04265nam 2201333z- 450 991055737270332120231214132924.0(CKB)5400000000042164(oapen)https://directory.doabooks.org/handle/20.500.12854/76458(EXLCZ)99540000000004216420202201d2021 |y 0engurmn|---annantxtrdacontentcrdamediacrrdacarrierCarbon LigandsFrom Fundamental Aspects to ApplicationsBasel, SwitzerlandMDPI - Multidisciplinary Digital Publishing Institute20211 electronic resource (311 p.)3-0365-1350-7 3-0365-1349-3 Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centered on elements of group 15, and it is only more recently that carbon ligands have proved to be valuable alternatives with the emergence of cyclic diaminocarbenes (NHC).This Special Issue aims to provide a contemporary overview of the advances in carbon ligand chemistry from fundamental aspects to applications.Carbon Ligands Research & information: generalbicssccarbenesylidesDFT calculationselectronic structurecatalysisligandsstructure-activity relationshipNHCnanoparticlecalixarenepalladium catalystSuzuki-Miyaura reactionamino-acidswatercarbon ligandamidenegative chargephosphonium ylideoxidepincermetathesisrutheniumnitro catalystsNHC ligandsolefinsselenonium ylidesselenonium saltschiralitystereogenic selenium atomasymmetric synthesisoptical resolutionreactivitymalariaPlasmodium falciparumgoldNHC-ligandshybrid moleculesdrug resistanceN-heterocyclic carbeneplatinummetal complexes195Pt NMRN-heterocyclic carbenesimidazolespectroscopyX-raymercury(II) complexT-shapedcarbodiphosphoranephosphorus ylidespincer ligandscoordination chemistryCu(I) complexphotoluminescencetitaniumhafniumcopolymerization of epoxide with CO2density functional theorynatural bond orbitalsaromaticityion pairsalkali metalstropylidenyl ionscyclooctatetraene ionsrhodiumelectron paramagnetic resonance (EPR) spectroscopydensity functional theory (DFT)electrochemistrycarbone complexescarbido complexestransition metal complexeschemical bondingpincer ligandmacrocyclelithiumpotassiumintramolecular C-H activationdehydrogenationcarboneligandgermylenecoordinationylideResearch & information: generalCanac Yvesedt1318571Canac YvesothBOOK9910557372703321Carbon Ligands3033415UNINA