04215nam 2201045z- 450 991055772790332120231214133434.0(CKB)5400000000046045(oapen)https://directory.doabooks.org/handle/20.500.12854/68530(EXLCZ)99540000000004604520202105d2021 |y 0engurmn|---annantxtrdacontentcrdamediacrrdacarrierσ- and π-Hole InteractionsBasel, SwitzerlandMDPI - Multidisciplinary Digital Publishing Institute20211 electronic resource (212 p.)3-0365-0464-8 3-0365-0465-6 This book describes unconventional noncovalent interactions and analyzes their importance for crystal growth in organic and hybrid organic–inorganic systems. Several examples illustrate how the combination of theory and experiment allows rationalizing the strength and directionality of noncovalent interactions. This book elegantly describes the results of a survey of X-ray structures of main group element compounds (M = Sn, Pb As, Sb, Bi, and Te) exhibiting intermolecular M•••Se noncovalent interactions in one of its chapters. Moreover, it provides a consistent description of noncovalent interactions, covering most groups of the periodic table. The interactions are described and discussed using their trivial names. That is, a comprehensive and accurate description is provided for alkali, alkaline earth, regium, spodium, triel, tetrel, pnictogen, chalcogen, halogen, and aerogen bonding interactions. No other book is available covering such an extensive number of interactions and examples where these interactions are relevant. relevant.Research & information: generalbicsscBiology, life sciencesbicsscnon-covalent interactionsregium bondssilver(I)coinage metalspyrazolatesphosphineshalogen bondinghydrogen bonding sigma-hole interactionstheoretical studiescharacterizationsnoncovalent interactionsLewis acidsLewis basesspodium bondsσ/π-hole interactionsEDTA2,6-diaminopurinecadmiumco-crystalH-bondingπ–π stackingtriazinane1,3,5-TriazacyclohexaneHirshfeld surface analysisDFT studyC–H···π interactionhybridization of a nitrogen atom in sulfonamidesmolecular cocrystalsandwiched-layer structureC–I···F halogen bondsπ···π stacking interactionsPBE0-D3(BJ) calculationssecondary bondingsupramolecularcrystal engineeringtetrel bondingpnictogen bondingchalcogen bondingseleniumstructural chemistrymain group elementsπ–hole interactionsubstituent effectsvibrational spectroscopylocal vibrational mode theorydirect measure for π–hole interaction strengthnoncovalent interactionhydrogen bondingnickelSchiff basescrystallographyσ-holeπ-holecrystal growthsupramolecular chemistryσ-hole interactionsself-assemblyscanning tunneling microscopyResearch & information: generalBiology, life sciencesFrontera Antonioedt1309866Frontera AntonioothBOOK9910557727903321Σ- and π-Hole Interactions3654759UNINA