Pre-Treatments on Its Catalytic Performance -- Precisely Engineered Supported Gold Clusters as a Stable Catalyst for Propylene Epoxidation -- Tailoring Gold Nanoparticles with Tunable Core Size and Their Catalytic Applications -- Propylene Epoxidation on Au/Ti-containing Supports: The Effect of the Support -- Controlled Engineering of Supported Metal Nanoparticles Using Electrospraying: Robust Removal of Stabilising Ligands -- Conclusions and Future Work -- Appendix.This book describes a detailed multi-scale approach integrating nano- (active site), meso- (porous catalyst architecture) and macroscale (reactor) efforts, to address the challenges of producing a better epoxidation catalyst. It contains an in-depth study of the design and synthesis of gold nanoparticles and their application as a catalyst for direct gas phase propylene epoxidation. “Direct” means using only hydrogen and oxygen in one step, which is key for sustainable manufacturing, as opposed to commercialised, more complex production routes requiring multiple steps, or integration with another chemical plant. The insights gained can be used for rational design for stable and selective catalysts for other reactions. It also details the step-by-step process to build an epoxidation reactor system with a focus on safety aspects, which can be used as a guidebook for undergraduate and graduate students in chemical engineering. Beyond heterogeneous catalysis, the new, easily accomplished methodology for synthesising atomically precise nanoparticles is shown to be relevant to electrocatalysis and to healthcare applications, such as anti-microbial surfaces. This book will be of interest to researchers, engineers and experts in the related areas of chemical engineering, chemistry, material science and electrochemistry.Springer Theses, Recognizing Outstanding Ph.D. Research,2190-5061Chemical engineeringNanotechnologyCatalysisSustainabilityChemical EngineeringNanotechnologyCatalysisSustainabilityChemical engineering.Nanotechnology.Catalysis.Sustainability.Chemical Engineering.Nanotechnology.Catalysis.Sustainability.338.4Kapil Nidhi1265993MiAaPQMiAaPQMiAaPQ9910624320103321Stable Supported Gold Nanoparticle Catalyst for Environmentally Responsible Propylene Epoxidation2968426UNINA