06651nam 2200445 450 991058347160332120181207125014.00-12-814269-30-12-814268-5(CKB)4100000002037910(MiAaPQ)EBC5236984(PPN)233365540(EXLCZ)99410000000203791020180221h20182018 uy 0engurcnu||||||||rdacontentrdamediardacarrierElements of structures and defects of crystalline materials /Tsang-Tse FangAmsterdam, Netherlands :Elsevier,2018.©20181 online resource (216 pages) illustrationsebook version : 9780128142691 Includes bibliographical references and index.Machine generated contents note:pt. IStructures of the Crystalline Materials --1.The Electron Configuration of Atoms --1.1.Atoms With a Single Electron --1.2.Atoms With More Than One Electron --1.2.1.Penetration and Shielding --1.2.2.Energetic d-Orbital Collapse of Free Neutral Atoms at the Beginning of the Transition Rows --2.Bonding Within Crystal Structures --2.1.Bonding in Ionic Crystals --2.1.1.Energy for Forming the Ions From Neutral Atoms --2.1.2.Thermodynamic Viewpoint of Bond Energy --2.2.Covalent Bonds --2.2.1.Formation Energy and Mechanism of Covalent Bonding --2.3.Metallic Bonds --2.3.1.Cohesive Energy of Metals --2.4.Effect of Bonding on the Material Properties by Means of the Potential-Well Concept --2.4.1.Elastic Modulus --2.4.2.Melting Temperatures --2.4.3.Thermal Property --3.The Structures of Crystalline Crystals --3.1.Arrangements of Atoms and Ions in Crystalline Solids: Space Lattice --3.2.Metallic Structures --3.3.Ionic Structures --3.3.1.Pauling's Rules --3.4.Structural Distortion in Ionic Structures --3.4.1.Effects of Crystal Field on the Structures of the Oxides --3.4.2.Crystal Field Stabilization Energy --3.4.3.Effects of the d Electron Configuration on the Radii of Transition Metal Ions --3.4.4.Jahn -- Teller Distortions --3.4.5.Structure Distortions Arising From Asymmetric Electron Density or Inert Pair Effect --3.5.Structure of Material Technological Interest --3.5.1.Structure and the Related Feature of ZnO --3.5.2.Structure and the Related Feature of SiC --3.5.3.Structure and the Related Feature of TiO2 --3.5.4.Structure and the Related Feature of ZrO2 --3.5.5.Structure and the Related Feature of Spinel (AB2O4) --3.5.6.Structure and the Related Feature of Perovskite ABO3 --pt. IIDefects of Crystalline Materials --4.Point Defects in Crystalline Materials --4.1.Point Defects in Metals --4.1.1.Solid Solutions --4.1.2.Factors Affecting the Solubility of Impurity Atoms in a Substitutional Solid Solution --4.1.3.Factors Affecting the Solubility of the Impurity Atoms in an Interstitial Solid Solution --4.1.4.Equilibrium Concentration of Point Defects --4.2.Point Defects in Ionic Solids --4.2.1.Notation for the Description of Point Defects in Binary Metal Oxides --4.2.2.Defect Structures in Stoichiometric Ionic Crystals --4.2.3.Defect Structures in Nonstoichiometric Ionic Crystals --4.2.4.Defect Reactions --4.2.5.Formulation of Defect Equations --4.2.6.Defect Equilibrium in Ionic Solids --4.2.7.Defect Association --5.Line Defects in Crystalline Solids --5.1.The Discrepancy Between the Theoretical and Observed Yield Stresses of Crystals --5.2.Observations of Dislocations --5.3.Crystallographic Slip --5.4.Elementary Geometric Characteristics of Dislocations --5.4.1.The Edge Dislocation --5.4.2.The Screw Dislocation --5.4.3.The Mixed Dislocation --5.5.Critical Resolved Shear Stress --5.6.Plastic Flow Associated With the Slip of the Dislocation Motion --5.7.Stress Fields of Dislocations --5.7.1.Constitutive Equations With Lame Constants --5.7.2.Stress Field of a Screw Dislocation --5.7.3.Stress Fields of an Edge Dislocation --5.8.Energy of a Dislocation --5.8.1.Strain Energy of a Screw Dislocation --5.8.2.Strain Energy of an Edge Dislocation --5.9.Line Tension of a Dislocation --5.10.Forces Upon Dislocations --5.11.The Bowing of a Dislocation --5.12.Force Between Dislocations --5.13.Peach-Koehler Equation --5.14.Reactions Between Dislocations --5.14.1.Dislocation Nodes --5.14.2.Kinks and Jogs --5.14.3.Intersections of Dislocations --5.15.Extended Dislocations --5.15.1.Partial Dislocations --5.15.2.Faults in the Stacking in FCC Crystals --5.15.3.Equilibrium Separation Between Partial Dislocations --6.Two-Dimensional (Interfaces) and Three-Dimensional (Second Phases) Imperfections in Solids --6.1.Grain Boundaries --6.1.1.Tilt Boundary --6.1.2.Twist Boundary --6.1.3.Coincidence Site Lattice --6.2.Interphase Boundaries in Solids --6.2.1.Coherent Boundary --6.2.2.Incoherent Boundary --6.2.3.Partially Coherent or Semicoherent Boundary --6.3.Surface Tension, Surface Stress, and Surface Free Energy of Interfaces --6.4.Free Surface --6.4.1.Calculate the Surface Free Energy of a Pure Solid FCC Metal --6.5.Interfaces of Phases --6.5.1.Wetting --6.5.2.Equilibrium Shapes of Grains --6.5.3.Morphological Changes of Second Phases --6.6.Effect of Interface Curvature on the Equilibrium Pressure Between Two Phases --6.7.Effect of the Interface Curvature on the Equilibrium Solubility Between Two Phases --6.8.Equilibrium Vacancy Concentration Changes at Curved Surfaces: Driving Force for Sintering.Pt. 1. Structure of the crystalline materials -- The electron configuration of atoms -- Bonding within crystal structures -- The structures of crystalline crystals -- Part II. Defects of Crystalline Materials -- Point defects in crystalline materials -- Line defects in crystalline solids -- Two-dimensional (interfaces) and three-dimensional (second phases) imperfections in solids.CrystalsStructureCrystalsDefectsCrystalsStructure.CrystalsDefects.548.81Fang Tsang-Tse873509MiAaPQMiAaPQMiAaPQBOOK9910583471603321Elements of structures and defects of crystalline materials1950104UNINA