04220nam 2201057z- 450 991055772790332120210501(CKB)5400000000046045(oapen)https://directory.doabooks.org/handle/20.500.12854/68530(oapen)doab68530(EXLCZ)99540000000004604520202105d2021 |y 0engurmn|---annantxtrdacontentcrdamediacrrdacarrierσ- and π-Hole InteractionsBasel, SwitzerlandMDPI - Multidisciplinary Digital Publishing Institute20211 online resource (212 p.)3-0365-0464-8 3-0365-0465-6 This book describes unconventional noncovalent interactions and analyzes their importance for crystal growth in organic and hybrid organic-inorganic systems. Several examples illustrate how the combination of theory and experiment allows rationalizing the strength and directionality of noncovalent interactions. This book elegantly describes the results of a survey of X-ray structures of main group element compounds (M = Sn, Pb As, Sb, Bi, and Te) exhibiting intermolecular M•••Se noncovalent interactions in one of its chapters. Moreover, it provides a consistent description of noncovalent interactions, covering most groups of the periodic table. The interactions are described and discussed using their trivial names. That is, a comprehensive and accurate description is provided for alkali, alkaline earth, regium, spodium, triel, tetrel, pnictogen, chalcogen, halogen, and aerogen bonding interactions. No other book is available covering such an extensive number of interactions and examples where these interactions are relevant. relevant.Biology, life sciencesbicsscResearch & information: generalbicssc1,3,5-Triazacyclohexane2,6-diaminopurineC-H···π interactionC-I···F halogen bondscadmiumchalcogen bondingcharacterizationsco-crystalcoinage metalscrystal engineeringcrystal growthcrystallographyDFT studydirect measure for π-hole interaction strengthEDTAH-bondinghalogen bondingHirshfeld surface analysishybridization of a nitrogen atom in sulfonamideshydrogen bondinghydrogen bonding sigma-hole interactionsLewis acidsLewis baseslocal vibrational mode theorymain group elementsmolecular cocrystalnickelnon-covalent interactionsnoncovalent interactionnoncovalent interactionsPBE0-D3(BJ) calculationsphosphinespnictogen bondingpyrazolatesregium bondssandwiched-layer structurescanning tunneling microscopySchiff basessecondary bondingseleniumself-assemblysilver(I)spodium bondsstructural chemistrysubstituent effectssupramolecularsupramolecular chemistrytetrel bondingtheoretical studiestriazinanevibrational spectroscopyπ-holeπ-hole interactionπ-π stackingπ···π stacking interactionsσ-holeσ-hole interactionsσ/π-hole interactionsBiology, life sciencesResearch & information: generalFrontera Antonioedt1309866Frontera AntonioothBOOK9910557727903321Σ- and π-Hole Interactions4416894UNINA